Supercapacitor leakage in energy-harvesting sensor nodes: fact or fiction?

As interest in energy-harvesting sensor nodes continues to grow, the use of supercapacitors as energy stores or buffers is gaining popularity. The reasons for their use are numerous, and include their high power density, simple interfacing requirements, simpler measurement of state-of-charge, and a greater number of charging cycles than secondary batteries. However, supercapacitor energy densities are orders of magnitude lower. Furthermore, they have been reported to exhibit significant leakage, and this has been shown to increase exponentially with terminal voltage (and hence stored energy). This observation has resulted in a number of algorithms, designs and methods being proposed for effective operation of supercapacitor-based energy-harvesting sensor nodes. In this paper, it is argued that traditional ‘leakage’ is not as significant as has commonly been suggested. Instead, what is observed as leakage is in fact predominantly due to internal charge redistribution. As a result, it is suggested that different approaches are required in order to effectively utilize supercapacitors in energy-harvesting sensor nodes

Printing of wirelessly rechargeable solid-state supercapacitors for soft, smart contact lenses with continuous operations

Recent advances in smart contact lenses are essential to the realization of medical applications and vision imaging for augmented reality through wireless communication systems. However, previous research on smart contact lenses has been driven by a wired system or wireless power transfer with temporal and spatial restrictions, which can limit their continuous use and require energy storage devices. Also, the rigidity, heat, and large sizes of conventional batteries are not suitable for the soft, smart contact lens. Here, we describe a human pilot trial of a soft, smart contact lens with a wirelessly rechargeable, solid-state supercapacitor for continuous operation. After printing the supercapacitor, all device components (antenna, rectifier, and light-emitting diode) are fully integrated with stretchable structures for this soft lens without obstructing vision. The good reliability against thermal and electromagnetic radiations and the results of the in vivo tests provide the substantial promise of future smart contact lenses

Energy Harvesting and Management for Wireless Autonomous Sensors

Wireless autonomous sensors that harvest ambient energy are attractive solutions, due to their convenience and economic benefits. A number of wireless autonomous sensor platforms which consume less than 100?W under duty-cycled operation are available. Energy harvesting technology (including photovoltaics, vibration harvesters, and thermoelectrics) can be used to power autonomous sensors. A developed system is presented that uses a photovoltaic module to efficiently charge a supercapacitor, which in turn provides energy to a microcontroller-based autonomous sensing platform. The embedded software on the node is structured around a framework in which equal precedent is given to each aspect of the sensor node through the inclusion of distinct software stacks for energy management and sensor processing. This promotes structured and modular design, allowing for efficient code reuse and encourages the standardisation of interchangeable protocols

Supercapacitor assisted LDO (SCALDO) techniquean extra low frequency design approach to high efficiency DC-DC converters and how it compares with the classical switched capacitor converters

Supercapacitor assisted low dropout regulators (SCALDO) were proposed as an alternative design approach to DC-DC converters, where the supercapacitor circulation frequency (switching frequency) is in the order of few Hz to few 10s of Hz, with an output stage based on a low dropout regulator stage. For converters such as 12–5V, 5–3.3V and 5–1.5V, the technique provides efficiency improvement factors of 2, 1.33 and 3 respectively, in compared to linear converters with same input-output combinations. In a 5–1.5V SCALDO regulator, using thin profile supercapacitors in the range of fractional farads to few farads, this translates to an approximate end to end efficiency of near 90%. However, there were concerns that this patented technique is merely a variation of well-known switched capacitor (charge pump) converters. This paper is aimed at providing a broad overview of the capability of SCALDO technique with generalized theory, indicating its capabilities and limitations, and comparing the practical performance with a typical switched capacitor converter of similar current capability

Accurate supercapacitor modeling for energy-harvesting wireless sensor nodes

Supercapacitors are often used in energy-harvesting wireless sensor nodes (EH-WSNs) to store harvested energy. Until now, research into the use of supercapacitors in EH-WSNs has considered them to be ideal or over-simplified, with non-ideal behavior attributed to substantial leakage currents. In this brief, we show that observations previously attributed to leakage are predominantly due to redistribution of charge inside the supercapacitor. We confirm this hypothesis through the development of a circuit-based model which accurately represents non-ideal behavior. The model correlates well with practical validations representing the operation of an EH-WSN, and allows behavior to be simulated over long periods

Nonlinear Control of a DC MicroGrid for the Integration of Photovoltaic Panels

New connection constraints for the power network (Grid Codes) require more flexible and reliable systems, with robust solutions to cope with uncertainties and intermittence from renewable energy sources (renewables), such as photovoltaic arrays. The interconnection of such renewables with storage systems through a Direct Current (DC) MicroGrid can fulfill these requirements. A "Plug and Play" approach based on the "System of Systems" philosophy using distributed control methodologies is developed in the present work. This approach allows to interconnect a number of elements to a DC MicroGrid as power sources like photovoltaic arrays, storage systems in different time scales like batteries and supercapacitors, and loads like electric vehicles and the main AC grid. The proposed scheme can easily be scalable to a much larger number of elements.Comment: arXiv admin note: text overlap with arXiv:1607.0848

In situ NMR and electrochemical quartz crystal microbalance techniques reveal the structure of the electrical double layer in supercapacitors.

Supercapacitors store charge through the electrosorption of ions on microporous electrodes. Despite major efforts to understand this phenomenon, a molecular-level picture of the electrical double layer in working devices is still lacking as few techniques can selectively observe the ionic species at the electrode/electrolyte interface. Here, we use in situ NMR to directly quantify the populations of anionic and cationic species within a working microporous carbon supercapacitor electrode. Our results show that charge storage mechanisms are different for positively and negatively polarized electrodes for the electrolyte tetraethylphosphonium tetrafluoroborate in acetonitrile; for positive polarization charging proceeds by exchange of the cations for anions, whereas for negative polarization, cation adsorption dominates. In situ electrochemical quartz crystal microbalance measurements support the NMR results and indicate that adsorbed ions are only partially solvated. These results provide new molecular-level insight, with the methodology offering exciting possibilities for the study of pore/ion size, desolvation and other effects on charge storage in supercapacitors