Combustion regimes in sequential combustors: Flame propagation and autoignition at elevated temperature and pressure

This numerical study investigates the combustion modes in the second stage of a sequential combustor at atmospheric and high pressure. The sequential burner (SB) features a mixing section with fuel injection into a hot vitiated crossflow. Depending on the dominant combustion mode, a recirculation zone assists flame anchoring in the combustion chamber. The flame is located sufficiently downstream of the injector resulting in partially premixed conditions. First, combustion regime maps are obtained from 0-D and 1-D simulations showing the co-existence of three combustion modes: autoignition, flame propagation and flame propagation assisted by autoignition. These regime maps can be used to understand the combustion modes at play in turbulent sequential combustors, as shown with 3-D large eddy simulations (LES) with semi-detailed chemistry. In addition to the simulation of steady-state combustion at three different operating conditions, transient simulations are performed: (i) ignition of the combustor with autoignition as the dominant mode, (ii) ignition that is initiated by autoignition and that is followed by a transition to a propagation stabilized flame, and (iii) a transient change of the inlet temperature (decrease by 150 K) resulting into a change of the combustion regime. These results show the importance of the recirculation zone for the ignition and the anchoring of a propagating type flame. On the contrary, the autoignition flame stabilizes due to continuous self-ignition of the mixture and the recirculation zone does not play an important role for the flame anchoring

Task-based Augmented Contour Trees with Fibonacci Heaps

This paper presents a new algorithm for the fast, shared memory, multi-core computation of augmented contour trees on triangulations. In contrast to most existing parallel algorithms our technique computes augmented trees, enabling the full extent of contour tree based applications including data segmentation. Our approach completely revisits the traditional, sequential contour tree algorithm to re-formulate all the steps of the computation as a set of independent local tasks. This includes a new computation procedure based on Fibonacci heaps for the join and split trees, two intermediate data structures used to compute the contour tree, whose constructions are efficiently carried out concurrently thanks to the dynamic scheduling of task parallelism. We also introduce a new parallel algorithm for the combination of these two trees into the output global contour tree. Overall, this results in superior time performance in practice, both in sequential and in parallel thanks to the OpenMP task runtime. We report performance numbers that compare our approach to reference sequential and multi-threaded implementations for the computation of augmented merge and contour trees. These experiments demonstrate the run-time efficiency of our approach and its scalability on common workstations. We demonstrate the utility of our approach in data segmentation applications

STRONTIUM ISOTOPE SYSTEMATICS AND GEOCHEMISTRY OF COAL UTILIZATION BY-PRODUCTS

Coal combustion for energy generation creates large quantities of solid coal utilization by-products (CUB), including fly ash, bottom ash, and flue gas desulfurization products. These materials are either used in environmental and industrial applications or stored adjacent to power plants. The development of new techniques to track and understand the behavior of CUB in the environment is essential to the safe utilization of coal. In this research, sequential leaching techniques are coupled with strontium (Sr) isotope analysis to investigate the influence of coal type and combustion process on the geochemical characteristics of CUB. Sequential leaches of water, acetic acid, and hydrochloric acid were carried out on a variety of CUB types. Systematic differences in 87Sr/86Sr ratios were observed (1) among different types of CUB, and (2) between leachates and their corresponding bulk CUB values. These differences can help elucidate the origins of the inorganic components of coal, as well as the transformations that occur during combustion. In addition, this study demonstrates for the first time that there are multiple sources of Sr in coal that remain isotopically distinct during combustion. The degree of isotopic homogenization induced during the formation of CUB appears to be controlled by the feed coal chemistry and the particular combustion technology used. The Sr isotope data, when combined with major and trace element results, suggest that a greater fraction of Sr is bound in detrital minerals in higher-rank coals, while authigenic minerals and organic complexes comprise the dominant form of Sr in lower-rank coals. Investigation of CUB produced from fluidized bed combustion (FBC) also demonstrates that the combustion process can strongly impact the behavior of the inorganic components of coal during utilization. The association of potentially toxic trace elements with certain soluble Sr-bearing phases in CUB make Sr isotopes a promising tool to trace the release of these species during interactions with water. Application of Sr isotopes to studies of coal and CUB could facilitate the development of better disposal techniques by serving as a robust tracer of CUB in the environment

Ignition of Deflagration and Detonation Ahead of the Flame due to Radiative Preheating of Suspended Micro Particles

We study a flame propagating in the gaseous combustible mixture with suspended inert particles. The gas is assumed to be transparent for the radiation emitted by the combustion products, while particles absorb and re-emit the radiation. Thermal radiation heats the particles, which in turn transfer the heat to the surrounding gaseous mixture by means of heat conduction, so that the gas temperature lags that of the particles. We consider different scenarios depending on the spatial distribution of the particles, their size and the number density. In the case of uniform distribution of the particles the radiation causes a modest increase of the temperature ahead of the flame and the corresponding increase of the flame velocity. The effects of radiation preheating is stronger for a flame with smaller normal velocity. In the case of non-uniform distribution of the particles, such that the particles number density is smaller just ahead of the flame and increases in the distant region ahead of the flame, the preheating caused by the thermal radiation may trigger additional independent source of ignition. This scenario requires the formation of a temperature gradient with the maximum temperature sufficient for ignition in the region of denser particles cloud ahead of the advancing flame. Depending on the steepness of the temperature gradient formed in the unburned mixture, either deflagration or detonation can be initiated via the Zeldovich's gradient mechanism. The ignition and the resulting combustion regimes depend on the temperature profile which is formed in effect of radiation absorption and gas-dynamic expansion. In the case of coal dust flames propagating through a layered dust cloud the effect of radiation heat transfer can result in the propagation of combustion wave with velocity up to 1000m/s and can be a plausible explanation of the origin of dust explosion in coal mines.Comment: 45 pages, 14 figures. Accepted for publication Combustion and Flame 29 June 201

Numerical Analysis of Solid Rocket Motor Instabilities With AP Composite Propellants

A non-steady model for the combustion of ammonium perchlorate composite propellants has been developed in order to be incorporated into a comprehensive gasdynamics model of solid rocket motor flow fields. The model including the heterogeneous combustion and turbulence mechanisms is applied to nonlinear combustion instability analyses. This paper describes the essential mechanisms and features of the model and discusses the methodology of non-steady calculations of the combustion instabilities of solid rocket motors

Hydrogen-atom Attack on Phenol and Toluene is \u3cem\u3eortho\u3c/em\u3e-directed

The reaction of H + phenol and H/D + toluene has been studied in a supersonic expansion after electric discharge. The (1 + 1′) resonance-enhanced multiphoton ionization (REMPI) spectra of the reaction products, at m/z = parent + 1, or parent + 2 amu, were measured by scanning the first (resonance) laser. The resulting spectra are highly structured. Ionization energies were measured by scanning the second (ionization) laser, while the first laser was tuned to a specific transition. Theoretical calculations, benchmarked to the well-studied H + benzene → cyclohexadienyl radical reaction, were performed. The spectrum arising from the reaction of H + phenol is attributed solely to the ortho-hydroxy-cyclohexadienyl radical, which was found in two conformers (syn and anti). Similarly, the reaction of H/D + toluene formed solely the ortho isomer. The preference for the ortho isomer at 100–200 K in the molecular beam is attributed to kinetic, not thermodynamic effects, caused by an entrance channel barrier that is ∼5 kJ mol−1 lower for ortho than for other isomers. Based on these results, we predict that the reaction of H + phenol and H + toluene should still favour the ortho isomer under elevated temperature conditions in the early stages of combustion (200–400 °C)