462 research outputs found
Test of quantum chemistry in vibrationally-hot hydrogen molecules
Precision measurements are performed on highly excited vibrational quantum
states of molecular hydrogen. The rovibrational levels of H
(), lying only cm below the first dissociation
limit, were populated by photodissociation of HS and their level energies
were accurately determined by two-photon Doppler-free spectroscopy. A
comparison between the experimental results on level energies with the
best \textit{ab initio} calculations shows good agreement, where the present
experimental accuracy of cm is more precise than
theory, hence providing a gateway to further test theoretical advances in this
benchmark quantum system.Comment: 5 pages, 4 figures, and 2 table
B\,^1\Sigma^{+}_{u} and EF\,^{1}\Sigma^{+}_{g} level energies of D
Accurate absolute level energies of the B\,^1\Sigma^{+}_{u}, and
EF\,^{1}\Sigma^{+}_{g}, rovibrational quantum states of molecular
deuterium are derived by combining results from a Doppler-free two-photon laser
excitation study on several lines in the
(0,0) band, with results
from a Fourier-transform spectroscopic emission study on a low-pressure
hydrogen discharge. Level energy uncertainties as low as 0.0005 cm are
obtained for some low-lying E\,^{1}\Sigma^{+}_{g} inner-well rovibrational
levels, while uncertainties for higher-lying rovibrational levels and those of
the F\,^{1}\Sigma^{+}_{g} outer-well states are nominally 0.005 cm.
Level energies of B\,^1\Sigma^{+}_{u} rovibrational levels, for
and are determined at an accuracy of 0.001 cm. Computed
wavelengths of D Lyman transitions in the
B\,^1\Sigma^{+}_{u}-X\,^{1}\Sigma^{+}_{g} () bands are also tabulated
for future applications.Comment: appears in Journal of Molecular Spectroscopy (2014
High-precision laser spectroscopy of the CO A - X (2,0), (3,0) and (4,0) bands
High-precision two-photon Doppler-free frequency measurements have been
performed on the CO A - X fourth-positive system (2,0),
(3,0), and (4,0) bands. Absolute frequencies of forty-three transitions, for
rotational quantum numbers up to , have been determined at an accuracy
of cm, using advanced techniques of two-color 2+1'
resonance-enhanced multi-photon ionization, Sagnac interferometry,
frequency-chirp analysis on the laser pulses, and correction for AC-Stark
shifts. The accurate transition frequencies of the CO A - X
system are of relevance for comparison with astronomical data in the search for
possible drifts of fundamental constants in the early universe. The present
accuracies in laboratory wavelengths of may be considered exact for the purpose of such comparisons.Comment: 13 pages, 6 figures, The Journal of Chemical Physics (2015) accepte
Ramsey-type microwave spectroscopy on CO ()
Using a Ramsey-type setup, the lambda-doublet transition in the level of the state of CO was measured to be 394 064 870(10)
Hz. In our molecular beam apparatus, a beam of metastable CO is prepared in a
single quantum level by expanding CO into vacuum and exciting the molecules
using a narrow-band UV laser system. After passing two microwave zones that are
separated by 50 cm, the molecules are state-selectively deflected and detected
1 meter downstream on a position sensitive detector. In order to keep the
molecules in a single level, a magnetic bias field is applied. We find
the field-free transition frequency by taking the average of the and transitions,
which have an almost equal but opposite Zeeman shift. The accuracy of this
proof-of-principle experiment is a factor of 100 more accurate than the
previous best value obtained for this transition
A constraint on a varying proton--electron mass ratio 1.5 billion years after the Big Bang
A molecular hydrogen absorber at a lookback time of 12.4 billion years,
corresponding to 10 of the age of the universe today, is analyzed to put a
constraint on a varying proton--electron mass ratio, . A high resolution
spectrum of the J14432724 quasar, which was observed with the Very Large
Telescope, is used to create an accurate model of 89 Lyman and Werner band
transitions whose relative frequencies are sensitive to , yielding a limit
on the relative deviation from the current laboratory value of
.Comment: Accepted for publication in PRL. Includes supplemental materia
Rayleigh-Brillouin light scattering spectroscopy of nitrous oxide (NO)
High signal-to-noise and high-resolution light scattering spectra are
measured for nitrous oxide (NO) gas at an incident wavelength of 403.00 nm,
at 90 scattering, at room temperature and at gas pressures in the range
bar. The resulting Rayleigh-Brillouin light scattering spectra are
compared to a number of models describing in an approximate manner the
collisional dynamics and energy transfer in this gaseous medium of this
polyatomic molecular species. The Tenti-S6 model, based on macroscopic gas
transport coefficients, reproduces the scattering profiles in the entire
pressure range at less than 2\% deviation at a similar level as does the
alternative kinetic Grad's 6-moment model, which is based on the internal
collisional relaxation as a decisive parameter. A hydrodynamic model fails to
reproduce experimental spectra for the low pressures of 0.5-1 bar, but yields
very good agreement (\%) in the pressure range bar. While these
three models have a different physical basis the internal molecular relaxation
derived can for all three be described in terms of a bulk viscosity of Pas. A 'rough-sphere' model, previously
shown to be effective to describe light scattering in SF gas, is not found
to be suitable, likely in view of the non-sphericity and asymmetry of the N-N-O
structured linear polyatomic molecule
CARS spectroscopy of the () band in
Molecular hydrogen is a benchmark system for bound state quantum calculation
and tests of quantum electrodynamical effects. While spectroscopic measurements
on the stable species have progressively improved over the years, high
resolution studies on the radioactive isotopologues , and
have been limited. Here we present an accurate determination of
transition energies in the fundamental vibrational
band of the ground electronic state, by means of high resolution Coherent
Anti-Stokes Raman Spectroscopy. With the present experimental uncertainty of
, which is a fivefold improvement over previous
measurements, agreement with the latest theoretical calculations is
demonstrated.Comment: 9 pages, 3 figure
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