Enhanced drag in pipe turbulent flow by an aqueous electrolyte: an electroviscous effect

Drag enhancement is reported for turbulent pipe flow of aqueous electrolyte solutions. No electroviscous effect was obtained with laminar flow. Nor was any unusual pressure drop observed for laminar or turbulent flow of non-electrolyte aqueous solutions such as sugar. An electroviscous theory was advanced that predicted the drag enhancement for a 1/1 electrolyte solution. The theory depended on consideration of Debye length

A shape-deformable and thermally stable solid-state electrolyte based on a plastic crystal composite polymer electrolyte for flexible/safer lithium-ion batteries

A solid-state electrolyte with reliable electrochemical performance, mechanical robustness and safety features is strongly pursued to facilitate the progress of flexible batteries. Here, we demonstrate a shape-deformable and thermally stable plastic crystal composite polymer electrolyte (denoted as "PC-CPE") as a new class of solid-state electrolyte to achieve this challenging goal. The PC-CPE is composed of UV (ultraviolet)-cured ethoxylated trimethylolpropane triacrylate (ETPTA) macromer/close-packed Al 2O3 nanoparticles (acting as the mechanical framework) and succinonitrile-mediated plastic crystal electrolyte (serving as the ionic transport channel). This chemical/structural uniqueness of the PC-CPE brings remarkable improvement in mechanical flexibility and thermal stability, as compared to conventional carbonate-based liquid electrolytes that are fluidic and volatile. In addition, the PC-CPE precursor mixture (i.e., prior to UV irradiation) with well-adjusted rheological properties, via collaboration with a UV-assisted imprint lithography technique, produces the micropatterned PC-CPE with tunable dimensions. Notably, the cell incorporating the self-standing PC-CPE, which acts as a thermally stable electrolyte and also a separator membrane, maintains stable charge/discharge behavior even after exposure to thermal shock condition (=130 ??C/0.5 h), while a control cell assembled with a carbonate-based liquid electrolyte and a polyethylene separator membrane loses electrochemical activity.close1

Inappropriate electrolyte repletion for patients undergoing endoscopic procedures

At Thomas Jefferson University Hospital (TJUH), there has been a perceived necessity among housestaff and fellows to routinely check and replete serum potassium and magnesium for inpatients prior to endoscopic procedures In addition, there was an unwritten policy that these electrolytes needed to be aggressively repleted, with a goal potassium above 4.0 and magnesium above 2.0 Contributing factors include absence of clear policy, fear of adverse outcomes during procedures, and fear of delay of procedures leading to increased hospital stay This practice has led to unwarranted lab draws, costs of lab tests and electrolyte riders, and possible delayed procedures Goals Clarify policies regarding electrolyte repletion Determine frequency of inappropriate electrolyte checking and repletion Determine monetary cost of this action Decrease frequency of inappropriate electrolyte lab check and repletionhttps://jdc.jefferson.edu/patientsafetyposters/1023/thumbnail.jp

Review on Multi-Scale Models of Solid-Electrolyte Interphase Formation

Electrolyte reduction products form the solid-electrolyte interphase (SEI) on negative electrodes of lithium-ion batteries. Even though this process practically stabilizes the electrode-electrolyte interface, it results in continued capacity-fade limiting lifetime and safety of lithium-ion batteries. Recent atomistic and continuum theories give new insights into the growth of structures and the transport of ions in the SEI. The diffusion of neutral radicals has emerged as a prominent candidate for the long-term growth mechanism, because it predicts the observed potential dependence of SEI growth.Comment: 8 pages, 4 figure

Solid electrolyte cell

A solid electrolyte cell including a body of solid ionized gas-conductive electrolyte having mutually spaced surfaces and on which is deposited a multiplicity of mutually spaced electrodes is described. Strips and of bare substances are interposed between electrodes, so that currents of ionic gas may be established between the electrodes via the bare strips, whereby electrical resistance for the cells is lowered and the gas conductivity is enhanced

Improved silver-zinc battery-terminal seals

Development of battery terminal seal for sealing electrolyte for periods of three to five years is discussed. Operating conditions of battery are defined. Components of electrolyte seal and method of production are reported. Schematic diagrams of device are included

Electrostatic depletion forces between planar surfaces

The interaction between two dielectric plates immersed in an electrolyte solution is examined by using a variational perturbation approximation for the grand partition function. This approach differs from previous treatments in that the screening length between the plates is treated as a variational parameter. A key finding is that adjacent to each plate is a layer of ion depletion with thickness given by about one-half of a Bjerrum length. Consequently, for plate-plate separations less than the Bjerrum length, nearly all the electrolyte is excluded from between the plates, and the interaction is given by the sum of a van der Waals interaction and an attractive osmotic depletion force. In contrast to the predictions of previous theories, the interaction between the plates at short range increases with increasing electrolyte concentration and may provide an important contribution to the salt-induced attraction, commonly referred to as salting out. Because the range of the osmotic depletion force is roughly equal to the Bjerrum length, it increases with the square of the valency of the electrolyte. At larger plate-plate separations, the van der Waals interaction is screened as electrolyte enters the space between the plates, leading to an exponential decay of the interactions, as has been previously observed. However, this interaction is slightly stronger than that previously predicted, due to ion depletion from the surface of the interface, also this effect increases with increasing electrolyte concentration