118 research outputs found
Bonding in MgSi and AlMgSi Compounds Relevant to AlMgSi Alloys
The bonding and stability of MgSi and AlMgSi compounds relevant to AlMgSi
alloys is investigated with the use of (L)APW+(lo) DFT calculations. We show
that the and phases found in the precipitation sequence are
characterised by the presence of covalent bonds between Si-Si nearest neighbour
pairs and covalent/ionic bonds between Mg-Si nearest neighbour pairs. We then
investigate the stability of two recently discovered precipitate phases, U1 and
U2, both containing Al in addition to Mg and Si. We show that both phases are
characterised by tightly bound Al-Si networks, made possible by a transfer of
charge from the Mg atoms.Comment: 11 pages, 30 figures, submitted to Phys. Rev.
Physical properties of Thallium-Tellurium based thermoelectric compounds using first-principles simulations
We present a study of the thermodynamic and physical properties of Tl5Te3,
BiTl9Te6 and SbTl9Te6 compounds by means of density functional theory based
calculations. The optimized lattice constants of the compounds are in good
agreement with the experimental data. The electronic density of states and band
structures are calculated to understand the bonding mechanism in the three
compounds. The indirect band gap of BiTl9Te6 and SbTl9Te6 compounds are found
to be equal to 0.256 eV and 0.374 eV, respectively. The spin-orbit coupling has
important effects on the electronic structure of the two semiconducting
compounds and should therefore be included for a good numerical description of
these materials. The elastic constants of the three compounds have been
calculated, and the bulk modulus, shear modulus, and young's modulus have been
determined. The change from ductile to brittle behavior after Sb or Bi alloying
is related to the change of the electronic properties. Finally, the Debye
temperature, longitudinal, transverse and average sound velocities have been
obtained
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