Canopy uptake dominates nighttime carbonyl sulfide fluxes in a boreal forest

Nighttime vegetative uptake of carbonyl sulfide (COS) can exist due to the incomplete closure of stomata and the light independence of the enzyme carbonic anhydrase, which complicates the use of COS as a tracer for gross primary productivity (GPP). In this study we derived nighttime COS fluxes in a boreal forest (the SMEAR II station in Hyytiälä, Finland; 61°51′ N, 24°17′ E; 181 m a.s.l.) from June to November 2015 using two different methods: eddy-covariance (EC) measurements (FCOS-EC) and the radon-tracer method (FCOS-Rn). The total nighttime COS fluxes averaged over the whole measurement period were −6.8 ± 2.2 and −7.9 ± 3.8 pmol m−2 s−1 for FCOS-Rn and FCOS-EC, respectively, which is 33–38 % of the average daytime fluxes and 21 % of the total daily COS uptake. The correlation of 222Rn (of which the source is the soil) with COS (average R2  =  0.58) was lower than with CO2 (0.70), suggesting that the main sink of COS is not located at the ground. These observations are supported by soil chamber measurements that show that soil contributes to only 34–40 % of the total nighttime COS uptake. We found a decrease in COS uptake with decreasing nighttime stomatal conductance and increasing vapor-pressure deficit and air temperature, driven by stomatal closure in response to a warm and dry period in August. We also discuss the effect that canopy layer mixing can have on the radon-tracer method and the sensitivity of (FCOS-EC) to atmospheric turbulence. Our results suggest that the nighttime uptake of COS is mainly driven by the tree foliage and is significant in a boreal forest, such that it needs to be taken into account when using COS as a tracer for GPP

Stomatal control of leaf fluxes of carbonyl sulfide and CO₂ in a <i>Typha</i> freshwater marsh

Carbonyl sulfide (COS) is an emerging tracer to constrain land photosynthesis at canopy to global scales, because leaf COS and CO2 uptake processes are linked through stomatal diffusion. The COS tracer approach requires knowledge of the concentration normalized ratio of COS uptake to photosynthesis, commonly known as the leaf relative uptake (LRU). LRU is known to increase under low light, but the environmental controls over LRU variability in the field are poorly understood due to scant leaf scale observations.Here we present the first direct observations of LRU responses to environmental variables in the field. We measured leaf COS and CO2 fluxes at a freshwater marsh in summer 2013. Daytime leaf COS and CO2 uptake showed similar peaks in the mid-morning and late afternoon separated by a prolonged midday depression, highlighting the common stomatal control on diffusion. At night, in contrast to CO2, COS uptake continued, indicating partially open stomata. LRU ratios showed a clear relationship with photosynthetically active radiation (PAR), converging to 1.0 at high PAR, while increasing sharply at low PAR. Daytime integrated LRU (calculated from daytime mean COS and CO2 uptake) ranged from 1 to 1.5, with a mean of 1.2 across the campaign, significantly lower than the previously reported laboratory mean value (∼ 1.6). Our results indicate two major determinants of LRU – light and vapor deficit. Light is the primary driver of LRU because CO2 assimilation capacity increases with light, while COS consumption capacity does not. Superimposed upon the light response is a secondary effect that high vapor deficit further reduces LRU, causing LRU minima to occur in the afternoon, not at noon. The partial stomatal closure induced by high vapor deficit suppresses COS uptake more strongly than CO2 uptake because stomatal resistance is a more dominant component in the total resistance of COS. Using stomatal conductance estimates, we show that LRU variability can be explained in terms of different patterns of stomatal vs. internal limitations on COS and CO2 uptake. Our findings illustrate the stomata-driven coupling of COS and CO2 uptake during the most photosynthetically active period in the field and provide an in situ characterization of LRU – a key parameter required for the use of COS as a photosynthetic tracer

Angular Distribution of Decay Leptons from e^+e^- \to W^+W^- at Threshold

The reaction $e^+e^- \to W^+W^-$ produces a $W$-boson pair with a non-trivial spin correlation at threshold. This correlation leads to a characteristic angular correlation between the leptons produced in $W^{\pm} \to \ell ^{\pm} \nu$ (angles relative to the $e^-$ beam direction): $d \sigma /d \cos \theta_+ d \cos \theta_- \sim (1-\cos \theta_+) (1+ \cos \theta_-) (1+\cos \theta_- \cos \theta_+)$ . If only the $\ell^-$ is observed, its angular distribution is $d \sigma / d \cos \theta_- \sim (1+\cos \theta_-)(3-\cos \theta_-)$, implying a forward-backward asymmetry of 3/8. An analytic result is also given for the azimuthal correlation. These results are reproduced by a Monte Carlo program, that also enables us to study the effects of the $W$ decay width. The threshold behaviour, which stems from the dominance of $\nu$-exchange, is contrasted with that due to $\gamma$- and $Z$-exchange, which is relevant for annihilation in the helicity state $e^-_Re^+_L$.Comment: 10 pages, 6 figures, LaTeX, simpler derivation of main results, also added a comparison with Monte Carlo expectation

Limits on the use of cobalt sulfide as anode of p-type dye-sensitized solar cells

Thin films of cobalt sulfide (CoS) of thickness l &lt; 10m have been employed as anodes of p-type dye-sensitized solar cells (p-DSCs) when P1-sensitized nickel oxide (NiO) was the photoactive cathode and /I - constituted the redox mediator. In the role of counter electrode for p-DSCs, CoS was preferred over traditional platinized fluorine-doped indium oxide (Pt-FTO) due to the lower cost of the starting materials (Co salts) and the easier procedure of deposition onto large area substrates. The latter process was carried out via direct precipitation of CoS from aqueous solutions. The photoconversion efficiency (η) of the corresponding device was 0.07%. This value is about 35% less than the efficiency that is obtained with the analogous p-DSC employing the Pt-FTO anode (η = 0.11). Unlike p-DSCs based on Pt-FTO anodes, the photoelectrochemical cells employing CoS electrodes showed that this anodic material was not able to sustain the photocurrent densities generated by P1-sensitized NiO at a given photopotential. Illumination of the p-DSCs with CoS anodes and P1-sensitized NiO cathodes actually induced the reverse bias of the photoelectrochemical cell with CoS behaving like a p-type semiconductor with no degeneracy. © 2017 IOP Publishing Ltd

Parameterization of Pontecorvo-Maki-Nakagawa-Sakata mixing matrix based on CP-violating bipair neutrino mixing

CP violation in neutrino interactions is described by three phases contained in Pontecorvo-Maki-Nakagawa-Sakata mixing matrix ($U_{PMNS}$). We argue that the phenomenologocally consistent result of the Dirac CP violation can be obtained if $U_{PMNS}$ is constructed along bipair neutrino mixing scheme, namely, requiring that $| U_{12} | = | U_{32} | {\rm and} | U_{22} | = | U_{23} | (\rm case 1)$ and $| U_{12} | = | U_{22} | {\rm and} | U_{32} | = | U_{33}| (\rm case 2)$, where $U_{ij}$ stands for the $i$-$j$ matrix element of $U_{PMNS}$. As a results, the solar, atmospheric and reactor neutrino mixing angles $\theta_{12}$, $\theta_{23}$ and $\theta_{13}$, respectively, are correlated to satisfy $\cos 2{\theta_{12}} = \sin^2\theta_{23} - \tan^2\theta_{13}$ (case 1) or $\cos 2{\theta_{12}} = \cos^2\theta_{23} - \tan^2\theta_{13}$ (case 2). Furthermore, if Dirac CP violation is observed to be maximal, $\theta_{23}$ is determined by $\theta_{13}$ to be: $\sin^2\theta_{23} \approx ({\sqrt 2 - 1})({\cos^2\theta_{13} + \sqrt 2 \sin^2\theta_{13}})$ (case 1) or $\cos^2\theta_{23} \approx ({\sqrt 2 - 1})({\cos^2\theta_{13} + \sqrt 2 \sin^2\theta_{13}})$ (case 2). For the case of non-maximal Dirac CP violation, we perform numerical computation to show relations between the CP-violating Dirac phase and the mixing angles.Comment: 7 pages, 3 figures, version to appear in Modern Physics Letters

That is how we do it around here: Levels of identification, masculine honor, and social activism against organized crime in the south of Italy

Masculine honor is an important cultural code in the south of Italy. Italian criminal organizations (COs) manipulate and exploit this code to maintain legitimacy among local populations and exert social control in the territory where they operate. This research tested the hypothesis that different levels of identification—the region and the nation—would have opposite associations with male honor-related values and, indirectly, with intentions to oppose COs collectively. Results from a sample of young southern Italians (N?=?170) showed that regional identification positively predicted endorsement of male honor-related values, which in turn were associated with lowered intentions to oppose COs. In contrast, national identification negatively predicted male honor-related values, associated in turn with stronger intentions to oppose COs. These results also held when perceived risk and social dominance orientation were taken into account. Directions for future research are discussed

Coal desulfurization

Organic sulfur is removed from coal by treatment with an organic solution of iron pentacarbonyl. Organic sulfur compounds can be removed by reaction of the iron pentacarbonyl with coal to generate CO and COS off-gases. The CO gas separated from COS can be passed over hot iron fillings to generate iron pentacarbonyl