Abstract

This is the first of a series of papers on a systematic application of the NRQED bound state theory of Caswell and Lepage to higher-order radiative corrections to the hyperfine structure of the muonium ground state. This paper describes the calculation of the α2(Zα)\alpha^2 (Z\alpha) radiative correction. Our result for the complete α2(Zα)\alpha^2 (Z\alpha) correction is 0.424(4) kHz, which reduces the theoretical uncertainty significantly. The remaining uncertainty is dominated by that of the numerical evaluation of the nonlogarithmic part of the α(Zα)2\alpha (Z\alpha )^2 term and logarithmic terms of order α4\alpha^4.Comment: 56 pages, Rev.tex V3.0 and epsf.tex. 12 postscript files are called in the text. Version accepted by Phys. Rev. D. A new table is adde

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