Modeling electrolyte composition effects on anion-exchange membrane water electrolyzer performance

Anion-exchange membrane (AEM) water electrolysis could allow inexpensive and greener hydrogen production than other alternatives, such as steam methane reforming. To increase performance, hydroxide salts are often added to the water feed, with the tradeoff of corrosivity and complexity. Recently, carbonate salts that are less corrosive have shown promise, but their specific functionality remains unknown. In this paper, we use a mathematical model to compare an AEM electrolyzer with added potassium carbonate to an AEM electrolyzer with added potassium hydroxide. We show that the conductivity of the carbonate-form membrane has little impact on the performance of the device, but that carbonate ions replace hydroxide in the ionomer, which creates a Nernstian voltage difference across the membrane. The replacement of hydroxide anions with carbonate also reduces utilization of the catalyst in the anode, resulting in an additional voltage loss

Process for preparing higher oxides of the alkali and alkaline earth metals

High purity inorganic higher oxides of the alkali and alkaline earth metals are prepared by subjecting the hydroxide of the alkali and alkaline earth metal to a radio frequency discharge sustained in oxygen. The process is particulary adaptable to the production of high purity potassium superoxide by subjecting potassium hydroxide to glow discharge sustained in oxygen under the pressure of about 0.75 to 1.00 torr

The reactions pertaining to zinc-silver and cadmium-silver batteries Quarterly report

Electrochemical oxidation of zinc, thermal decomposition of silver oxide, and solubility determinations of silver oxides in potassium hydroxide

Space-suit carbon dioxide absorption system: A concept

Partial pressure of carbon dioxide within a space suit is maintained at safe levels by regenerating carbon dioxide with potassium hydroxide solution on board spacecraft or by portable units

Fire extinguishant materials

Fire extinguishant composition comprising a mixture of a finely divided aluminum compound and alkali metal, stannous or plumbous halide is provided. Aluminum compound may be aluminum hydroxide, alumina or boehmite but preferably it is an alkali metal dawsonite. The metal halide may be an alkali metal, e.g. potassium iodide, bromide or chloride or stannous or plumbous iodide, bromide or chloride. Potassium iodide is preferred

Effects of high-energy protons on selected cells Final report, Jun. 1966 - Aug. 1966

Irradiation effects of high energy protons studied on silver-cadmium and nickel-cadmium cells containing battery electrodes and potassium hydroxide electrolyte

Recrystallized parylene as a mask for silicon chemical etching

This paper presents the first use of recrystallized parylene as masking material for silicon chemical etch. Recrystallized parylene was obtained by melting parylene C at 350°C for 2 hours. The masking ability of recrystallized parylene was tested in HNA (hydrofluoric acid, nitric acid and acetic acid) solution of various ratios, KOH (potassium hydroxide) solution and TMAH (tetramethylammonium hydroxide) at different temperatures and concentrations. It is found that interface between parylene and the substrate can be attacked, which results in undercuts. Otherwise, recrystallized parylene exhibited good adhesion to silicon, complete protection of unexposed silicon and silicon etching rates comparable to literature data

Improved surface quality of anisotropically etched silicon {111} planes for mm-scale integrated optics

We have studied the surface quality of millimeter-scale optical mirrors produced by etching CZ and FZ silicon wafers in potassium hydroxide to expose the $\{111\}$ planes. We find that the FZ surfaces have four times lower noise power at spatial frequencies up to $500\, {mm}^{-1}$. We conclude that mirrors made using FZ wafers have higher optical quality

Friction modifier using adherent metallic multilayered or mixed element layer conversion coatings

A process for creating conversion coatings and spin, drawing, and extrusion finishes for surfaces, wherein the conversion coatings and spin, drawing, and extrusion finishes contain potassium, phosphorus, nitrogen, silicon, and one or more non-alkaline metals. The process comprises forming a first aqueous solution of silicate, potassium hydroxide, and ammonium hydroxide; forming a second aqueous solution of water, phosphoric acid, ammonium hydroxide, an alkali metal hydroxide, and one or more non-alkaline metals, and then combining the first solution with the second solution to form a final solution. This final solution forms an anti-friction multi-layer conversion coating or a spin, drawing, and extrusion finish on a surface when applied to the surface, either directly or as an additive in lubricating fluids

Study to investigate and improve the zinc electrode for spacecraft electrochemical cells Final report, 30 May 1966 - 30 Jun. 1967

Zincate diffusivity in alkaline electrolyte determined as function of potassium hydroxide concentration and temperatur