We develop a novel approach to phase transitions in quantum spin models based
on a relation to their classical counterparts. Explicitly, we show that
whenever chessboard estimates can be used to prove a phase transition in the
classical model, the corresponding quantum model will have a similar phase
transition, provided the inverse temperature β and the magnitude of the
quantum spins \CalS satisfy \beta\ll\sqrt\CalS. From the quantum system we
require that it is reflection positive and that it has a meaningful classical
limit; the core technical estimate may be described as an extension of the
Berezin-Lieb inequalities down to the level of matrix elements. The general
theory is applied to prove phase transitions in various quantum spin systems
with \CalS\gg1. The most notable examples are the quantum orbital-compass
model on Z2 and the quantum 120-degree model on Z3 which are shown to
exhibit symmetry breaking at low-temperatures despite the infinite degeneracy
of their (classical) ground state.Comment: 47 pages, version to appear in CMP (style files included