Photoconductivity of CdS-CdSe granular films: influence of microstructure

We study experimentally the photoconductivity of CdS-CdSe sintered granular films obtained by the screen printing method. We mostly focus on the dependences of photoconductivity on film's microstructure, which varies with changing heat-treatment conditions. The maximum photoconductivity is found for samples with compact packing of individual grains, which nevertheless are separated by gaps. Such a microstructure is typical for films heat-treated during an intermediate (optimal) time. In order to understand whether the dominant mechanism of charge transfer is identical with the one in monocrystals, we perform temperature measurements of photoresistance. Corresponding curves have the same peculiar nonmonotonic shape as in CdSe monocrystals, from which we conclude that the basic mechanism is also the same. It is suggested that the optimal heat-treatment time appears as a result of a competition between two mechanisms: improvement of film's connectivity and its oxidation. Photoresistance is also measured in vacuum and in helium atmosphere, which suppress oxygen and water absorption/chemisorption at intergrain boundaries. We demonstrate that this suppression increases photoconductivity, especially at high temperatures.Comment: 12 pages, 8 figures, final versio

Brittleness of ceramics

The main characteristics of mechanical properties of ceramics are summarized and the causes of their brittleness, especially the limited mobility of dislocations, are discussed. The possibility of improving the fracture toughness of ceramics and the basic research needs relating to technology, structure and mechanical properties of ceramics are stressed in connection with their possible applications in engineering at high temperature

Novel vortex lattice transition in d-wave superconductors

We study the vortex state in a magnetic field parallel to the $c$ axis in the framework of the extended Ginzburg Landau equation. We find the vortex acquires a fourfold modulation proportional to $\cos(4\phi)$ where $\phi$ is the angle ${\bf r}$ makes with the $a$-axis. This term gives rise to an attractive interaction between two vortices when they are aligned parallel to $(1,1,0)$ or $(1,-1,0)$. We predict the first order vortex lattice transition at $B=H_{cr}\sim \kappa^{-1} H_{c2}(t)$ from triangular into the square lattice tilted by $45^\circ$ from the $a$ axis. This gives the critical field $H_{cr}$ a few Tesla for YBCO and Bi2212 monocrystals at low temperatures ($T\leq 10 K$).Comment: 6 pages, 4 figure