3,194 research outputs found
Unusual superexchange pathways in a Ni triangular lattice of NiGaS with negative charge-transfer energy
We have studied the electronic structure of the Ni triangular lattice in
NiGaS using photoemission spectroscopy and subsequent model
calculations. The cluster-model analysis of the Ni 2 core-level spectrum
shows that the S 3 to Ni 3 charge-transfer energy is -1 eV and the
ground state is dominated by the configuration ( is a S 3 hole).
Cell perturbation analysis for the NiS triangular lattice indicates that
the strong S 3 hole character of the ground state provides the enhanced
superexchange interaction between the third nearest neighbor sites.Comment: 10 pages, 5 figures, accepted to PR
Signature of Carrier-Induced Ferromagnetism in Ti_{1-x}Co_{x}O_{2-delta}: Exchange Interaction Between High-Spin Co 2+ and the Ti 3d Conduction Band
X-ray photoemission spectroscopy measurements were performed on thin-film
samples of rutile Ti_{1-x}Co_{x}O_{2-delta} to reveal the electronic structure.
The Co 2p core level spectra indicate that the Co ions take the high-spin Co 2+
configuration, consistent with substitution on the Ti site. The high spin state
and the shift due to the exchange splitting of the conduction band suggest
strong hybridization between carriers in the Ti 3d t2g band and the t2g states
of the high-spin Co 2+. These observations support the argument that room
temperature ferromagnetism in Ti_{1-x}Co_{x}O_{2-delta} is intrinsic.Comment: 4 pages, 5 figures. Accepted for publication in Physical Review
Letter
Orbital Ordering Structures in (Nd,Pr)0.5Sr0.5MnO3 Manganite Thin Films on Perovskite (011) Substrates
Structural study of orbital-ordered manganite thin films has been conducted
using synchrotron radiation, and a ground state electronic phase diagram is
made. The lattice parameters of four manganite thin films, Nd0.5Sr0.5MnO3
(NSMO) or Pr0.5Sr0.5MnO3 (PSMO) on (011) surfaces of SrTiO3 (STO) or
[(LaAlO3){0.3}(SrAl0.5Ta0.5O3){0.7}] (LSAT), were measured as a function of
temperature. The result shows, as expected based on previous knowledge of bulk
materials, that the films' resistivity is closely related to their structures.
Observed superlattice reflections indicate that NSMO thin films have an
antiferro-orbital-ordered phase as their low-temperature phase while PSMO film
on LSAT has a ferro-orbital-ordered phase, and that on STO has no
orbital-ordered phase. A metallic ground state was observed only in films
having a narrow region of A-site ion radius, while larger ions favor
ferro-orbital-ordered structure and smaller ions stabilize
antiferro-orbital-ordered structure. The key to the orbital-ordering transition
in (011) film is found to be the in-plane displacement along [0-1 1] direction.Comment: 19pages, 11 figure
High-energy spectroscopic study of the III-V nitride-based diluted magnetic semiconductor GaMnN
We have studied the electronic structure of the diluted magnetic
semiconductor GaMnN ( = 0.0, 0.02 and 0.042) grown on Sn-doped
-type GaN using photoemission and soft x-ray absorption spectroscopy. Mn
-edge x-ray absorption have indicated that the Mn ions are in the
tetrahedral crystal field and that their valence is divalent. Upon Mn doping
into GaN, new state were found to form within the band gap of GaN, and the
Fermi level was shifted downward. Satellite structures in the Mn 2 core
level and the Mn 3 partial density of states were analyzed using
configuration-interaction calculation on a MnN cluster model. The deduced
electronic structure parameters reveal that the - exchange coupling in
GaMnN is stronger than that in GaMnAs.Comment: 6pages, 10figures. To be published to Phys. Rev.
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