Tuning Nanocrystal Surface Depletion by Controlling Dopant Distribution as a Route Toward Enhanced Film Conductivity

Electron conduction through bare metal oxide nanocrystal (NC) films is hindered by surface depletion regions resulting from the presence of surface states. We control the radial dopant distribution in tin-doped indium oxide (ITO) NCs as a means to manipulate the NC depletion width. We find in films of ITO NCs of equal overall dopant concentration that those with dopant-enriched surfaces show decreased depletion width and increased conductivity. Variable temperature conductivity data shows electron localization length increases and associated depletion width decreases monotonically with increased density of dopants near the NC surface. We calculate band profiles for NCs of differing radial dopant distributions and, in agreement with variable temperature conductivity fits, find NCs with dopant-enriched surfaces have narrower depletion widths and longer localization lengths than those with dopant-enriched cores. Following amelioration of NC surface depletion by atomic layer deposition of alumina, all films of equal overall dopant concentration have similar conductivity. Variable temperature conductivity measurements on alumina-capped films indicate all films behave as granular metals. Herein, we conclude that dopant-enriched surfaces decrease the near-surface depletion region, which directly increases the electron localization length and conductivity of NC films

C.V.D. annual report: November 1965 research project RU27-1 :an analogue method for the determination of potential distributions in semiconductor systems

A general method for the solution of the nonlinear Shockley-Poisson differential equation which governs the potential distribution in non-degenerate semiconductor systems is described which can be applied to the evaluation of depletion layer widths, carrier densities and capacitance bias relationships of p-n junction structures. The method is based upon the use of a particular type of resistance network analogue and results obtained for several one and two dimensional configurations are discussed

A Test Of Pre-Main-Sequence Lithium Depletion Models

Despite the extensive study of lithium depletion during pre-main-sequence (PMS) contraction, studies of individual stars show discrepancies between ages determined from the Hertzsprung-Russell (H-R) diagram and ages determined from lithium depletion, indicating open questions in the PMS evolutionary models. To further test these models, we present high-resolution spectra for members of the beta Pictoris Moving Group (BPMG), which is young and nearby. We measure equivalent widths of the 6707.8 angstrom Li I line in these stars and use them to determine lithium abundances. We combine the lithium abundance with the predictions of PMS evolutionary models in order to calculate a lithium depletion age for each star. We compare this age to the age predicted by the H-R diagram of the same model. We find that the evolutionary models underpredict the amount of lithium depletion for the BPMG given its nominal H-R diagram age of similar to 12 Myr, particularly for the mid-M stars, which have no observable Li I line. This results in systematically older ages calculated from lithium depletion isochrones than from the H-R diagram. We suggest that this discrepancy may be related to the discrepancy between measured M-dwarf radii and the smaller radii predicted by evolutionary models

A Test of Pre-Main-Sequence Lithium Depletion Models

Despite the extensive study of lithium depletion during pre-main-sequence contraction, studies of individual stars show discrepancies between ages determined from the HR diagram and ages determined from lithium depletion (Song et al. 2002, White & Hillenbrand 2005) indicating open questions in the pre-main-sequence evolutionary models. To further test these models, we present high resolution spectra for members of the Beta Pictoris Moving Group (BPMG), which is young and nearby. We measure equivalent widths of the 6707.8 Angstrom Li I line in these stars and use them to determine lithium abundances. We combine the lithium abundance with the predictions of pre-main-sequence evolutionary models in order to calculate a lithium depletion age for each star. We compare this age to the age predicted by the HR diagram of the same model. We find that the evolutionary models under-predict the amount of lithium depletion for the BPMG given its nominal HR diagram age of ~12 Myr (Zuckerman et al. 2001), particularly for the mid-M stars, which have no observable Li I line. This results in systematically older ages calculated from lithium depletion isochrones than from the HR diagram. We suggest that this discrepancy may be related to the discrepancy between measured M-dwarf radii and the smaller radii predicted by evolutionary models.Comment: Accepted by ApJ; 21 pages, 5 figure

Effect of polymer-polymer interactions on the surface tension of colloid-polymer mixtures

The density profile and surface tension for the interface of phase-separated colloid-polymer mixtures have been studied in the framework of the square gradient approximation for both ideal and interacting polymers in good solvent. The calculations show that in the presence of polymer-polymer excluded volume interactions the interfaces have lower widths and surface tensions compared to the case of ideal polymers. These results are a direct consequence of the shorter range and smaller depth of the depletion potential between colloidal particles induced by interacting polymers.Comment: 12 pages, 5 figures, accepted for J. Chem. Phy

Observational signatures for depletion in the Spite plateau: solving the cosmological Li discrepancy?

We present Li abundances for 73 stars in the metallicity range -3.5 < [Fe/H] < -1.0 using improved IRFM temperatures (Casagrande et al. 2010) with precise E(B-V) values obtained mostly from interstellar NaI D lines, and high-quality equivalent widths (errors ~ 3%). At all metallicities we uncover a fine-structure in the Li abundances of Spite plateau stars, which we trace to Li depletion that depends on both metallicity and mass. Models including atomic diffusion and turbulent mixing seem to reproduce the observed Li depletion assuming a primordial Li abundance ALi = 2.64 dex (MARCS models) or 2.72 (Kurucz overshooting models), in good agreement with current predictions (ALi = 2.72) from standard BBN. We are currently expanding our sample to have a better coverage of different evolutionary stages at the high and low metallicity ends, in order to verify our findings.Comment: In press, Light elements in the Universe, Proceedings IAU Symposium No. 268, 2010. C. Charbonnel, M. Tosi, F. Primas & C. Chiappini, ed

Ultralight boson cloud depletion in binary systems

Ultralight scalars can extract rotational energy from astrophysical black holes through superradiant instabilities, forming macroscopic boson clouds. This process is most efficient when the Compton wavelength of the boson is comparable to the size of the black hole horizon, i.e. when the "gravitational fine structure constant" $\alpha\equiv G \mu M/\hbar c\sim 1$. If the black hole/cloud system is in a binary, tidal perturbations from the companion can produce resonant transitions between the energy levels of the cloud, depleting it by an amount that depends on the nature of the transition and on the parameters of the binary. Previous cloud depletion estimates considered binaries in circular orbit and made the approximation $\alpha\ll 1$. Here we use black hole perturbation theory to compute instability rates and decay widths for generic values of $\alpha$, and we show that this leads to much larger cloud depletion estimates when $\alpha \gtrsim 0.1$. We also study eccentric binary orbits. We show that in this case resonances can occur at all harmonics of the orbital frequency, significantly extending the range of frequencies where cloud depletion may be observable with gravitational wave interferometers.Comment: 12 pages, 6 figures. v2: references added, matches published versio

Stellar Mixing and the Primordial Lithium Abundance

We compare the properties of recent samples of the lithium abundances in halo stars to one another and to the predictions of theoretical models including rotational mixing, and we examine the data for trends with metal abundance. We find from a KS test that in the absence of any correction for chemical evolution, the Ryan, Norris, & Beers (1999} sample is fully consistent with mild rotational mixing induced depletion and, therefore, with an initial lithium abundance higher than the observed value. Tests for outliers depend sensitively on the threshold for defining their presence, but we find a 10$--$45% probability that the RNB sample is drawn from the rotationally mixed models with a 0.2 dex median depletion (with lower probabilities corresponding to higher depletion factors). When chemical evolution trends (Li/H versus Fe/H) are treated in the linear plane we find that the dispersion in the RNB sample is not explained by chemical evolution; the inferred bounds on lithium depletion from rotational mixing are similar to those derived from models without chemical evolution. We find that differences in the equivalent width measurements are primarily responsible for different observational conclusions concerning the lithium dispersion in halo stars. The standard Big Bang Nucleosynthesis predicted lithium abundance which corresponds to the deuterium abundance inferred from observations of high-redshift, low-metallicity QSO absorbers requires halo star lithium depletion in an amount consistent with that from our models of rotational mixing, but inconsistent with no depletion.Comment: 39 pages, 9 figures; submitted Ap