Self-Diffusion along Dislocations in Ultra High Purity Iron

Abstract

Self-diffusion along dislocations in ultra high purity iron containing 0.5-1.2 mass ppm carbon, 0.1-1.0 mass ppm nitrogen and 1.8-4.0 mass ppm oxygen has been studied by the radioactive tracer method with the sputter-microsectioning technique. Below 700 K, the self-diffusion coefficient along dislocations has been determined directly from the type C kinetics classified by Harrison, whereas above 800 K it has been obtained by the type B kinetics assuming that the effective radius of dislocation pipe is equal to 5 × 10 −10 m. The temperature dependence of the self-diffusion coefficient along dislocations does not show a linear Arrhenius relation. Below 900 K the Arrhenius plot shows slightly downward curvature. However, above 900 K the self-diffusion coefficient along dislocations increases remarkably with increasing temperature. The value at 900 K is 10 −14 m 2 s −1 , while it takes 10 −10 m 2 s −1 at the Curie temperature (1043 K). It seems that the steep increase of the self-diffusion coefficient along dislocations near the Curie temperature is related to the magnetic transformation in ultra high purity iron