VLA observations of water masers towards 6.7 GHz methanol maser sources

22 GHz water and 6.7 GHz methanol masers are usually thought as signposts of early stages of high-mass star formation but little is known about their associations and the physical environments they occur in. The aim was to obtain accurate positions and morphologies of the water maser emission and relate them to the methanol maser emission recently mapped with Very Long Baseline Interferometry. A sample of 31 methanol maser sources was searched for 22 GHz water masers using the VLA and observed in the 6.7 GHz methanol maser line with the 32 m Torun dish simultaneously. Water maser clusters were detected towards 27 sites finding 15 new sources. The detection rate of water maser emission associated with methanol sources was as high as 71%. In a large number of objects (18/21) the structure of water maser is well aligned with that of the extended emission at 4.5 $\mu$m confirming the origin of water emission from outflows. The sources with methanol emission with ring-like morphologies, which likely trace a circumstellar disk/torus, either do not show associated water masers or the distribution of water maser spots is orthogonal to the major axis of the ring. The two maser species are generally powered by the same high-mass young stellar object but probe different parts of its environment. The morphology of water and methanol maser emission in a minority of sources is consistent with a scenario that 6.7 GHz methanol masers trace a disc/torus around a protostar while the associated 22 GHz water masers arise in outflows. The majority of sources in which methanol maser emission is associated with the water maser appears to trace outflows. The two types of associations might be related to different evolutionary phases.Comment: accepted by Astronomy & Astrophysic

Trace levels of metallic corrosion in water determined by emission spectrography

Emission spectrographic method determines trace amounts of inorganic impurities in potable water. The capability of this innovation should arouse considerable interest among plant biologists, chemists working in organic synthesis, and pathologists

Discriminating cool-water from warm-water carbonates and their diagenetic environments using element geochemistry: the Oligocene Tikorangi Formation (Taranaki Basin) and the dolomite effect

Fields portrayed within bivariate element plots have been used to distinguish between carbonates formed in warm- (tropical) water and cool- (temperate) water depositional settings. Here, element concentrations (Ca, Mg, Sr, Na, Fe, and Mn) have been determined for the carbonate fraction of bulk samples from the late Oligocene Tikorangi Formation, a subsurface, mixed dolomite-calcite, cool-water limestone sequence in Taranaki Basin, New Zealand. While the occurrence of dolomite is rare in New Zealand Cenozoic carbonates, and in cool-water carbonates more generally, the dolomite in the Tikorangi carbonates is shown to have a dramatic effect on the "traditional" positioning of cool-water limestone fields within bivariate element plots. Rare undolomitised, wholly calcitic carbonate samples in the Tikorangi Formation have the following average composition: Mg 2800 ppm; Ca 319 100 ppm; Na 800 ppm; Fe 6300 ppm; Sr 2400 ppm; and Mn 300 ppm. Tikorangi Formation dolomite-rich samples (>15% dolomite) have average values of: Mg 53 400 ppm; Ca 290 400 ppm; Na 4700 ppm; Fe 28 100 ppm; Sr 5400 ppm; and Mn 500 ppm. Element-element plots for dolomite-bearing samples show elevated Mg, Na, and Sr values compared with most other low-Mg calcite New Zealand Cenozoic limestones. The increased trace element contents are directly attributable to the trace element-enriched nature of the burial-derived dolomites, termed here the "dolomite effect". Fe levels in the Tikorangi Formation carbonates far exceed both modern and ancient cool-water and warm-water analogues, while Sr values are also higher than those in modern Tasmanian cool-water carbonates, and approach modern Bahaman warm-water carbonate values. Trace element data used in conjunction with more traditional petrographic data have aided in the diagenetic interpretation of the carbonate-dominated Tikorangi sequence. The geochemical results have been particularly useful for providing more definitive evidence for deep burial dolomitisation of the deposits under the influence of marine-modified pore fluids

Water quality of Texas bays (nutrients, trace elements and toxic compounds)

This manuscript is designed to compare the nutrient balances and trace element significance in Texas Bays and Estuaries. The task of assigning water quality criteria in all estuarine waters rests with the federal Environmental Protection Agency. However, the Texas Bays and Estuaries represent a unique range of environments of the U.S. Coast that stand alone and therefore must be assigned standards appropriate to the environment. Therefore we have compared several Texas Bays relative to nutrients and trace elements through an analysis of data from our files, a life history data bank from literature survey, a study of the Corpus Christi area, personal communication with a wide range of individuals and information from the Texas Water Quality Board, Texas Water Development Board, the U.S. Geological Survey and the State Health Department.May 30, 1974Taken in part from a report on Development of Biological Criteria, Establishment of Guidelines for Texas Coast Management IAC-(74-75)-0685 NSF RANN-61-34870xMarine Scienc

Experimental and computational studies of water drops falling through model oil with surfactant and subjected to an electric field

The behaviour of a single sub-millimetre-size water drop falling through a viscous oil while subjected to an electric field is of fundamental importance to industrial applications such as crude oil electrocoalescers. Detailed studies, both experimental and computational, have been performed previously, but an often challenging issue has been the characterization of the fluids. As numerous authors have noted, it is very difficult to have a perfectly clean water-oil system even for very pure model oils, and the presence of trace chemicals may significantly alter the interface behaviour. In this work, we consider a well- characterized water-oil system where controlled amounts of a surface active agent (Span 80) have been added to the oil. This addition dominates any trace contaminants in the oil, such that the interface behaviour can also be well-characterized. We present the results of experiments and corresponding two-phase- flow simulations of a falling water drop covered in surfactant and subjected to a monopolar square voltage pulse. The results are compared and good agreement is found for surfactant concentrations below the critical micelle concentration.Comment: 7 pages, 9 figures, to be presented at the ICDL 2014 conferenc

Trace gas assimilation of Mars orbiter observations

Ozone, water vapour and argon are minor constituents in the Martian atmosphere, observations of which can be of use in constraining atmospheric dynamical and physical processes. This is especially true in the winter season of each hemisphere, when the bulk of the main constituent in the atmosphere (CO2 ) condenses in the polar regions shifting the balance of atmospheric composition to a more trace gas rich air mass. Current Mars Global Circulation Models (MGCMs) are able to represent the photochemistry occuring in the atmosphere, with constraints being imposed by comparisons with observations. However, a long term comparison using data assimilation provides a more robust constraint on the model. We aim to provide a technique for trace gas data assimilation for the analysis of observations from current and future satellite missions (such as ExoMars) which observe the spatial and temporal distribution of trace gases on Mars

Movement of Trace Elements During Residence in the Antarctic Ice: a Laboratory Simulation

Recent work has determined that differences in the trace element distribution between Antarctic eucrites and non-Antarctic eucrites may be due to weathering during residence in the ice, and samples that demonstrate trace element disturbances do not necessarily correspond to eucrites that appear badly weathered to the naked eye. This study constitutes a preliminary test of the idea that long-term residence in the ice is the cause of the trace element disturbances observed in the eucrites. Samples of a non-Antarctic eucrite were leached in water at room temperature conditions. Liquid samples were analyzed for rare earth element abundances using ion chromatography. The results for the short-term study showed little or no evidence that leaching had occurred. However, there were tantalizing hints that something may be happening. The residual solid samples are currently being analyzed for the unleached trace metals using instrumental neutron activation analysis and should show evidence of disturbance if the chromatography clues were real. In addition, another set of samples continues to be intermittently sampled for later analysis. The results should give us information about the movement of trace elements under our conditions and allow us to make some tentative extrapolations to what we observe in actual Antarctic eucrite samples

Nd & Hf concentrations and isotopic compositions in the Baltic Sea

Within a process study in the framework of the international GEOTRACES program and led by the Institute of Oceanology of the Polish Academy of Sciences (IOPAN) a two-week cruise on the R/V Oceania sailed in November 2011 to investigate the distribution of trace elements and their isotopes in the Baltic Sea. The scientific goals were particularly focused on compiling trace element budgets for the Baltic Sea including in- and outflow, as well as to investigate elemental behavior and isotopic fractionation associated with the redox gradients of the Baltic Sea water column and the permanently anoxic conditions within its deep basins (i.e. Gotland Deep, Landsort Deep). The Baltic Sea is a shallow, brackish inland sea with an average salinity of ~7 psu in the mixed layer. It is fed by the Bothnian Sea in the north, by the Finland Sea in the east, as well as by numerous rivers from Scandinavia and the Baltic states, and it is drained through the Danish Strait into the North Sea. In the opposite direction, a denser bottom water mass enters the Baltic Sea through deeper channels from the Danish Strait successively filling the deep basins northward. Below 130 m water depth, the water column is permanently anoxic. Here we present the first combined data set of Nd and Hf concentrations and isotopic compositions for the Baltic Sea. A total of 21 water samples (60L volume per sample) including two water column profiles from the deeper basins were filtered (0.45 μm) and Nd and Hf were extracted and analysed following the accepted GEOTRACES protocols. The distribution patterns of the two elements and their isotopic compositions are compared to hydrographic data and oxygen measurements and provide information on sources and mixing of water masses, as well as on exchange processes with the underlying sediments, which are influenced by the prevailing redox gradients

Seasonal variation of some trace metal concentrations in some fish species on stretch of River Kubanni, Zaria

In a semi-urbanized stretch of river Kubanni, Zaria, seasonal variations of some tree metals (copper, zinc and lead) in fish species (Clarias sp., Tilapia sp and Alestes sp) were investigated over a period of eight months. Water and fish were sampled monthly, pooled separately and seasonal analysis of each trace determined using atomic absorption method. The concentration of each of the elements in water higher in the dry season than during the rainy season. The dry and rainy season concentrations of copper, zinc and lead were 6.85~c10.66 mu gg super(-1)&1.45~c1.10 mu gg super(-1); 2.13~c1.68 mu gg super(-1)&0.1 5~c0.05 mu gg super(-1); and 0.52~c0.50 mu gg super(-1) & 0.31~c0.14 mu gg super(-1) respectively. Similarly, all the three accumulated more zinc and lead in the dry season than during the rainy season. Tilapia species and to some extent, Alestes species being pelagic had a higher concentration of trace metals than Clarias species which is a bottom dwelling fish Tilapia species may therefore be a better indicator species than Clarias species for monitoring trace metals in water bodies. Reasons for the observed variations in the trace metals were discusse