Increased Cycling Efficiency and Rate Capability of Copper-coated Silicon Anodes in Lithium-ion Batteries

Cycling efficiency and rate capability of porous copper-coated, amorphous silicon thin-film negative electrodes are compared to equivalent silicon thin-film electrodes in lithium-ion batteries. The presence of a copper layer coated on the active material plays a beneficial role in increasing the cycling efficiency and the rate capability of silicon thin-film electrodes. Between 3C and C/8 discharge rates, the available cell energy decreased by 8% and 18% for 40 nm copper-coated silicon and equivalent silicon thin-film electrodes, respectively. Copper-coated silicon thin-film electrodes also show higher cycling efficiency, resulting in lower capacity fade, than equivalent silicon thin-film electrodes. We believe that copper appears to act as a glue that binds the electrode together and prevents the electronic isolation of silicon particles, thereby decreasing capacity loss. Rate capability decreases significantly at higher copper-coating thicknesses as the silicon active-material is not accessed, suggesting that the thickness and porosity of the copper coating need to be optimized for enhanced capacity retention and rate capability in this system.Comment: 15 pages, 6 figure

Investigation of a high speed data handling system for use with multispectral aircraft scanners

A buffer memory data handling technique for use with multispectral aircraft scanners is presented which allows digital data generated at high data rates to be recorded on magnetic tape. A digital memory is used to temporarily store the data for subsequent recording at slower rates during the passive time of the scan line, thereby increasing the maximum data rate recording capability over real-time recording. Three possible implementations are described and the maximum data rate capability is defined in terms of the speed capability of the key hardware components. The maximum data rates can be used to define the maximum ground resolution achievable by a multispectral aircraft scanner using conventional data handling techniques

Ge Nanowires Anode sheathed with Amorphous Carbon for Rechargeable Lithium batteries

Interdisciplinary School of Green EnergyThe composite electrode composed of single crystalline Ge NWs sheathed with amorphous carbon showed excellent electrochemical properties of large reversible capacity, high coulombic efficiency, excellent rate capability and stable cycle performance. c-Ge NWs synthesized by using thermal decomposition of C2H2 gas at 700 °C under Ar atmosphere after SLS (solution-liquid-solid) growth were found to have good performance during cycling with Li. The rate capability for charging was shown reversible capacity of 963 mAh/g with a coulombic efficiency of 90% and 700 mAh/g at the rate of 6C (= 4800mA/g). Capacity retention after 100 cycles was 72% at the rate of 0.5C. The improved electrochemical performance of c-Ge-NWs fabricated in our experiment was attributed to the formation of amorphous Ge NWs during cycling and a homogenous carbon coating on Ge NWs. Thus, these results suggest that the use of nanowires structure can be promising for alloy anode materials in lithium ion batteries

Plasma contactor performance characterization

The plasma contactor performance is outlined. Some performance objectives are given including expellant compatibility, high electron production capability, high ion production capability, high reliability for starting and operation, passive emission control, switchover capability between ion/electron emission, low ion and electron energies, low system mass, and low expellant consumption rate. The basic elements of the hollow cathode are shown along with key features of the plasma source

Measurements of the Rate Capability of Various Resistive Plate Chambers

Resistive Plate Chambers (RPCs) exhibit a significant loss of efficiency for the detection of particles, when subjected to high particle fluxes. This rate limitation is related to the usually high resistivity of the resistive plates used in their construction. This paper reports on measurements of the performance of three different glass RPC designs featuring a different total resistance of the resistive plates. The measurements were performed with 120 GeV protons at varying beam intensitie

A comprehensive study of rate capability in Multi-Wire Proportional Chambers

Systematic measurements on the rate capability of thin MWPCs operated in Xenon, Argon and Neon mixtures using CO2 as UV-quencher are presented. A good agreement between data and existing models has been found, allowing us to present the rate capability of MWPCs in a comprehensive way and ultimately connect it with the mobilities of the drifting ions.Comment: 29 pages, 18 figure