DL Kepert

KR Trigwell

Titanium and niobium
tetrachlorides form the eight-coordinate adducts [TiCl4(naars)2] and[NbCl4(naars)2] with 1,8-bisdimethylarsinonaphthalene.
The visible spectrum of the latter compound shows that as a result of the small
?bite? of this bidentate ligand, the order of orbital energies is dxy &lt; dxz,
dyz &lt; dx2-y2 &lt; dz2.





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Eight-coordinate complexes of titanium and niobium tetrachlorides with 1,8- Bisdimethylarsinonaphthalene

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