Supported ITZ modification efficiencies via surface coating nanoparticles on aggregate and its influence on properties

In order to modify the porous interfacial transition zone (ITZ) microstructure of concrete more efficiently, a method of coating aggregate surfaces by using several nanoparticles was evaluated in this study. The compressive strength, chloride penetration of sound, and pre-loading samples were assessed in relation to the type of coating materials used (slag, nano-CaCO3, and nano-SiO2) and the designed coating thickness (5, 10, and 15 mu m). The ITZ microstructure was quantitatively determined via Backscattered electron (BSE) image analysis. Results showed that the overall performance of concrete is highly dependent on the coating materials and the designed coating thickness. Increasing the coating thickness of slag and nano-SiO2 could improve the chloride penetration resistance but decrease the compressive strength. Using nano-CaCO3 to coat the aggregate leads to a significant reduction in the properties of the so-prepared concrete. Though coating inert fine particles around aggregate could disturb the initial particle packing and modify the ITZ, it is not able to improve the overall concrete properties. Coating aggregate could determine the ITZ microstructure, especially within the region that is around 30 mu m away from aggregate surface

Effect of biocomposite edible coatings based on pea starch and guar gum on nutritional quality of ‘Valencia’ orange during storage

Application of environmentally friendly components is an approach for substitution of synthetic substances in commercial waxes applied to citrus. In this study, the effect of biocomposite edible coatings based on pea starch and guar gum (PSGG) on total vitamin C, phenolic, flavonoid, anthocyanins, and carotenoid content, and antioxidant capacity of ‘Valencia’ orange stored at 5 °C and 20 °C for four weeks were evaluated. The fruits were coated by a single layer PSGG coating, blended composite PSGG coating containing shellac (Sh) and oleic acid as hydrophobic compounds (PSGG-Sh), and a layer-by-layer (LBL) coating (PSGG as an internal layer and Sh as an external layer). The results showed no significant differences in changes of bioactive compounds between coating treatments after first week storage at both temperatures. The PSGG coatings incorporated with hydrophobic compounds (PSGG-Sh) better preserved the nutritional value and the antioxidant potential of oranges during storage compared with other treatments. The single layer PSGG coating was almost similar to bilayer coating in preserving nutritional value of fruit during storage and less effective than the blended composite PSGG-Sh coating

Advanced protective coating for superalloys

Superior oxidation protection for nickel-base alloys at temperatures up to 1367 K was obtained with cobalt-base alloy coating. Coating had 25 Cr, 14 Al, and 0.5 Y weight percent composition. Coating was applied by electron beam vapor deposition to thickness of 76 to 127 microns

Method of protecting a surface with a silicon-slurry/aluminide coating

A low cost coating for protecting metallic base system substrates from high temperatures, high gas velocity oxidation, thermal fatigue and hot corrosion is described. The coating is particularly useful for protecting vanes and blades in aircraft and land based gas turbine engines. A lacquer slurry comprising cellulose nitrate containing high purity silicon powder is sprayed onto the superalloy substrates. The silicon layer is then aluminized to complete the coating. The Si-Al coating is less costly to produce than advanced aluminides and protects the substrate from oxidation and thermal fatigue for a much longer period of time than the conventional aluminide coatings. While more expensive Pt-Al coatings and physical vapor deposited MCrAlY coatings may last longer or provide equal protection on certain substrates, the Si-Al coating exceeded the performance of both types of coatings on certain superalloys in high gas velocity oxidation and thermal fatigue. Also, the Si-Al coating increased the resistance of certain superalloys to hot corrosion

Mechanical behavior of thermal barrier coatings for gas turbine blades

Plasma-sprayed thermal barrier coatings (TBCs) will enable turbine components to operate at higher temperatures and lower cooling gas flow rates; thereby improving their efficiency. Future developments are limited by precise knowledge of the material properties and failure mechanisms of the coating system. Details of this nature are needed for realistic modeling of the coating system which will, in turn, promote advancements in coating technology. Complementary experiments and analytical modeling which were undertaken in order to define and measure the important failure processes for plasma-sprayed coatings are presented. The experimental portion includes two different tests which were developed to measure coating properties. These are termed tensile adhesion and acoustic emission tests. The analytical modeling section details a finite element method which was used to calculate the stress distribution in the coating system. Some preliminary results are presented

Sliding wear of a-C:H coatings against alumina in corrosive media

This paper reports the results obtained from the study of friction and sliding wear in two corrosive solutions of an a-C:H coating deposited on 316L stainless against an alumina ball, employed as static counter part. Calculations of the values of the von Mises stresses developed at the coating–substrate interface, as soon as the ball touches the coated sample, and how this state of stress influences the response of the coated system under the corrosion environment, are presented and discussed. The results obtained from these calculations, as well as from the experiments conducted in the present research, are compared with other experiments published in the literature, where a-C:H coatings deposited on different substrates and with different coating architectures were tested in similar corrosive media. It has been determined that in those systems, where the von Mises stress in the coating, found in the vicinity of the interface, exceeds the threshold value of approximately 370MPa, coating failure with spallation will take place, regardless of the substrate nature on which this coating has been deposited. From this analysis it has been concluded that the coating yield strength is of utmost importance in conferring the a-C:H coated system there quired stability in a corrosive solution

Ammonia sensing using lossy mode resonances in a tapered optical fibre coated with porphyrin-incorporated titanium dioxide

The development of an ammonia sensor, formed by the deposition of a functionalised titanium dioxide film onto a tapered optical fibre is presented. The titanium dioxide coating allows the coupling of light from the fundamental core mode to a lossy mode supported by the coating, thus creating lossy mode resonance (LMR) in the transmission spectrum. The porphyrin compound that was used to functionalise the coating was removed from the titanium dioxide coating upon exposure to ammonia, causing a change in the refractive index of the coating and a concomitant shift in the central wavelength of the lossy mode resonance. Concentrations of ammonia as small as 1ppm was detected with a response time of less than 1min. © (2016) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only

Integrating-sphere coating

Sodium chloride, used with proper solvent-dispersant combination, forms very durable reflective coatings. Several other inorganic salts, such as barium sulfate, barium carbonate, sodium fluoride, potassium chloride, sodium hexafluorosilicate, and aluminum oxide, are also suitable. Sodium chloride may also be used with other formulations to produce same type of coating

Sorption-induced Static Bending of Microcantilevers Coated with Viscoelastic Material

Absorption of a chemical analyte into a polymercoating results in an expansion governed by the concentration and type of analyte that has diffused into the bulk of the coating. When the coating is attached to a microcantilever, this expansion results in bending of the device. Assuming that absorption (i.e., diffusion across the surface barrier into the bulk of the coating) is Fickian, with a rate of absorption that is proportional to the difference between the absorbed concentration and the equilibrium concentration, and the coating is elastic, the bending response of the coated device should exhibit a first-order behavior. However, for polymercoatings, complex behaviors exhibiting an overshoot that slowly decays to the steady-state value have been observed. A theoretical model of absorption-induced static bending of a microcantilever coated with a viscoelastic material is presented, starting from the general stress/strain relationship for a viscoelastic material. The model accounts for viscoelasticstress relaxation and possible coating plasticization. Calculated responses show that the model is capable of reproducing the same transient behavior exhibited in the experimental data. The theory presented can also be used for extracting viscoelasticproperties of the coating from the measured bending data

White primer permits a corrosion-resistant coating of minimum weight

White primer for coating 2219 aluminum alloy supplies a base for a top coating of enamel. A formulation of pigments and vehicle results in a primer with high corrosion resistance and minimum film thickness