A reanalysis of ozone on Mars from assimilation of SPICAM observations

We have assimilated for the first time SPICAM retrievals of total ozone into a Martian global circulation model to provide a global reanalysis of the ozone cycle. Disagreement in total ozone between model prediction and assimilation is observed between 45°S–10°S from LS=135–180° and at northern polar (60°N–90°N) latitudes during northern fall (LS=150–195°). Large percentage differences in total ozone at northern fall polar latitudes identified through the assimilation process are linked with excessive northward transport of water vapour west of Tharsis and over Arabia Terra. Modelling biases in water vapour can also explain the underestimation of total ozone between 45°S–10°S from LS=135–180°. Heterogeneous uptake of odd hydrogen radicals are unable to explain the outstanding underestimation of northern polar total ozone in late northern fall. Assimilation of total ozone retrievals results in alterations of the modelled spatial distribution of ozone in the southern polar winter high altitude ozone layer. This illustrates the potential use of assimilation methods in constraining total ozone where SPICAM cannot observe, in a region where total ozone is especially important for potential investigations of the polar dynamics

Aura Ozone Monitoring Garden Lithograph

This lithograph describes where ozone is found, how it is formed, and the effects of ozone on biological processes. How and why NASA studies ozone is covered along with how individuals can monitor ground level (tropospheric) ozone by starting their own ozone-monitoring garden. Educational levels: Middle school, High school

The Influence of Wave– and Zonal Mean–Ozone Feedbacks on the Quasi-biennial Oscillation

The effects of wave and zonal mean ozone heating on the evolution of the quasi-biennial oscillation (QBO) are examined using a two-dimensional mechanistic model of the equatorial stratosphere. The model atmosphere is governed by coupled equations for the zonal mean and (linear) wave fields of ozone, temperature, and wind, and is driven by specifying the amplitudes of a Kelvin wave and a Rossby–gravity wave at the lower boundary. Wave–mean flow interactions are accounted for in the model, but not wave–wave interactions. A reference simulation (RS) of the QBO, in which ozone feedbacks are neglected, is carried out and the results compared with Upper Atmosphere Research Satellite observations. The RS is then compared with three model experiments, which examine separately and in combination the effects of wave ozone and zonal mean ozone feedbacks. Wave–ozone feedbacks alone increase the driving by the Kelvin and Rossby–gravity waves by up to 10%, producing stronger zonal wind shear zones and a stronger meridional circulation. Zonal mean–ozone feedbacks (ozone QBO) alone decrease the magnitude of the temperature QBO by up to 15%, which in turn affects the momentum deposition by the wave fields. Overall, the zonal mean–ozone feedbacks increase the magnitude of the meridional circulation by up to 30%. The combined effects of wave–ozone and ozone QBO feedbacks generally produce a larger response then either process alone. Moreover, these combined ozone feedbacks produce a temperature QBO amplitude that is up to 30% larger than simulations without the feedbacks. Correspondingly, significant changes are also observed in the zonal wind and ozone QBOs. When ozone feedbacks are included in the model, the Kelvin and Rossby–gravity wave amplitudes can be reduced by ∼10% and still produce a QBO similar to simulations without ozone

Impact of the assimilation of ozone from the Tropospheric Emission Spectrometer on surface ozone across North America

We examine the impact of assimilating ozone observations from the Tropospheric Emission Spectrometer (TES) on North American surface ozone abundances in the GEOS-Chem model in August 2006. The assimilation reduces the negative bias in the modeled free tropospheric ozone, which enhances the ozone flux into the boundary layer. Surface ozone abundances increased by as much as 9 ppb in western North America and by less than 2 ppb in the southeast, resulting in a total background source of ozone of 20-40 ppb. The enhanced ozone in the model reduced the model bias with respect to surface ozone observations in the western USA, but exacerbated it in the east. This increase in the bias in the boundary layer in the east, despite the agreement between the assimilation and ozonesonde measurements in the free troposphere, suggests errors in the ozone sources or sinks or in boundary layer mixing in the model. © 2009

Is the Ozone Hole Over Your Classroom?

First year university science students are surveyed about their understanding of the ozone layer, ozone depletion and the effect of ozone depletion on Australia. Although students seem to understand the basic function of the ozone layer, over 65% of students incorrectly believe that the ozone hole is over Australia, and over 90% of students incorrectly believe that the ozone hole is present during the summer. Together these ideas seem to explain why nearly 75% of students blame the ozone hole for Australia’s high rate of skin cancer. Survey results also indicate that students seem confused about global warming, and the connection with ozone depletion. Conclusions from this study suggest that better teaching resources for environmental issues such as ozone depletion and global warming are needed before improvements in students’ understanding can be expected

Efficient compact micro DBD plasma reactor for ozone generation for industrial application in liquid and gas phase systems

Ozone is well known as a powerful, fast reacting oxidant. Ozone based processes produce no by-product residual as non-reacted ozone decomposes to molecular oxygen. Therefore an application of ozone is widely accepted as one of the main approaches for a Sustainable and Clean Technologies development. There are number of technologies which require ozone to be delivered to specific points of a production network or reactors construction. Due to space constraints, high reactivity and short life time of ozone the use of ozone generators even of a bench top scale is practically limited. This requires development of mini/micro scale ozone generator which can be directly incorporated into production units. Our report presents a feasibility study of a new micro scale rector for ozone generation (MROG). Data on MROG calibration and indigo decomposition at different operation conditions are presented. At selected operation conditions with residence time of 0.25 s the process of ozone generation is not limited by reaction rate and the amount of ozone produced is a function of power applied. It was shown that the MROG is capable to produce ozone at voltage level starting from 3.5kV with ozone concentration of 5.28*10⁻⁶ (mol/L) at 5kV. This is in line with data presented on numerical investigation for a MROG. It was shown that in compare to a conventional ozone generator, MROG has lower power consumption at low voltages and atmospheric pressure. The MROG construction makes it applicable for both submerged and dry systems. With a robust compact design MROG can be used as an integrated module for production lines of high complexity

Pretreatment of secondary effluents in view of optimal ozone-based AOP removal of trace organic contaminants : bench-scale comparison of efficiency and energy consumption

This study compares the performance of several ozone-based advanced oxidation processes (AOPs), in combination with filtration, in terms of trace organic contaminant (TrOC) removal efficiency and energy and cost requirement. It was shown that the hydroxyl radical ((OH)-O-center dot) scavenging rate of the secondary wastewater effluent decreased as a result of an additional pretreatment step, leading to an increase of ozone and (OH)-O-center dot exposures at the same ozone dose. Adding filtration such as sand filtration or granular activated carbon filtration (GACF) as a pretreatment increased the removal efficiency of TrOCs by all tested ozone-based AOPs and reduced the minimum effective ozone dose for TrOC elimination. When the applied ozone dose is more than this minimum effective ozone dose, the elimination of TrOCs can be observed. For example, because of the use of anion resin filtration, 17 alpha-ethinylestradiol elimination contributed by the process of ozone-based AOP increased from 34.6 to 42.1% at an ozone dose of 1.0 g O-3/g dissolved organic carbon. Ozone-based AOPs coupled with filtration as a pretreatment were found to be more cost-efficient than the single AOPs at all ozone dose levels. The energy consumption of ozone-based AOPs was decreased by more than 25% when applying GACF as a pretreatment. In comparison with other filtration techniques, the pretreatment of secondary effluents by GACF before ozonation was proven to be the most cost-effective method for TrOC elimination

SIMULATING OZONE EFFECTS ON FOREST PRODUCTIVITY: INTERACTIONS AMONG LEAF‐, CANOPY‐, AND STAND‐LEVEL PROCESSES

Ozone pollution in the lower atmosphere is known to have adverse effects on forest vegetation, but the degree to which mature forests are impacted has been very difficult to assess directly. In this study, we combined leaf‐level ozone response data from independent ozone fumigation studies with a forest ecosystem model in order simulate the effects of ambient ozone on mature hardwood forests. Reductions in leaf carbon gain were determined as a linear function of ozone flux to the leaf interior, calculated as the product of ozone concentration and leaf stomatal conductance. This relationship was applied to individual canopy layers within the model in order to allow interaction with stand‐ and canopy‐level factors such as light attenuation, leaf morphology, soil water limitations, and vertical ozone gradients. The resulting model was applied to 64 locations across the northeastern United States using ambient ozone data from 1987 to 1992. Predicted declines in annual net primary production ranged from 3 to 16% with greatest reductions in southern portions of the region where ozone levels were highest, and on soils with high water‐holding capacity where drought stress was absent. Reductions in predicted wood growth were slightly greater (3–22%) because wood is a lower carbon allocation priority in the model than leaf and root growth. Interannual variation in predicted ozone effects was small due to concurrent fluctuations in ozone and climate. Periods of high ozone often coincided with hot, dry weather conditions, causing reduced stomatal conductance and ozone uptake. Within‐canopy ozone concentration gradients had little effect on predicted growth reductions because concentrations remained high through upper canopy layers where net carbon assimilation and ozone uptake were greatest. Sensitivity analyses indicate a trade‐off between model sensitivity to available soil water and foliar nitrogen and demonstrate uncertainties regarding several assumptions used in the model. Uncertainties surrounding ozone effects on stomatal function and plant water use efficiency were found to have important implications on current predictions. Field measurements of ozone effects on mature forests will be needed before the accuracy of model predictions can be fully assessed