The cathode catalyst layer in a proton exchange membrane fuel cell is now known to contain ionomer nanofibers and experiments have demonstrated a fuel cell performance increase of 107% greater for the case with 10% of the cathode catalyst layer ionomer in nanofiber form versus the same case without nanofibers. This difference is consistent with trends observed in previously published experimental results. These results are significant since they suggest alternative methods to reduce platinum loading in fuel cells and to optimize fuel cell performance