15,192 research outputs found
Adsorption, Segregation and Magnetization of a Single Mn Adatom on the GaAs (110) Surface
Density functional calculations with a large unit cell have been conducted to
investigate adsorption, segregation and magnetization of Mn monomer on
GaAs(110). The Mn adatom is rather mobile along the trench on GaAs(110), with
an energy barrier of 0.56 eV. The energy barrier for segregation across the
trenches is nevertheless very high, 1.67 eV. The plots of density of states
display a wide gap in the majority spin channel, but show plenty of
metal-induced gap states in the minority spin channel. The Mn atoms might be
invisibl in scanning tunneling microscope (STM) images taken with small biases,
due to the directional p-d hybridization. For example, one will more likely see
two bright spots on Mn/GaAs(110), despite the fact that there is only one Mn
adatom in the system
Superconductivity and Phase Diagram in (LiFe)OHFeSeS
A series of (LiFe)OHFeSeS (0 x 1)
samples were successfully synthesized via hydrothermal reaction method and the
phase diagram is established. Magnetic susceptibility suggests that an
antiferromagnetism arising from (LiFe)OH layers coexists with
superconductivity, and the antiferromagnetic transition temperature nearly
remains constant for various S doping levels. In addition, the lattice
parameters of the both a and c axes decrease and the superconducting transition
temperature T is gradually suppressed with the substitution of S for Se,
and eventually superconductivity vanishes at = 0.90. The decrease of T
could be attributed to the effect of chemical pressure induced by the smaller
ionic size of S relative to that of Se, being consistent with the effect of
hydrostatic pressure on (LiFe)OHFeSe. But the detailed
investigation on the relationships between and the crystallographic
facts suggests a very different dependence of on anion height from
the Fe2 layer or -Fe2- angle from those in FeAs-based superconductors.Comment: 6 pages, 6 figure
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