Flexibility-assisted heat removal in thin crystalline silicon solar cells

Thin crystalline silicon solar photovoltaics holds great potential for reducing the module price by material saving and increasing the efficiency by reduced bulk recombination loss. However, the module efficiency decreases rather sensitively as the module temperature rises under sunlight. Effective, inexpensive approach to cooling modules would accelerate large-scale market adoption of thin crystalline silicon photovoltaics. For effective cooling, we exploit high flexibility of single-crystalline thin silicon films to create wavy solar cells. These wavy cells possess larger surface area than conventional flat cells, while occupying the same projected area. We experimentally demonstrate that the temperature of thin wavy crystalline silicon solar cells under the sunlight can be significantly reduced by increased convective cooling due to their large surface area. The substantial efficiency gain, achieved by the effective heat removal, points to high-performance thin crystalline silicon photovoltaic systems that are radically different in configuration from conventional systems.Comment: 33 pages, 17 figure

Nonisovalent Si-III-V and Si-II-VI alloys: Covalent, ionic, and mixed phases

Nonequilibrium growth of Si-III-V or Si-II-VI alloys is a promising approach to obtaining optically more active Si-based materials. We propose a new class of nonisovalent Si2AlP (or Si2ZnS) alloys in which the Al-P (or Zn-S) atomic chains are as densely packed as possible in the host Si matrix. As a hybrid of the lattice-matched parent phases, Si2AlP (or Si2ZnS) provides an ideal material system with tunable local chemical orders around Si atoms within the same composition and structural motif. Here, using first-principles hybrid functional calculations, we discuss how the local chemical orders affect the electronic and optical properties of the nonisovalent alloys.