A high-pressure premixed flat-flame burner for chemical process studies

A premixed flat-flame burner was designed and tested with methane-air mixtures at pressures from 1.1 to 20 atm and equivalence ratios from 0.7 to 1.1. Reactant velocity in the burner mixing chamber was used to characterize the range of stable flames at each pressure-equivalence-ratio condition. Color photographs of the flames were used to determine flame zone thickness and flame height. The results show that this burner can be used for chemical process studies in premixed high pressure methane-air flames up to 20 atm

Saturated laser fluorescence in turbulent sooting flames at high pressure

The primary objective was to develop a quantitative, single pulse, laser-saturated fluorescence (LSF) technique for measurement of radical species concentrations in practical flames. The species of immediate interest was the hydroxyl radical. Measurements were made in both turbulent premixed diffusion flames at pressures between 1 and 20 atm. Interferences from Mie scattering were assessed by doping with particles or by controlling soot loading through variation of equivalence ratio and fuel type. The efficacy of the LSF method at high pressure was addressed by comparing fluorescence and adsorption measurements in a premixed, laminar flat flame at 1-20 atm. Signal-averaging over many laser shots is sufficient to determine the local concentration of radical species in laminar flames. However, for turbulent flames, single pulse measurements are more appropriate since a statistically significant number of laser pulses is needed to determine the probability function (PDF). PDFs can be analyzed to give true average properties and true local kinetics in turbulent, chemically reactive flows

On the Structure and Stabilization Mechanisms of Planar and Cylindrical Premixed Flames

The configurational simplicity of the stationary one-dimensional flames renders them intrinsically attractive for fundamental flame structure studies. The possibility and fidelity of studies of such flames on earth, however, have been severely restricted by the unidirectional nature of the gravity vector. To demonstrate these complications, let us first consider the premixed flame. Here a stationary, one-dimensional flame can be established by using the flat-flame burner. We next consider nonpremixed flames. First it may be noted that in an unbounded gravity-free environment, the only stationary one-dimensional flame is the spherical flame. Indeed, this is a major motivation for the study of microgravity droplet combustion, in which the gas-phase processes can be approximated to be quasi-steady because of the significant disparity between the gas and liquid densities for subcritical combustion. In view of the above considerations, an experimental and theoretical program on cylindrical and spherical premixed and nonpremixed flames in microgravity has been initiated. For premixed flames, we are interested in: (1) assessing the heat loss versus flow divergence as the dominant stabilization mechanism; (2) determining the laminar flame speed by using this configuration; and (3) understanding the development of flamefront instability and the effects of the flame curvature on the burning intensity

Experimental and numerical investigations of the relation between OH* emission, flame speed and mass consumption rate

6 PagesWe investigate the relation between the intensity of the luminous emission of the excited OH* radical and the mass consumption rate of lean planar premixed methane-air flames. The flames were maintained perfectly flat using parametric acoustic stabilization in an imposed acoustic field. The consumption rate of the flames was varied by changing both the equivalence ratio and the temperature of the unburned mixture. We also compare our experimental measurements to the results of numerical simulations, using detailed chemical kinetics. For lean flames, we find that the OH* emission intensity is linear with mass consumption rate but, not proportional. Consequently, the relative fluctuation in mass consumption rate is not linearly related to the relative fluctuation in OH* emission intensity

Palomar 13: a velocity dispersion inflated by binaries ?

Recently, combining radial velocities from Keck/HIRES echelle spectra with published proper motion membership probabilities, Cote et al (2002) observed a sample of 21 stars, probable members of Palomar 13, a globular cluster in the Galactic halo. Their projected velocity dispersion sigma_p = 2.2 +/-0.4 km/s gives a mass-to-light ratio M/L_V = 40 +24/-17, about one order of magnitude larger than the usual estimate for globular clusters. We present here radial velocities measured from three different CCD frames of commissioning observations obtained with the new ESO/VLT instrument FLAMES (Fibre Large Array Multi Element Spectrograph). From these data, now publicly available, we measure the homogeneous radial velocities of eight probable members of this globular cluster. A new projected velocity dispersion sigma_p = 0.6-0.9 +/-0.3 km/s implies Palomar 13 mass-to-light ratio M/L_V = 3-7, similar to the usual value for globular clusters. We discuss briefly the two most obvious reasons for the previous unusual mass-to-light ratio finding: binaries, now clearly detected, and more homogeneous data from the multi-fibre FLAMES spectrograph.Comment: 9 pages, 2 Postscript figure

A transiting planet among 23 new near-threshold candidates from the OGLE survey - OGLE-TR-182

By re-processing the data of the second season of the OGLE survey for planetary transits and adding new mesurements on the same fields gathered in subsequent years with the OGLE telescope, we have identified 23 new transit candidates, recorded as OGLE-TR-178 to OGLE-TR-200. We studied the nature of these objects with the FLAMES/UVES multi-fiber spectrograph on the VLT. One of the candidates, OGLE-TR-182, was confirmed as a transiting gas giant planet on a 4-day orbit. We characterised it with further observations using the FORS1 camera and UVES spectrograph on the VLT. OGLE-TR-182b is a typical ``hot Jupiter'' with an orbital period of 3.98 days, a mass of 1.01 +- 0.15 MJup and a radius of 1.13 (+0.24-0.08) RJup. Confirming this transiting planet required a large investment in telescope time with the best instruments available, and we comment on the difficulty of the confirmation process for transiting planets in the OGLE survey. We delienate the zone were confirmation is difficult or impossible, and discuss the implications for the Corot space mission in its quest for transiting telluric planets.Comment: 7 pages, submitted to Astronomy and Astrophysic

Diamond films from combustion of methyl acetylene and propadiene

To date diamond films grown with the combustion technique have used either acetylene or, rarely, ethylene as the fuel. However, there are barriers to large scale commercialization of the combustion technique using either fuel. For example, acetylene is relatively expensive and difficult to handle, while the use of ethylene gives relatively low growth rates. In this letter we propose replacing acetylene with MAPPTM gas, a commercial mixture of methyl acetylene and propadiene in liquefied petroleum gas (primarily propylene). MAPP gas is considerably cheaper, safer, and easier to handle than acetylene. Furthermore, the experiments described here suggest that MAPP gas flames are only slightly less efficient than acetylene flames at converting fuel carbon atoms into diamond

Experimental Methodology for Estimation of Local Heat Fluxes and Burning Rates in Steady Laminar Boundary Layer Diffusion Flames.

Modeling the realistic burning behavior of condensed-phase fuels has remained out of reach, in part because of an inability to resolve the complex interactions occurring at the interface between gas-phase flames and condensed-phase fuels. The current research provides a technique to explore the dynamic relationship between a combustible condensed fuel surface and gas-phase flames in laminar boundary layers. Experiments have previously been conducted in both forced and free convective environments over both solid and liquid fuels. A unique methodology, based on the Reynolds Analogy, was used to estimate local mass burning rates and flame heat fluxes for these laminar boundary layer diffusion flames utilizing local temperature gradients at the fuel surface. Local mass burning rates and convective and radiative heat feedback from the flames were measured in both the pyrolysis and plume regions by using temperature gradients mapped near the wall by a two-axis traverse system. These experiments are time-consuming and can be challenging to design as the condensed fuel surface burns steadily for only a limited period of time following ignition. The temperature profiles near the fuel surface need to be mapped during steady burning of a condensed fuel surface at a very high spatial resolution in order to capture reasonable estimates of local temperature gradients. Careful corrections for radiative heat losses from the thermocouples are also essential for accurate measurements. For these reasons, the whole experimental setup needs to be automated with a computer-controlled traverse mechanism, eliminating most errors due to positioning of a micro-thermocouple. An outline of steps to reproducibly capture near-wall temperature gradients and use them to assess local burning rates and heat fluxes is provided

Laser Raman diagnostics in subsonic and supersonic turbulent jet diffusion flames

Ultraviolet (UV) spontaneous vibrational Raman scattering combined with laser-induced predissociative fluorescence (LIPF) is developed for temperature and multi-species concentration measurements. Simultaneous measurements of temperature, major species (H2, O2, N2, H2O), and minor species (OH) concentrations are made with a 'single' narrow band KrF excimer laser in subsonic and supersonic lifted turbulent hydrogen-air diffusion flames. The UV Raman system is calibrated with a flat-flame diffusion burner operated at several known equivalence ratios from fuel-lean to fuel-rich. Temperature measurements made by the ratio of Stokes/anti-Stokes signal and by the ideal gas law are compared. The single shot measurement precision for concentration and temperature measurement is 5 to 10 pct. Calibration constants and bandwidth factors are determined from the flat burner measurements and used in a data reduction program to arrive at temperature and species concentration measurements. These simultaneous measurements of temperature and multi-species concentrations allow a better understanding of the complex turbulence-chemistry interactions and provide information for the input and validation of CFD models