Infrared imaging and spectroscopy of the Luminous Blue Variables Wra 751 and AG Car

We present ground-based infrared imaging and ISO spectroscopy of the luminous blue variables Wra 751 and AG Car. The images show in both cases a detached shell with a roughly circular distribution of emission. The infrared images of AG Car coincide very well with the optical images. The optical (H[FORMULA]) image of Wra 751 is different from the infrared image; the H[FORMULA] nebula is suggested to be a scattering nebula containing cold dust particles. Fitting both the images and the spectra consistently with a 1-D radiative transfer model, we derive properties of their dust shells. Wra 751 is surrounded by a dust shell with inner and outer radii of 0.17 and 0.34 pc respectively and a dust mass of 0.017 [FORMULA]. The dust shell of AG Car has inner and outer radii of 0.37 and 0.81 pc respectively and a total dust mass of 0.25 [FORMULA]. Dust mass-loss rates during the formation of the shells are 2.7[FORMULA] and 3.4[FORMULA] [FORMULA] yr-1, respectively. The total dust mass and hence the derived dust mass-loss rates are uncertain by at least a factor of two. For AG Car, the derived dust mass and mass-loss rate are higher than previous estimates. This is mainly caused by the fact that a contribution of very large grains ([FORMULA] 10 µm) is needed to explain the flux levels at longer wavelengths. Dust models for both objects fail to explain the flux shortward of 15 to 20 µm: a population of small warm grains, not in thermal equilibrium with the central star is necessary to explain this excess. Similarities between dust shells around Wolf-Rayet stars and Wra 751 and AG Car (mass, grain size population, morphology) suggest a similar formation history and imply an evolutionary connection. A similar connection with red supergiants is suggested on the basis of the dust composition and derived time-averaged mass-loss rates

Prelaunch characterization of the Ozone Monitoring Instrument transfer function in the spectral domain

A method and an experimental measurement setup to accurately characterize the instrument transfer function in the spectral domain for hyperspectral spectrometers in the ultraviolet-visible wavelength range are described. The application to the on-ground calibration of the Ozone Monitoring Instrument (OMI) on board the Earth Observing System Aura satellite is presented and discussed. With this method and setup, based on an echelle grating, a sampling of the instrument transfer function in the spectral domain can be selected and is not limited by the spectral resolution and sampling of the spectrometer that is being characterized. The importance of accurately knowing the OMI instrument transfer functions in the spectral domain for in-flight differential optical absorption spectroscopy retrievals and wavelength calibration is discussed. The analysis of the OMI measurement data is presented and shows that the instrument transfer functions in the spectral domain as a function of wavelength and viewing angle can be determined with high accurac

The C-C-C bending modes of PAHs:a new emission plateau from 15 to 20 mu m

We have obtained 2.5-45 mu m spectra of a sample of compact H II regions, YSOs and evolved stars in order to study the origin and evolution of interstellar Polycyclic Aromatic Hydrocarbon molecules (PAHs). Besides the well-known, strong PAH bands at 3.3, 6.2, 7.7, 8.6, and 11.2 mu m, these spectra reveal for the first time, a ubiquitous emission plateau from 15 to 20 mu m While the overall shape of this plateau is very similar in all sources, the detailed profiles vary from source to source. In particular, some sources show a distinct emission feature at 16.4 mu m. Moreover, the integrated intensity of this plateau varies relative to the PAH emission features by a factor 10 in our sample. We attribute this 15-20 mu m plateau to a blend of many emission features due to the interstellar or circumstellar PAH family present in these sources. Laboratory studies and quantum chemical calculations show that PAH molecules invariably possess emission features in this wavelength region, arising from C-CC bending modes which cause in- and out-of-plane distortion of the carbon skeleton. These modes are very sensitive to the molecular structure of the specific PAHs present and hence different molecules emit at different wavelengths. Analysis of the available data on the IR characteristics of PAHs show that a collection of PAHs will give rise to a broad plateau in this region. We have analyzed the size distribution of PAHs giving rise to the IR emission spectra of the sources in our samples. While much of the 15-20 mu m plateau is thought to arise in relatively large PAHs and PAH clusters, we attribute the 16.4 mu m feature to the small end of the interstellar PAH size distribution. We conclude that the observed increased strength of the 15-20 mu m plateau relative to the shorter wavelength IR emission features in regions of massive star formation is caused by a preponderance of larger PAHs and PAH clusters in those sources. Possibly this reflects the importance of coagulation in the dense molecular cloud environment from which these stars are formed