Using recent results by the authors on the spectral asymptotics of the
Neumann Laplacian with magnetic field, we give precise estimates on the
critical field, HC3, describing the appearance of superconductivity in
superconductors of type II. Furthermore, we prove that the local and global
definitions of this field coincide. Near HC3 only a small part, near the
boundary points where the curvature is maximal, of the sample carries
superconductivity. We give precise estimates on the size of this zone and decay
estimates in both the normal (to the boundary) and parallel variables