Analysis of products from the pyrolysis of plastics recovered from the commercial scale recycling of waste electrical and electronic equipment

Three plastic fractions from a commercial waste electrical and electronic equipment (WEEE) processing plant were collected and investigated for the possibility of recycling them by batch pyrolysis. The first plastic was from equipment containing cathode ray tubes (CRTs), the second plastic was from refrigeration equipment, and the third plastic was from mixed WEEE. Initially, the decomposition of each of the plastics was investigated using a TGA linked to a FT-ir spectrometer which showed that the CRT plastic decomposed to form aliphatic and aromatic compounds, the refrigerator plastic decomposed to form aldehydes, CO2, aromatic, and aliphatic compounds, and the mixed WEEE plastic decomposed to form aromatic and aliphatic compounds, CO2, and CO. Each plastic mixture was also pyrolysed in a batch reactor to determine the halogen and metal content of the pyrolysis products, additionally, characterisation of the pyrolysis oils was carried out by GC-MS and the pyrolysis gases by GC-FID and GC-TCD. It was found that the halogen content of the oils was relatively low but the halogen and metal content of the chars was high. The pyrolysis oils were found to contain valuable chemical products and the pyrolysis gases were mainly halogen free, making them suitable as a fuel

Stochastic Analysis of Synchronization in a Supermarket Refrigeration System

Display cases in supermarket systems often exhibit synchronization, in which the expansion valves in the display cases turn on and off at exactly the same time. The study of the influence of switching noise on synchronization in supermarket refrigeration systems is the subject matter of this work. For this purpose, we model it as a hybrid system, for which synchronization corresponds to a periodic trajectory. Subsequently, we investigate the influence of switching noise. We develop a statistical method for computing an intensity function, which measures how often the refrigeration system stays synchronized. By analyzing the intensity, we conclude that the increase in measurement uncertainty yields the decrease at the prevalence of synchronization.Comment: In Proceedings HAS 2014, arXiv:1501.0540

Super-heavy fermion material as metallic refrigerant for adiabatic demagnetization cooling

Low-temperature refrigeration is of crucial importance in fundamental research of condensed matter physics, as the investigations of fascinating quantum phenomena, such as superconductivity, superfluidity and quantum criticality, often require refrigeration down to very low temperatures. Currently, cryogenic refrigerators with $^3$He gas are widely used for cooling below 1 Kelvin. However, usage of the gas is being increasingly difficult due to the current world-wide shortage. Therefore, it is important to consider alternative methods of refrigeration. Here, we show that a new type of refrigerant, super-heavy electron metal, YbCo$_2$Zn$_{20}$, can be used for adiabatic demagnetization refrigeration, which does not require 3He gas. A number of advantages includes much better metallic thermal conductivity compared to the conventional insulating refrigerants. We also demonstrate that the cooling performance is optimized in Yb$_{1-x}$Sc$_x$Co$_2$Zn$_{20}$ by partial Sc substitution with $x\sim$0.19. The substitution induces chemical pressure which drives the materials close to a zero-field quantum critical point. This leads to an additional enhancement of the magnetocaloric effect in low fields and low temperatures enabling final temperatures well below 100 mK. Such performance has up to now been restricted to insulators. Since nearly a century the same principle of using local magnetic moments has been applied for adiabatic demagnetization cooling. This study opens new possibilities of using itinerant magnetic moments for the cryogen-free refrigeration

Cycling Joule Thomson refrigerator

A symmetrical adsorption pump/compressor system having a pair of mirror image legs and a Joule Thomson expander, or valve, interposed between the legs thereof for providing a, efficient refrigeration cycle is described. The system further includes a plurality of gas operational heat switches adapted selectively to transfer heat from a thermal load and to transfer or discharge heat through a heat projector, such as a radiator or the like. The heat switches comprise heat pressurizable chambers adapted for alternate pressurization in response to adsorption and desorption of a pressurizing gas confined therein

Experimental determination of the optimum working conditions of a transcritical CO2 refrigeration plant with integrated mechanical subcooling

Subcooling methods for transcritical CO2 plants are being studied in order to improve their behavior. Among them, the Integrated Mechanical Subcooling system is one of the most promising owing that performs with high efficiency and it is a total-CO2 system. This work presents the experimental determination of the optimum working conditions of a transcritical CO2 plant working with an integrated mechanical subcooling system. The plant was tested at different pressure and subcooling conditions in order to optimize the COP of the plant and determine the optimal conditions for three ambient temperatures 25.0 °C, 30.4 °C and 35.1 °C and evaporation levels between −15.6 °C and −4.1 °C. Optimum operating conditions were determined and two correlations are proposed to determine the optimal pressure and subcooling as function the gas-cooler outlet temperature and the evaporation level