California Methanol Assessment; Volume II, Technical Report

A joint effort by the Jet Propulsion Laboratory and the California Institute of Technology Division of Chemistry and Chemical Engineering has brought together sponsors from both the public and private sectors for an analysis of the prospects for methanol use as a fuel in California, primarily for the transportation and stationary application sectors. Increasing optimism in 1982 for a slower rise in oil prices and a more realistic understanding of the costs of methanol production have had a negative effect on methanol viability in the near term (before the year 2000). Methanol was determined to have some promise in the transportation sector, but is not forecasted for large-scale use until beyond the year 2000. Similarly, while alternative use of methanol can have a positive effect on air quality (reducing NOx, SOx, and other emissions), a best case estimate is for less than 4% reduction in peak ozone by 2000 at realistic neat methanol vehicle adoption rates. Methanol is not likely to be a viable fuel in the stationary application sector because it cannot compete economically with conventional fuels except in very limited cases. On the production end, it was determined that methanol produced from natural gas will continue to dominate supply options through the year 2000, and the present and planned industry capacity is somewhat in excess of all projected needs. Nonsubsidized coal-based methanol cannot compete with conventional feedstocks using current technology, but coal-based methanol has promise in the long term (after the year 2000), providing that industry is willing to take the technical and market risks and that government agencies will help facilitate the environment for methanol. Given that the prospects for viable major markets (stationary applications and neat fuel in passenger cars) are unlikely in the 1980s and early 1990s, the next steps for methanol are in further experimentation and research of production and utilization technologies, expanded use as an octane enhancer, and selected fleet implementation. In the view of the study, it is not advantageous at this time to establish policies within California that attempt to expand methanol use rapidly as a neat fuel for passenger cars or to induce electric utility use of methanol on a widespread basis

A search for 95 GHz class I methanol masers in molecular outflows

We have observed a sample of 288 molecular outflow sources including 123 high-mass and 165 low-mass sources to search for class I methanol masers at 95 GHz transition and to investigate relationship between outflow characteristics and class I methanol maser emission with the PMO-13.7m radio telescope. Our survey detected 62 sources with 95 GHz methanol masers above 3$\sigma$ detection limit, which include 47 high-mass sources and 15 low-mass sources. Therefore the detection rate is 38% for high-mass outflow sources and 9% for low-mass outflow sources, suggesting that class I methanol maser is relatively easily excited in high-mass sources. There are 37 newly detected 95 GHz methanol masers (including 27 high-mass and 10 low-mass sources), 19 of which are newly identified (i.e. first identification) class I methanol masers (including 13 high-mass and 6 low-mass sources). Statistical analysis for the distributions of maser detections with the outflow parameters reveals that the maser detection efficiency increases with outflow properties (e.g. mass, momentum, kinetic energy and mechanical luminosity of outflows etc.). Systematic investigations of relationships between the intrinsic luminosity of methanol maser and the outflow properties (including mass, momentum, kinetic energy, bolometric luminosity and mass loss rate of central stellar sources) indicate a positive correlations. This further supports that class I methanol masers are collisionally pumped and associated with shocks, where outflows interact with the surrounding ambient medium.Comment: 32 pages, 5 figures, accepted by Ap

Evaporation and Discharge Dynamics of Highly Charged Multicomponent Droplets Generated by Electrospray Ionization

We investigate the Rayleigh discharge and evaporation dynamics of highly charged two-component droplets consisting principally of methanol with 2-methoxyethanol, tert-butanol, or m-nitrobenzyl alcohol. A phase Doppler anemometer (PDA) characterizes droplets generated by electrospray ionization (ESI) according to size, velocity, and charge as they move through a uniform electric field within an ion mobility spectrometer (IMS). Repeated field reversals result in droplet “ping-pong” through the PDA. This generates individual droplet histories of solvent evaporation behavior and the dynamics of charge loss to progeny droplets during Rayleigh discharge events. On average, methanol droplets discharge at 127% their Rayleigh limit of charge, q_R, and release 25% of the net charge. Charge loss from methanol/2-methoxyethanol droplets behaves similarly to pure 2-methoxyethanol droplets which release ~28% of their net charge. Binary methanol droplets containing up to 50% tert-butanol discharge at a lower percent q_R than pure methanol and release a greater fraction of their net charge. Mixed 99% methanol/1% m-nitrobenzyl alcohol droplets possess discharge characteristics similar to those of methanol. However, droplets of methanol containing 2% m-nitrobenzyl evaporate down to a fixed size and charge that remains constant with no observable discharges. Quasi-steady-state evaporation models accurately describe observed evaporation phenomena in which methanol/tert-butanol droplets evaporate at a rate similar to that of pure methanol and methanol/2-methoxyethanol droplets evaporate at a rate similar to that of 2-methoxyethanol. We compare these results to previous Rayleigh discharge experiments and discuss the implications for binary solvents in electrospray mass spectrometry (ESI-MS) and field-induced droplet ionization mass spectrometry (FIDI-MS)

The Liquidus Temperature for Methanol-Water Mixtures at High Pressure and Low Temperature, with Application to Titan

Methanol is a potentially important impurity in subsurface oceans on Titan and Enceladus. We report measurements of the freezing of methanol-water samples at pressures up to 350~MPa using a volumetric cell with sapphire windows. For low concentrations of methanol, the liquidus temperature is typically a few degrees below the corresponding ice freezing point, while at high concentrations it follows the pure methanol trend. In the Ice-III regime, we observe several long-lived metastable states. The results suggest that methanol is a more effective antifreeze than previously estimated, and might have played an important role in the development of Titan's subsurface ocean

Detection of abundant solid methanol toward young low mass stars

We present detections of the absorption band at 3.53 micron due to solid methanol toward three low-mass young stellar objects located in the Serpens and Chameleon molecular cloud complexes. The sources were observed as part of a large spectroscopic survey of ~40 protostars. This is the first detection of solid methanol in the vicinity of low mass (M <1 Msol) young stars and shows that the formation of methanol does not depend on the proximity of massive young stars. The abundances of solid methanol compared to water ice for the three sources are in the range 15-25% which is comparable to those for the most methanol-rich massive sources known. The presence of abundant methanol in the circumstellar environment of some low mass young stars has important consequences for the formation scenarios of methanol and more complex organic species near young solar-type stars.Comment: Accepted for publication in A&A letter

Exploiting of Wasted Cooking Oil at Making Biodiesel Through Transesterification Process with Applies K2CO3 Catalyst as Fuel Diesel of Renewable

This research aim is to know the influence from various USAge of K2CO3 catalyst and methanol solvent to biodiesel from wasted cooking oil. The making of biodiesel from waste cooking oil as raw material this before all was done by using esterification process with purpose to reduce %FFA >5% become < 5% with some help of the same solvent that is methanol and K2CO3 catalyst, then is continued to phase herein after is processing transesterification. The tranesterification process if wasted cooking oil in methanol to yield biodiesel applies alkaline catalyst. Sighting of % K2CO3 and methanol volume to product biodiesel need to be done to get product biodiesel fulfilling standart. Process tranesterification of wasted cooking oil using alkaline catalyst (K2CO3 ) and methanol solvent is done with various % K2CO3 that 0,1%, 1.0%, 1.5% and methanol equel to 15 ml, 20 ml , 25 ml. This research done by the way of mixing wasted cooking oil , methanol and K2CO3 in neck gourd four with operating condition 70 oC during 1 hour and result of his it's dissociated in separatory funnel then is hushed during 24 hour. From the research was received by the optimum condition in the use K2CO3 with concentration 0.5% wt and the volume of methanol 1250 ml. Result of the analysis of physical characteristics and chemistry biodiesel that was received % rendemen 56,07%, density 0,852 gr/ml, pH 7,1, acid number 0,53 of mgKOH, flashpoint 168 oC, % water content 0.03%, viscosity 3.09 cSt and calories value 6374.54 cal/gr. The biodiesel product that have got has been fulfill the Indonesian standard biodiesel quality

UV photodesorption of methanol in pure and CO-rich ices: desorption rates of the intact molecule and of the photofragments

Wavelength dependent photodesorption rates have been determined using synchrotron radiation, for condensed pure and mixed methanol ice in the 7 -- 14 eV range. The VUV photodesorption of intact methanol molecules from pure methanol ices is found to be of the order of 10$^{-5}$ molecules/photon, that is two orders of magnitude below what is generally used in astrochemical models. This rate gets even lower ($<$ 10$^{-6}$ molecules/photon) when the methanol is mixed with CO molecules in the ices. This is consistent with a picture in which photodissociation and recombination processes are at the origin of intact methanol desorption from pure CH$_3$OH ices. Such low rates are explained by the fact that the overall photodesorption process is dominated by the desorption of the photofragments CO, CH$_3$, OH, H$_2$CO and CH$_3$O/CH$_2$OH, whose photodesorption rates are given in this study. Our results suggest that the role of the photodesorption as a mechanism to explain the observed gas phase abundances of methanol in cold media is probably overestimated. Nevertheless, the photodesorption of radicals from methanol-rich ices may stand at the origin of the gas phase presence of radicals such as CH$_3$O, therefore opening new gas phase chemical routes for the formation of complex molecules.Comment: 13 pages, 2 figures, 1 tabl

The first high-resolution observations of 37.7-, 38.3- and 38.5-GHz methanol masers

We have used the Australia Telescope Compact Array (ATCA) to undertake the first high angular resolution observations of 37.7-GHz ($7_{-2} - 8_{-1}E$) methanol masers towards a sample of eleven high-mass star formation regions which host strong 6.7-GHz methanol masers. The 37.7-GHz methanol sites are coincident to within the astrometric uncertainty (0.4 arcseconds) with the 6.7-GHz methanol masers associated with the same star formation region. However, spatial and spectral comparison of the 6.7- and 37.7-GHz maser emission within individual sources shows that the 37.7-GHz masers are less often, or to a lesser degree co-spatial than are the 12.2-GHz and 6.7-GHz masers. We also made sensitive, high angular resolution observations of the 38.3- and 38.5-GHz class II methanol transitions ($6_{2} - 5_{3}A^{-}$ and $6_{2} - 5_{3}A^{+}$, respectively) and the 36.2-GHz ($4_{-1} - 3_{0}E$) class I methanol transition towards the same sample of eleven sources. The 37.7-, 38.3- and 38.5-GHz methanol masers are unresolved in the current observations, which implies a lower limit on the brightness temperature of the strongest masers of more than $10^6$K. We detected the 38.3-GHz methanol transition towards 7 sources, 5 of which are new detections and detected the 38.5-GHz transition towards 6 sources, 4 of which are new detections. We detected 36.2-GHz class I methanol masers towards all eleven sources, 6 of these are new detections for this transition, of which 4 sources do not have previously reported class I methanol masers from any transition.Comment: Accepted for publication in MNRAS, 34 pages, 20 figure

12.2-GHz methanol maser MMB follow-up catalogue - II. Longitude range 186 to 330 degrees

We present the second portion of a catalogue of 12.2-GHz methanol masers detected towards 6.7-GHz methanol masers observed in the unbiased Methanol Multibeam (MMB) Survey. Using the Parkes radio telescope we have targeted all 207 6.7-GHz methanol masers in the longitude range 186 to 330 degrees for 12.2-GHz counterparts. We report the detection of 83 12.2-GHz methanol masers, and one additional source which we suspect is thermal emission, equating to a detection rate of 40 per cent. Of the 83 maser detections, 39 are reported here for the first time. We discuss source properties, including variability and highlight a number of unusual sources. We present a list of 45 candidates that are likely to harbor methanol masers in the 107.0-GHz transition.Comment: Accepted MNRAS 19 July 201