Electronic Properties of Topological Materials: Optical Excitations in Moebius Conjugated Polymers

Electronic structures and optical excitations in Moebius conjugated polymers are studied theoretically. Periodic and Moebius boundary conditions are applied to the tight binding model of poly(para-phenylene), taking exciton effects into account. We discuss that oligomers with a few structural units are more effective than polymers for observations of effects of discrete wave numbers that are shifted by the change in boundary condition. Next, calculations of optical absorption spectra are reported. Certain components of optical absorption for an electric field perpendicular to the polymer axis mix with absorption spectra for an electric field parallel to the polymer axis. Therefore, the polarization dependences of an electric field of light enable us to detect whether conjugated polymers have the Moebius boundary.Comment: 10 pages, 6 figures, to be published in J. Phys. Soc. Jpn., Vol. 74 No. 2 (February, 2005), Letter sectio

Embedding of fibre optic sensors within flexible host

This work deals with the establishment of a UV polymerisation procedure combined with moulding technology towards the development of a mass production technology for the fabrication of flexible polymers with optical fibres embedded. The concept is to provide an artificial sensing skin based on fibre optic sensors which can be applied to irregular or moveable surfaces for distributed pressure applications, as for instance in structural monitoring or rehabilitation. The selected polymers for such an application are here reviewed and their composition adjusted in order to accommodate the required flexibility. As compared to other techniques, UV polymerisation advantages are pointed out when moving towards industrial applications and large scale productions. Meanwhile, curing tests to embed optical fibres in the developed polymers are carried out with an in house developed glass mould set-up and the results are presented. Laser ablation of polymers is also discussed in order to reply the demand of complex fibre layout as for example meandering or curved shape patterns

Stiff Quantum Polymers

At ultralow temperatures, polymers exhibit quantum behavior, which is calculated here for the moments and of the end-to-end distribution in the large-stiffness regime. The result should be measurable for polymers in wide optical traps.Comment: 4 page

Molecules with enhanced electronic polarizabilities based on defect-like states in conjugated polymers

Highly conjugated organic polymers typically have large non-resonant electronic susceptibilities, which give the molecules unusual optical properties. To enhance these properties, defects are introduced into the polymer chain. Examples include light doping of the conjugated polymer and synthesis, conjugated polymers which incorporate either electron donating or accepting groups, and conjugated polymers which contain a photoexcitable species capable of reversibly transferring its electron to an acceptor. Such defects in the chain permit enhancement of the second hyperpolarizability by at least an order of magnitude

Ultraviolet and thermally stable polymer compositions

A new class of polymers is provided, namely, poly (diarylsiloxy) arylazines. These novel polymers have a basic chemical composition which has the property of stabilizing the optical and physical properties of the polymer against the degradative effect of ultraviolet light and high temperatures. This stabilization occurs at wavelengths including those shorter than found on the surface of the earth and in the absence or presence of oxygen, making the polymers useful for high performance coating applications in extraterrestrial space as well as similar applications in terrestrial service. The invention also provides novel aromatic azines which are useful in the preparation of polymers such as those described

Transmission and group delay of microring coupled-resonator optical waveguides

We measured the transmission and group delay of microring coupled-resonator optical waveguides (CROWs). The CROWs consisted of 12 weakly coupled, microring resonators fabricated in optical polymers (PMMA on Cytop). The intrinsic quality factor of the resonators was 18,000 and the interresonator coupling was 1%, resulting in a delay of 110-140 ps and a slowing factor of 23-29 over a 17 GHz bandwidth