Photoelectrochemical electrodes

The surface of a moderate band gap semiconductor such as p-type molybdenum sulfide is modified to contain an adherent film of charge mediating ionene polymer containing an electroactive unit such as bipyridimium. Electron transport between the electrode and the mediator film is favorable and photocorrosion and recombination processes are suppressed. Incorporation of particles of catalyst such as platinum within the film provides a reduction in overvoltage. The polymer film is readily deposited on the electrode surface and can be rendered stable by ionic or addition crosslinking. Catalyst can be predispersed in the polymer film or a salt can be impregnated into the film and reduced therein

Non-equilibrium umbrella sampling applied to force spectroscopy of soft matter

Physical systems often respond on a timescale which is longer than that of the measurement. This is particularly true in soft matter where direct experimental measurement, for example in force spectroscopy, drives the soft system out of equilibrium and provides a non-equilibrium measure. Here we demonstrate experimentally for the first time that equilibrium physical quantities (such as the mean square displacement) can be obtained from non-equilibrium measurements via umbrella sampling. Our model experimental system is a bead fluctuating in a time-varying optical trap. We also show this for simulated force spectroscopy on a complex soft molecule--a piston-rotaxane

On the Measure in Simplicial Gravity

Functional measures for lattice quantum gravity should agree with their continuum counterparts in the weak field, low momentum limit. After showing that the standard simplicial measure satisfies the above requirement, we prove that a class of recently proposed non-local measures for lattice gravity do not satisfy such a criterion, already to lowest order in the weak field expansion. We argue therefore that the latter cannot represent acceptable discrete functional measures for simplicial geometries.Comment: LaTeX, 15 pages, 2 figure

Workload reduction of a generalized Brownian network

We consider a dynamic control problem associated with a generalized Brownian network, the objective being to minimize expected discounted cost over an infinite planning horizon. In this Brownian control problem (BCP), both the system manager's control and the associated cumulative cost process may be locally of unbounded variation. Due to this aspect of the cost process, both the precise statement of the problem and its analysis involve delicate technical issues. We show that the BCP is equivalent, in a certain sense, to a reduced Brownian control problem (RBCP) of lower dimension. The RBCP is a singular stochastic control problem, in which both the controls and the cumulative cost process are locally of bounded variation.Comment: Published at http://dx.doi.org/10.1214/105051605000000458 in the Annals of Applied Probability (http://www.imstat.org/aap/) by the Institute of Mathematical Statistics (http://www.imstat.org

Quark Condensates: Flavour Dependence

We determine the q-bar q condensate for quark masses from zero up to that of the strange quark within a phenomenologically successful modelling of continuum QCD by solving the quark Schwinger-Dyson equation. The existence of multiple solutions to this equation is the key to an accurate and reliable extraction of this condensate using the operator product expansion. We explain why alternative definitions fail to give the physical condensate.Comment: 9 pages, 7 figures, uses appolb.cls, LaTeX. Talk presented by R. Williams at the EURIDICE Final Meeting, August 24-27th, 2006, Kazimierz, Polan