To enhance the performance of aircraft engines, high temperature materials are required being capable to operate at temperatures significantly higher than the temperature limit of about 1150°C approached for Ni-based superalloys currently employed. Nb/Nb5Si3-based composites are promising candidates for turbine engine applications at temperatures up to 1300°C, exhibiting balanced mechanical properties and reduced density compared to Ni-based superalloys [1]. To use these composites in gas turbine combustion atmosphere, environmental/thermal barrier coatings (E/TBCs) are required to protect them against heat, degradation in flowing water vapour and chemical attack of calcium-magnesium-alumino-silicate (CMAS)