Photoluminescence transient study of surface defects in ZnO nanorods grown by chemical bath deposition

Two deep level defects (2.25 and 2.03 eV) associated with oxygen vacancies (V$_o$) were identified in ZnO nanorods (NRs) grown by low cost chemical bath deposition. A transient behaviour in the photoluminescence (PL) intensity of the two V$_o$ states was found to be sensitive to the ambient environment and to NR post-growth treatment. The largest transient was found in samples dried on a hot plate with a PL intensity decay time, in air only, of 23 and 80 s for the 2.25 and 2.03 eV peaks, respectively. Resistance measurements under UV exposure exhibited a transient behaviour in full agreement with the PL transient indicating a clear role of atmospheric O$_2$ on the surface defect states. A model for surface defect transient behaviour due to band bending with respect to the Fermi level is proposed. The results have implications for a variety of sensing and photovoltaic applications of ZnO NRs

Design Criteria for Fracture Assessment of Pressurized Nuclear Components

This paper presents the design criteria adopted for fracture assessment of pressurized components of nuclear power plants. Although there are wide variety of components in a typical nuclear power plant, the thrust in this paper is on components which are part of the primary heat transport system. The paper presents an overview of design rules, practices adopted and experimental verification needed for ensuring the structural integrity of nuclear pressure vessels and piping

Theoretical analysis of acoustic stop bands in two-dimensional periodic scattering arrays

This paper presents a theoretical analysis of the recently reported observation of acoustic stop bands in two-dimensional scattering arrays (Robertson and Rudy, J. Acoust. Soc. Am. {\bf 104}, 694, 1998). A self-consistent wave scattering theory, incorporating all orders of multiple scattering, is used to obtain the wave transmission. The band structures for the regular arrays of cylinders are computed using the plane wave expansion method. The theoretical results compare favorably with the experimental data.Comment: 18 pages, 4 page

Acoustic Attenuation by Two-dimensional Arrays of Rigid Cylinders

In this Letter, we present a theoretical analysis of the acoustic transmission through two-dimensional arrays of straight rigid cylinders placed parallelly in the air. Both periodic and completely random arrangements of the cylinders are considered. The results for the sound attenuation through the periodic arrays are shown to be in a remarkable agreement with the reported experimental data. As the arrangement of the cylinders is randomized, the transmission is significantly reduced for a wider range of frequencies. For the periodic arrays, the acoustic band structures are computed by the plane-wave expansion method and are also shown to agree with previous results.Comment: 4 pages, 3 figure

Viscoelastic response of sonic band-gap materials

A brief report is presented on the effect of viscoelastic losses in a high density contrast sonic band-gap material of close-packed rubber spheres in air. The scattering properties of such a material are computed with an on-shell multiple scattering method, properties which are compared with the lossless case. The existence of an appreciable omnidirectional gap in the transmission spectrum, when losses are present, is also reported.Comment: 5 pages, 4 figures, submitted to PR

PHOTO-CRYSTALLIZATION IN a-Se 1-x Sb x THIN FILMS

The present paper reports photo-crystallization in amorphous thin films of Se 1-x Sb x where x is varied from 0 to 0.04. It is observed that photocrystallization occurs in these films when light is shone for more than 6 hours. The d. c. conductivity of the films increases by 2-3 orders of magnitude on crystallization, which is taken as a characteristic quantity to measure the extent of crystallization. X-ray diffraction and electron microscopy have been used to confirm crystallization. The results indicate that the effect of photo-crystallization decreases as Sb concentration increases

Cellulose: A review as natural, modified and activated carbon adsorbent

Cellulose is a biodegradable, renewable, non-meltable polymer which is insoluble in most solvents due to hydrogen bonding and crystallinity. Natural cellulose shows lower adsorption capacity as compared to modified cellulose and its capacity can be enhanced by modification usually by chemicals. This review focuses on the utilization of cellulose as an adsorbent in natural/modified form or as a precursor for activated carbon (AC) for adsorbing substances from water. The literature revealed that cellulose can be a promising precursor for production of activated carbon with appreciable surface area ( 1300 m2 g 1) and total pore volume ( 0.6 cm3 g 1) and the surface area and pore volume varies with the cellulose content. Finally, the purpose of review is to report a few controversies and unresolved questions concerning the preparation/properties of ACs from cellulose and to make aware to readers that there is still considerable scope for future development, characterization and utilization of ACs from cellulose.non

Scattering of elastic waves by periodic arrays of spherical bodies

We develop a formalism for the calculation of the frequency band structure of a phononic crystal consisting of non-overlapping elastic spheres, characterized by Lam\'e coefficients which may be complex and frequency dependent, arranged periodically in a host medium with different mass density and Lam\'e coefficients. We view the crystal as a sequence of planes of spheres, parallel to and having the two dimensional periodicity of a given crystallographic plane, and obtain the complex band structure of the infinite crystal associated with this plane. The method allows one to calculate, also, the transmission, reflection, and absorption coefficients for an elastic wave (longitudinal or transverse) incident, at any angle, on a slab of the crystal of finite thickness. We demonstrate the efficiency of the method by applying it to a specific example.Comment: 19 pages, 5 figures, Phys. Rev. B (in press