Ferromagnetic coupling and magnetic anisotropy in molecular Ni(II) squares

We investigated the magnetic properties of two isostructural Ni(II) metal complexes [Ni4Lb8] and [Ni4Lc8]. In each molecule the four Ni(II) centers form almost perfect regular squares. Magnetic coupling and anisotropy of single crystals were examined by magnetization measurements and in particular by high-field torque magnetometry at low temperatures. The data were analyzed in terms of an effective spin Hamiltonian appropriate for Ni(II) centers. For both compounds, we found a weak intramolecular ferromagnetic coupling of the four Ni(II) spins and sizable single-ion anisotropies of the easy-axis type. The coupling strengths are roughly identical for both compounds, whereas the zero-field-splitting parameters are significantly different. Possible reasons for this observation are discussed.Comment: 7 pages, 7 figure

Locality in GNS Representations of Deformation Quantization

In the framework of deformation quantization we apply the formal GNS construction to find representations of the deformed algebras in pre-Hilbert spaces over $\mathbb C[[\lambda]]$ and establish the notion of local operators in these pre-Hilbert spaces. The commutant within the local operators is used to distinguish `thermal' from `pure' representations. The computation of the local commutant is exemplified in various situations leading to the physically reasonable distinction between thermal representations and pure ones. Moreover, an analogue of von Neumann's double commutant theorem is proved in the particular situation of a GNS representation with respect to a KMS functional and for the Schr\"odinger representation on cotangent bundles. Finally we prove a formal version of the Tomita-Takesaki theorem.Comment: LaTeX2e, 29 page