Magnetic properties of the doped two-dimensional antiferromagnet

The variety of the normal-state magnetic properties of cuprate high-Tc superconductors is interpreted based on the self-consistent solution of the self-energy equations for the two-dimensional t-J model. The observed variations of the spin correlation length with the hole concentration x, of the spin susceptibility with x and temperature T and the scaling of the static uniform susceptibility are well reproduced by the calculated results. The nonmonotonic temperature dependence of the Cu spin-lattice relaxation rate is connected with two competing tendencies in the low-frequency susceptibility: its temperature decrease due to the increasing spin gap and the growth of the susceptibility in this frequency region with the temperature broadening of the maximum in the susceptibility.Comment: 6 pages, 5 figures, Proc. Int. Conf. "Modern Problems of Superconductivity", 9-14 Sept. 2002, Yalta, Ukrain

Electron Transfer in Porphyrin Complexes in Different Solvents

The electron transfer in different solvents is investigated for systems consisting of donor, bridge and acceptor. It is assumed that vibrational relaxation is much faster than the electron transfer. Electron transfer rates and final populations of the acceptor state are calculated numerically and in an approximate fashion analytically. In wide parameter regimes these solutions are in very good agreement. The theory is applied to the electron transfer in ${\rm H_2P-ZnP-Q}$ with free-base porphyrin (${\rm H_2P}$) being the donor, zinc porphyrin (${\rm ZnP}$) the bridge, and quinone (${\rm Q}$) the acceptor. It is shown that the electron transfer rates can be controlled efficiently by changing the energy of the bridging level which can be done by changing the solvent. The effect of the solvent is determined for different models.Comment: 28 pages + 5 figures, submitted to J. Phys. Chem. For more details see the Ph. D. thesis in quant-ph archive http://xxx.lanl.gov/abs/quant-ph/000100