Data for dissertation entitled "Anisotropic and Magnetic Microparticles: Preparation and Out-of-Equilibrium Assembly"

Data for Chapters 3-6 of the dissertation. The data includes raw and processed files for (CH3) SAXS analysis of hematite superball assemblies, (CH4) optical microscopy analysis and tracking of hematite microswimmers, (CH5) microscopy analysis of magnetic polystyrene microspheres, and (CH6) microscopy analysis of ellipsoidal magnetic polystyrene.</p

Data for dissertation entitled "Anisotropic and Magnetic Microparticles: Preparation and Out-of-Equilibrium Assembly"

Data for Chapters 3-6 of the dissertation. The data includes raw and processed files for (CH3) SAXS analysis of hematite superball assemblies, (CH4) optical microscopy analysis and tracking of hematite microswimmers, (CH5) microscopy analysis of magnetic polystyrene microspheres, and (CH6) microscopy analysis of ellipsoidal magnetic polystyrene.</p

Acoustic Bubble Dynamics in a Yield-Stress Fluid : Resonance Curve and Acoustic Radiation Force Data

A compilation of data on bubble oscillations in a model Carbopol gel. Bubbles are excited using an ultrasound transducer. Here, data are for single bubbles. No shape oscillations were investigated. We did a nicely resolved resonance curve and some acquisitions in an acoustic pressure gradient</div

Acoustic Bubble Dynamics in a Yield-Stress Fluid : Raw Data

A compilation of data on bubble oscillations in a model Carbopol gel. Bubbles are excited using an ultrasound transducer. Here, data are for single bubbles. We did a nicely resolved resonance curve (2019/08/15 - Bubble 1) and some acquisitions in an acoustic pressure gradient (2019/08/15 - Bubbles 2 to 6) and an investigation of shape oscillations (2019/10/10)</div

Data relating to Nucleophile responsive charge-reversing polycations for pDNA transfection

Polycationic carriers promise low cost and scalable gene therapy treatments, however inefficient intracellular unpacking of the genetic cargo has limited transfection efficiency. Charge-reversing polycations, which transition from cationic to neutral or negative charge, can offer targeted intracellular DNA release. We describe a new class of charge-reversing polycation which undergoes a cationic-to-neutral conversion by a reaction with cellular nucleophiles. The deionization reaction is relatively slow with primary amines, and much faster with thiols. In mammalian cells, the intracellular environment has elevated concentrations of amino acids (∼10×) and the thiol glutathione (∼1000×). We propose this allows for decationization of the polymeric carrier slowly in the extracellular space and then rapidly in the intracellular milleu for DNA release. We demonstrate that in a lipopolyplex formulation this leads to both improved transfection and reduced cytotoxicity when compared to a non-responsive polycationic control.</p

Data relating to Nucleophile responsive charge-reversing polycations for pDNA transfection

Polycationic carriers promise low cost and scalable gene therapy treatments, however inefficient intracellular unpacking of the genetic cargo has limited transfection efficiency. Charge-reversing polycations, which transition from cationic to neutral or negative charge, can offer targeted intracellular DNA release. We describe a new class of charge-reversing polycation which undergoes a cationic-to-neutral conversion by a reaction with cellular nucleophiles. The deionization reaction is relatively slow with primary amines, and much faster with thiols. In mammalian cells, the intracellular environment has elevated concentrations of amino acids (∼10×) and the thiol glutathione (∼1000×). We propose this allows for decationization of the polymeric carrier slowly in the extracellular space and then rapidly in the intracellular milleu for DNA release. We demonstrate that in a lipopolyplex formulation this leads to both improved transfection and reduced cytotoxicity when compared to a non-responsive polycationic control.</p

Data underlying the paper: Temporally programmed polymer-solvent interactions using a chemical reaction network

The data underlines the paper: Temporally programmed polymer-solvent interactions using a chemical reaction network. In this work a new modular chemical reaction network (CRN) was developed, which enables reversible formation of positive charges on a tertiary amine substrate, which are removed using nucleophilic signals that control the deactivation kinetics. The modular nature of the CRN enables incorporation in diverse polymer materials, leading to a temporally programmed transition from collapsed and hydrophobic to solvated, hydrophilic polymer chains by controlling polymer-solvent interactions. Depending on the layout of the CRN, we can create stimuli-responsive or autonomously responding materials.</p

Complete dataset for publication: Metal-ligand cooperative activation of HX (X=H, Br, OR) bond on Mn based pincer complexes

Complete dataset for the publication "Metal-ligand cooperative activation of HX (X=H, Br, OR) bond on Mn based pincer complexes " by Annika M. Krieger, Vivek Sinha, Adarsh V. Kalikadien, Evgeny A. Pidko in ZAAC (Zeitschrift für anorganische und allgemeine Chemie) - data for all figures / tables in the main text- data for all figures / tables of the supporting information- xyz coordinates of all DFT- and xTB-optimized structures of Mn pincer complexes</div

Raw data for paper "Manganese-mediated C-C bond formation: alkoxycarbonylation of organoboranes"

The dataset contains all spectral data produced and used in the preparation of the above mentioned manuscript.Numbering follows that of the available ESI that is published with the manuscript. For each entry the figurenumber is stated, together with a short description (usually the figure caption). The corresponding spectraldata is provided as xy-coordinates in the units indicated in the figure.</div

Raw data for paper "Manganese-mediated C-C bond formation: alkoxycarbonylation of organoboranes"

The dataset contains all spectral data produced and used in the preparation of the above mentioned manuscript.Numbering follows that of the available ESI that is published with the manuscript. For each entry the figurenumber is stated, together with a short description (usually the figure caption). The corresponding spectraldata is provided as xy-coordinates in the units indicated in the figure.</div