A Mononuclear and a Mixed-Valence Chain Polymer Arising from Copper(II) Halide Chemistry and the Use of 2,2'-Pyridil

Abstract

Reactions of 2, 2 -pyridil (pyCOCOpy) with (2) , respectively. Both complexes crystallize in the triclinic space group P 1. The lattice constants are a = 8.382(2), b = 9.778(2), c = 7.814(2), α = 101.17(1), β = 114.55(1), γ = 94.14(1) • for 1 and a = 8.738(1), b = 9.375(2), c = 7.966(1), α = 79.09(1), β = 64.25(1), γ = 81.7