An Insight Analysis of Nano sized powder of Jackfruit Seed

The preparation of biodegradable nanomaterials by blending starch nanocrystals with various polymer matrices are the most active research. This work reports aspect related to nano-sized particles of jackfruit seed. This approach is simple, faster, eco-friendly, cost effective and suitable for large scale production. X-Ray Diffraction studies analyze particles size, morphology, type of starch and degree of crystallinity. The particle size is found to be 12nm, specific surface area is 625 m2g-1, contains A-type starch and 32% degree of crystallinity. A morphology index (MI) is developed from FWHM of XRD data to understand interrelationship of particle size and specific surface area. MI range is from 0.50 to 0.74. It is correlated with the particle size and specific surface area. It is observed that MI has direct relationship with particle size and an inverse relationship with specific surface area.Comment: 12 Pages, 5 Figures, 5 Table

Structural investigations of poly(ethylene terephthalate)- graft-polystyrene copolymer films

Structural investigations of poly(ethylene terephthalate)-graft-polystyrene (PET-g-PS) films prepared by radiation-induced grafting of styrene onto commercial poly- (ethylene terephthalate) (PET) films were carried out by FTIR, X-ray diffraction (XRD), and differential scanning calorimetry (DSC). The variation in the degree of crystallinity and the thermal characteristics of PETfilms was correlated withthe amount of polystyrene grafted therein (i.e., the degree of grafting). The heat of melting was found to be a function of PET crystalline fraction in the grafted films. The grafting is found to take place by incorporation of amorphous polystyrene grafts in the entire noncrystalline (amorphous) region of the PET films and at the surface of the crystallites. This results in a decrease in the degree of crystallinity with the increase in the degree of grafting, attributed to the dilution of PET crystalline structure with the amorphous polystyrene, without almost any disruption in the inherent crystallinity

The imprint of photoevaporation on edge-on discs

We have performed hydrodynamic and radiative transfer calculations of a photoevaporating disc around a Herbig Ae/Be star to determine the evolution and observational impact of dust entrained in the wind. We find that the wind selectively entrains grains of different sizes at different radii resulting in a dust population that varies spatially and increases with height above the disc at radii > 10 AU. This variable grain population results in a 'wingnut' morphology to the dust density distribution. We calculate images of this dust distribution at NIR wavelengths that also show a wingnut morphology at all wavelengths considered. We have also considered the contribution that crystalline dust grains will have in the wind and show that a photoevaporative wind can result in a significant crystallinity fraction at all radii, when the disc is edge-on. However, when the disc's photosphere is unobscured, a photoevaporative wind makes no contribution to the observable crystallinity fraction in the disc. Finally, we conclude that the analysis of extended emission around edge-on discs could provide a new and independent method of testing photoevaporation models.Comment: 8 pages, 6 figures, accepted for publication in MNRA

Dust crystallinity in protoplanetary disks: the effect of diffusion/viscosity ratio

The process of turbulent radial mixing in protoplanetary disks has strong relevance to the analysis of the spatial distribution of crystalline dust species in disks around young stars and to studies of the composition of meteorites and comets in our own solar system. A debate has gone on in the recent literature on the ratio of the effective viscosity coefficient $\nu$ (responsible for accretion) to the turbulent diffusion coefficient $D$ (responsible for mixing). Numerical magneto-hydrodynamic simulations have yielded values between $\nu/D\simeq 10$ (Carballido, Stone & Pringle, 2005) and $\nu/D\simeq 0.85$ (Johansen & Klahr, 2005}). Here we present two analytic arguments for the ratio $\nu/D=1/3$ which are based on elegant, though strongly simplified assumptions. We argue that whichever of these numbers comes closest to reality may be determined {\em observationally} by using spatially resolved mid-infrared measurements of protoplanetary disks around Herbig stars. If meridional flows are present in the disk, then we expect less abundance of crystalline dust in the surface layers, a prediction which can likewise be observationally tested with mid-infrared interferometers.Comment: 9 pages, 5 figures, accepted for publication in A&

Crystalline silicates as a probe of disk formation history

We present a new perspective on the crystallinity of dust in protoplanetary disks. The dominant crystallization by thermal annealing happens in the very early phases of disk formation and evolution. Both the disk properties and the level of crystallinity are thereby directly linked to the properties of the molecular cloud core from which the star+disk system was formed. We show that, under the assumption of single star formation, rapidly rotating clouds produce disks which, after the main infall phase (i.e. in the optically revealed class II phase), are rather massive and have a high accretion rate but low crystallinity. Slowly rotating clouds, on the other hand, produce less massive disks with lower accretion rate, but high levels of crystallinity. Cloud fragmentation and the formation of multiple stars complicates the problem and necessitates further study. The underlying physics of the model is insufficiently understood to provide the precise relationship between crystallinity, disk mass and accretion rate. But the fact that with `standard' input physics the model produces disks which, in comparison to observations, appear to have either too high levels of crystallinity or too high disk masses, demonstrates that the comparison of these models to observations can place strong contraints on the disk physics. The question to ask is not why some sources are so crystalline, but why some other sources have such a low level of crystallinity.Comment: Accepted for publication in ApJ

Mineral maturity and crystallinity index are distinct characteristics of bone mineral

The purpose of this study was to test the hypothesis that mineral maturity and crystallinity index are two different characteristics of bone mineral. To this end, Fourier transform infrared microspectroscopy (FTIRM) was used. To test our hypothesis, synthetic apatites and human bone samples were used for the validation of the two parameters using FTIRM. Iliac crest samples from seven human controls and two with skeletal fluorosis were analyzed at the bone structural unit (BSU) level by FTIRM on sections 2–4 lm thick. Mineral maturity and crystallinity index were highly correlated in synthetic apatites but poorly correlated in normal human bone. In skeletal fluorosis, crystallinity index was increased and maturity decreased, supporting the fact of separate measurement of these two parameters. Moreover, results obtained in fluorosis suggested that mineral characteristics can be modified independently of bone remodeling. In conclusion, mineral maturity and crystallinity index are two different parameters measured separately by FTIRM and offering new perspectives to assess bone mineral traits in osteoporosis