Modelling and simulation framework for reactive transport of organic contaminants in bed-sediments using a pure java object - oriented paradigm

Numerical modelling and simulation of organic contaminant reactive transport in the environment is being increasingly relied upon for a wide range of tasks associated with risk-based decision-making, such as prediction of contaminant profiles, optimisation of remediation methods, and monitoring of changes resulting from an implemented remediation scheme. The lack of integration of multiple mechanistic models to a single modelling framework, however, has prevented the field of reactive transport modelling in bed-sediments from developing a cohesive understanding of contaminant fate and behaviour in the aquatic sediment environment. This paper will investigate the problems involved in the model integration process, discuss modelling and software development approaches, and present preliminary results from use of CORETRANS, a predictive modelling framework that simulates 1-dimensional organic contaminant reaction and transport in bed-sediments

Riverine transfer of heavy metals from Patagonia to the southwestern Atlantic Ocean

The occurrence and geochemical behaviour of Fe, Mn, Pb, Cu, Ni, Cr, Zn and Co are studied in riverine detrital materials transported by Patagonian rivers. Their riverine inputs have been estimated and the nature of these inputs to the Atlantic Ocean is discussed. Most of the metals are transported to the ocean via the suspended load; there is evidence that Fe oxides and organic matter are important phases controlling their distribution in the detrital non-residual fraction. Most heavy metal concentrations found in bed sediments, in suspended matter, and in the dissolved load of Patagonian rivers were comparable to those reported for non-polluted rivers. There is indication that human activity is altering riverine metal inputs to the ocean. In the northern basins – and indicatinganthropogenic effects – heavy metals distribution in the suspended load is very different from that found in bed sediments. The use of pesticides in the Negro River valley seems correlated with increased riverine input of Cu, mostly bound to the suspended load. The Deseado and Chico Rivers exhibit increased specific yield of metals as a consequence of extended erosion within their respective basins. The Santa Cruz is the drainage basin least affected by human activity and its metal-exporting capacity should be taken as an example of a relatively unaffected large hydrological system. In contrast, coal mining modifies the transport pattern of heavy metals in the Gallegos River, inasmuch as they are exported to the coastal zone mainly as dissolved load

Estimating specific surface area of fine stream bed sediments from geochemistry

Specific surface area (SSA) of headwater stream bed sediments is a fundamental property which determines the nature of sediment surface reactions and influences ecosystem-level, biological processes. Measurements of SSA – commonly undertaken by BET nitrogen adsorption – are relatively costly in terms of instrumentation and operator time. A novel approach is presented for estimating fine (2.5 mg kg−1), four elements were identified as significant predictors of SSA (ordered by decreasing predictive power): V > Ca > Al > Rb. The optimum model from these four elements accounted for 73% of the variation in bed sediment SSA (range 6–46 m2 g−1) with a root mean squared error of prediction – based on leave-one-out cross-validation – of 6.3 m2 g−1. It is believed that V is the most significant predictor because its concentration is strongly correlated both with the quantity of Fe-oxides and clay minerals in the stream bed sediments, which dominate sediment SSA. Sample heterogeneity in SSA – based on triplicate measurements of sub-samples – was a substantial source of variation (standard error = 2.2 m2 g−1) which cannot be accounted for in the regression model. The model was used to estimate bed sediment SSA at the other 1792 sites and at 30 duplicate sites where an extra sediment sample had been collected, 25 m from the original site. By delineating sub-catchments for the headwater sediment sites only those sub-catchments were selected with a dominant (>50% of the sub-catchment area) bedrock formation and land use type; the bedrock and land use classes accounted for 39% and 7% of the variation in bed sediment SSA, respectively. Variation in estimated, fine bed sediment SSA from the paired, duplicate sediment sites was small (2.7 m2 g−1), showing that local variation in SSA at stream sites is modest when compared to that between catchments. How the approach might be applied in other environments and its potential limitations are discussed

Origin and fate of copper in a small Mediterranean vineyard catchment: New insights from combined chemical extraction and δ65Cu isotopic composition

For centuries, many Mediterranean catchments were covered with vineyards in which copper was widely applied to protect grapevines against fungus. In the Mediterranean-type flow regime, brief and intense flood events increase the stream water discharge by up to 10 times and cause soil leaching and storm runoff. Because vineyards are primarily cultivated on steep slopes, high Cu fluxes are discharged by surface water runoff into the rivers. The purpose of this work was to investigate the riverine behavior and transport of anthropogenic Cu by coupling a sequential chemical extraction (SCE) procedure, used to determine Cu partitioning between residual and non-residual fractions, with δ65Cu isotopic measurements in each fraction. In the Baillaury catchment, France, we sampled soils (cultivated and abandoned), river bed sediments (BS), suspended particulate matter (SPM), and river water during the flash flood event of February 2009. Copper partitioning using SCE show that most of Cu in abandoned vineyard soil was in the residual phase (>60%) whereas in cultivated soil, BS and SPM, Cu was mostly (>25%) in non-residual fractions, mainly adsorbed onto iron oxide fractions. A small fraction of Cu was associated with organic matter (5 to 10%). Calculated enrichment factors (EF) are higher than 2 and the anthropogenic contribution was estimated between 50 to 85%. Values for δ65Cu in bulk samples were similar to bedrock therefore; δ65Cu on SCE fractions of superficial soils and SPM allowed for discrimination between Cu origin and distribution. Copper in residual fractions was of natural mineral origin (δ65Cu close to local bedrock, +0.07‰). Copper in water soluble fraction of SPM (δ65Cu = +0.26‰) was similar to dissolved river Cu (δ65Cu = +0.31‰). Copper from fungicide treatment (δ65Cu = −0.35‰) was bound to organic matter (δ65Cu = −0.20‰) without or with slight isotopic fractioning. A preferential adsorption of 65Cu onto iron oxides (δ65Cu = +0.5‰) is shown

A uniform isotopic and chemical signature of dust exported from Patagonia: Rock sources and occurrence in southern environments

Patagonia is considered to be the most important source of dust from South America that is deposited in surrounding areas, and we present here a systematic Sr and Nd isotopic study of sediment currently being exported. Eolian and suspended riverine sediments from Patagonia have a homogeneous chemical and isotopic composition that results from the mixing of by-products from explosive Andean volcanism, derived from the extensive Jurassic silicic Province of Chon Aike and pyroclastic materials from the basic to intermediate southern Andean Quaternary arc, which are easily denudated and dispersed. The main Andean uplift and the glaciations that began in the Late Tertiary account for the extensive distribution of these sediments in the extra-Andean region. The present geochemical signature of Patagonian sediments was produced during the Pleistocene, along with the onset of the southern Andean explosive arc volcanism. Previously published compositions of sediments from other southern South American source regions, assumed to be representative of Patagonia, are distinct from our data. Considering the alleged importance of Patagonia as a dust source for different depositional environments in southern latitudes, it is surprising to verify that the chemical and isotopic signatures of Patagonian-sourced sediments are different from those of sediments from the Southern Ocean, the Pampean Region or the Antarctic ice. Sediments from these areas have a crustal-like geochemical signature reflecting a mixed origin with sediment from other southern South American sources, whereas Patagonian sediments likely represent the basic to intermediate end-member composition

The signature of river- and wind-borne materials exported from Patagonia to the southern latitudes: a view from REEs and implications for paleoclimatic interpretations

Riverine and wind-borne materials transferred from Patagonia to the SW Atlantic exhibit a homogeneous rare earth element (REE) signature. They match well with the REE composition of Recent tephra from the Hudson volcano,and hence this implies a dominance of material supplied by this source and other similar Andean volcanoes. Due to the trapping effect of proglacial and reservoir lakes,the larger Patagonian rivers deliver to the ocean a suspended load with a slightly modified Andean signature,that shows a REE composition depleted in heavy REEs. In this paper we redefine Patagonia as a source of sediments,which is in contrast with other sources located in southern South America. Quaternary sediments deposited in the northern and,to a lesser extent, in the southern Scotia Sea, and most of the dust in ice cores of east Antarctica have REE compositions very similar to the loess from Buenos Aires Province and to Patagonian eolian dust. However,we rule out Buenos Aires province as a Holocene major source of sediments. Similarly to Buenos Aires loess (a proximal facies),it is likely that the REE compositions of most sediment cores of the Scotia Sea and Antarctica reflect a distal transport of dust with an admixed composition from two main sources: a major contribution from Patagonia,and a minor proportion from source areas containing sediments with a clear upper crustal signature (e.g.,western Argentina) or from Bolivia’s Altiplano. Evidence indicates that only during the Last Glacial Maximum,Patagonian materials were the predominant sediment source to the southern latitudes

The fate of steroid estrogens: Partitioning during wastewater treatment and onto river sediments

This is the author's accepted manuscript. The final published article is available from the link below. Copyright @ 2010 Springer Science+Business Media B.V.The partitioning of steroid estrogens in wastewater treatment and receiving waters is likely to influence their discharge to, and persistence in, the environment. This study investigated the partitioning behaviour of steroid estrogens in both laboratory and field studies. Partitioning onto activated sludge from laboratory-scale Husmann units was rapid with equilibrium achieved after 1 h. Sorption isotherms and Kd values decreased in the order 17α-ethinyl estradiol > 17α-estradiol > estrone > estriol without a sorption limit being achieved (1/n >1). Samples from a wastewater treatment works indicated no accumulation of steroid estrogens in solids from primary or secondary biological treatment, however, a range of steroid estrogens were identified in sediment samples from the River Thames. This would indicate that partitioning in the environment may play a role in the long-term fate of estrogens, with an indication that they will be recalcitrant in anaerobic conditions.EPSR

The mineral resources of the English Channel and Thames Estuary

This report accompanies the Marine mineral resource map the marine sand and gravel resources of the English Channel and Thames Estuary (Bide et al, 2012). It has been published as part of the research project Mineral Resource Assessment of the UK Continental Shelf commissioned by The Crown Estate. The map is one of a series that covers the UK Continental Shelf (UKCS). Knowledge of mineral resources is essential for effective and sustainable planning decisions. The marine mineral resource maps provide a comprehensive, relevant and accessible information base. This information will allow all stakeholders (planners, industry and members of the public) to visualise the distribution of offshore minerals to a common standard and at a common scale, an important requirement of an integrated marine planning system. The maps will also facilitate the conservation (safeguarding) of non-renewable mineral resources for future generations in accordance with the principles of sustainable development

The geochemistry of sea-bed sediments of the United Kingdom Continental Shelf : the North Sea, Hebrides and West Shetland shelves, and the Malin-Hebrides sea area

The sea area around the United Kingdom is used for a wide range of human activities all of which have a significant impact on the marine environment. The naturally-occurring concentrations of chemical elements in sea-bed sediments may be enhanced by contaminants introduced by input from rivers and the atmosphere and by more localised sources arising from shipping operations, exploitation of oil and gas, and by direct discharges from drainage systems, sewage outfalls, effluents from industry and waste' disposal at sea. It is therefore important to identify components of sea-floor sediments which are due to the rocks or older sediments from which they are derived, and those which are introduced into the environment. This report presents regional geochemical data for a variety of sediment types occurring in a wide range of environments. Samples have been collected offshore of the eastern coast of the UK where major river systems which drain heavily populated and industrialised catchment areas, such as the Thames, Humber and Tyne, flow into the North Sea, and on the shelf west of Scotland where man's activities have had much less impact. The data presented here provide a baseline for chemical element concentrations in sea-bed sediments against which future work may be assessed. It should therefore be of significance to a diverse range of interests including pollution control, fishing, natural resources, nature conservation, shipping, tourism, recreation, and waste disposal management. In addition the information will be of use to geologists in identifying the source of sea-bed sediments and the underlying glacial deposits

Reducing the external environmental costs of pastoral farming in New Zealand: experiences from the Te Arawa lakes, Rotorua

Decades of nutrient pollution have caused water quality to decline in the nationally iconic Te Arawa (Rotorua) lakes in New Zealand. Pastoral agriculture is a major nutrient source, and therefore this degradation represents an external environmental cost to intensive farming. This cost is borne by the wider community, and a major publically funded remediation programme is now under way. This article describes the range of actions being taken to reduce nutrient loads from internal (lake bed sediments) and external (primarily diffuse) sources in the lake catchments. The high economic cost and uncertain efficacy of engineering-based actions to reduce internal nutrient loads is highlighted. Major changes to land management practices to control diffuse nutrient pollution are required throughout New Zealand if the need for costly and lengthy remediation programmes elsewhere is to be avoided. More action to educate farmers and the public about eutrophication issues, development and enforcement of environmental standards, and further consideration of the use of market-based instruments are proposed as ways to correct the current market failure