Galvanic corrosion of aluminium–copper model alloys

Galvanic coupling between different α and θ phase-containing model Al–Cu alloys, deposited by magnetron sputtering, has revealed that the anodic α phase did not suffer corrosion and remained in the passive state in sulphate solution. Conversely, sulphate ions induced pitting of the cathodic θ phase. Pitting susceptibility of the cathode increased when the difference between the copper content of the anode and cathode increased. Similar observations were made for all the galvanic couples; further, the higher the copper content of a phase, then the greater its susceptibility to pitting

Surface pitting fatigue life of noninvolute, low-contact-ratio gears

Spur gear endurance tests were conducted to investigate the surface pitting fatigue life of noninvolute gears with low numbers of teeth and low contact ratios for use in advanced applications. The results were compared with those for a standard involute design with a low number of teeth. The gear pitch diameter was 8.89 cm (3.50 in.) with 12 teeth on both gear designs. Test conditions were an oil inlet temperature of 320 K (116 F), an oil outlet temperature of 350 K (170 F), a maximum Hertz stress of 1.49 GPa (216 ksi), and a speed of 10 000 rpm. The following results were obtained: the noninvolute gear had a surface pitting fatigue life approximately 1.6 times that of the standard involute gear of a similar design; and the surface pitting fatigue life of the 3.43-pitch AISI 8620 noninvolute gear was approximately equal to the surface pitting fatigue life of an 8-pitch, 28-tooth AISI 9310 gear at the same load but at a considerably higher maximum Hertz stress

Geabacter species enhances pit depth on 304L stainless steel in a medium lacking with electron donor

Geobacter sulfurreducens bacteria increased the open circuit potential of 304L stainless steel by around 320 mV in only a few hours after inoculation. This represents a significant increase in the corrosion risk. In contrast, the oxidation of acetate, which is catalysed by well-established biofilms, shifted the pitting potential towards positive values. In acetate-lacking media, pitting occurred with and without bacteria in the same range of potential values, but the presence of bacteria drastically increased the size of pits. AFM showed pits more than 10 times broader and deeper due to the presence of bacteria. In the absence of acetate, the masking effect due to acetate oxidation disappeared and the full corrosive effect of the biofilm was revealed. This also fully explains why pitting was predominantly observed close to surface areas where bacterial settlement was the densest

Factors affecting rind pitting in the mandarin hybrids "fortune" and "nova". The influence of exogenous growth regulators

The commercialization of the mandarin hybrids "Fortune" and "Nova" is hindered by the development of cold-induced pitting in the fruit rind which may develop either in the orchard or during storage and transport. In the late cropping cultivar "Fortune", the pitting develops on tree during the winter months and affects mainly the exposed fruit from the north-west quadrant of the tree. The induction of symptoms under uniform conditions in the cold-room reveals differences in the susceptibility to chilling injury among the fruits and the fruit sides. The green fruit is not susceptible. Susceptibility develops as pigmentation progresses, and it is higher for the exposed than for the non-exposed (covered by the foliage) fruits. The application of GA3 at colour-break delays pigmentation and retards the development of susceptibility. The waxing of the fruit offers some protection to cold in the cold-room. However, the incidence of pitting is not related to the wax content of the fruit rind and the application of a wax coverage on tree had only a marginal protective effect. No pitting is usually found on tree in the fruit of the early ripening "Nova" cultivar, which is usually harvested before the winter chilling. The pitting develops during cold storage (8-10 C), and is reduced by GA3 application at colour break, an effect related to the delay in rind pigmentation.info:eu-repo/semantics/publishedVersio

Direct observation of pitting corrosion evolutions on carbon steel surfaces at the nano-to-micro- scales.

The Cl--induced corrosion of metals and alloys is of relevance to a wide range of engineered materials, structures, and systems. Because of the challenges in studying pitting corrosion in a quantitative and statistically significant manner, its kinetics remain poorly understood. Herein, by direct, nano- to micro-scale observations using vertical scanning interferometry (VSI), we examine the temporal evolution of pitting corrosion on AISI 1045 carbon steel over large surface areas in Cl--free, and Cl--enriched solutions. Special focus is paid to examine the nucleation and growth of pits, and the associated formation of roughened regions on steel surfaces. By statistical analysis of hundreds of individual pits, three stages of pitting corrosion, namely, induction, propagation, and saturation, are quantitatively distinguished. By quantifying the kinetics of these processes, we contextualize our current understanding of electrochemical corrosion within a framework that considers spatial dynamics and morphology evolutions. In the presence of Cl- ions, corrosion is highly accelerated due to multiple autocatalytic factors including destabilization of protective surface oxide films and preservation of aggressive microenvironments within the pits, both of which promote continued pit nucleation and growth. These findings offer new insights into predicting and modeling steel corrosion processes in mid-pH aqueous environments

Chemical milling solution produces smooth surface finish on aluminum

Elementary sulfur mixed into a solution of caustic soda and salts produces an etchant which will chemically mill end-grain surfaces on aluminum plate. This composition results in the least amount of thickness variation and pitting

Role of direct microbial electron transfer in corrosion of steels

It has recently been discovered that many microbial species have the capacity to connect their metabolism to solid electrodes, directly exchanging electrons with them through membrane-bound redox compounds,nevertheless such a direct electron transfer pathway has been evoked rarely in the domain of microbial corrosion. Here was evidenced for the first time that the bacterium Geobacter sulfurreducens is able to increase the free potential of 304 L stainless steel up to 443 mV in only a few hours, which represents a drastic increase in the corrosion risk. In contrast, when the bacterial cells form a locally wellestablished biofilm, pitting potentials were delayed towards positive values. The microscopy pictures confirmed an intimate correlation between the zones where pitting occurred and the local settlement of cells. Geobacter species must now be considered as key players in the mechanisms of corrosion