Using Photo-Associative Ionization of Sodium to Demonstrate t he Opt ical Control of Cold Collisions

LVe present a study of cold collisions in a sample of magneto-optically trapped sodium atoms througli the technique of two-color photoassociative ionization spectroscopy. We demonstrate the inhibition of the process by adding an auxiliary %uppressor" laser beam and analyze tlie dependence of this optical shielding effect on the laser frequency and intensity. The possibility of using photons to control the atomic collision and to modify the thermodynamic properties of tlie cold gas is discussed. Tlie study of collisions involving laser cooled and trapped atorns has been the subject of intense investigations during the past few years. TIiis interest has been motivated by tlie desire of achieving the regime of a degenerated quantum gas and also by intrinsic features it presents, inainly tliat in tlie presence of light, collisions involving excited state atoms have duration comparable to the spontaneous emission time. In this regime, the exchange of energy between the atom ,and the modes of the radiation field (including vacuum) provides a prototype for studying the properties of nonequilibrium open systems coupled to reservoirs. As the kinetic energy of a two-body collision approaches zero, the number of partia1 waves coiitributing to the elastic collision reduces to one, the s-wave, and the information about the atomic interaction is comyletely contained in the scattering length a. The properties of a cold gas are therefore dependent on the scattering lengtli and its sign can determine the behavior of the system. Tlie recente achievement of the quantum gas regime iii a sample of laser cooled and magnetic trapped rubidium atoms[lI has opened new possibilities of studies involving the thermodymanics of a gas in such regime. Controlling the atomic interaction with photons can provide the condition to stabilize tlie gas in a single quantum state of the confining potential and also the manipulation of its thermodynamical properties. We liave recently demonstrated the possibility of controlling the atomic interaction by using photo-associative ionization (PAI) in a sample of cold sodium atoms held in a trapt2]. In this paper we present the studies of cold collisions using PAI as a prototype and the route we liave taken towards the demonstration of optical control of cold collisions. We discuss the possibility of using photons as a to01 to cliange the course of the atomic encounter, including the modification of attraction into repulsion aiid its applications. Photo-associative ionization as a prototype of cold collisions Conventional associative ionization occurring at ordinary temperatures proceeds in two distinct steps: excitation of isolated atoms followed by the collisional interaction between excited atomic states. Tlie collision event is fast compared to the radiative relaxation and the two steps are decoupled. In contrast, PAI starts with ground state partners moving sufficiently slow that they have time to absorb and spontaneously emit photons prior to the final ionizing interaction. The partners inust be close enough when the initial absorption takes place such tliat a significant fraction of the excited population survives to relaxation back to the ground state. Thus, PAI starts by promoting the ground state of the colliding species, designated by [Na,,Na], to a

Nonlinear absorption spectrum in perylene derivatives

Knowledge about nonlinear absorption spectra of materials used in photonic devices is of paramount importance in determining their optimum operation wavelengths. In this work, we have investigated the two-photon absorption (2PA) degenerate cross-section spectrum for perylene derivatives using the Z-scan technique with femtosecond laser pulses. All perylene derivatives studied present large 2PA cross-sections, only comparable to the best ones reported in the literature. The results achieved in the present investigation indicate perylene derivatives as promising materials for two-photon applications. ©2005 Optical Society of America

Two-photon absorption in oxazole derivatives: An experimental and quantum chemical study

Experimental and theoretical studies on the two-photon absorption properties of two oxazole derivatives: 2,5-diphenyloxazole (PPO) and 2-(4-biphenylyI)-5-phenyl-1,3,4-oxadiazole (PBD) are presented. The two-photon absorption cross-section spectra were determined by means of the Z-scan technique, from 460 up to 650 nm, and reached peak values of 84 GM for PBD and 27 GM for PPO. Density Functional Theory and response function formalism are used to determine the molecular structures and the one- and two-photon absorption properties and to assist in the interpretation of the experimental results. The Polarizable Continuum Model in one-photon absorption calculations is used to estimate solvent effects. (C) 2011 Elsevier B.V. All rights reserved.Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP)Fapesp (Fundacao de Amparo a Pesquisa do Estado de Sao Paulo)Conselho Nacional de Desenvolvimento Cientifico (CNPq)CNPq (Conselho Nacional de Desenvolvimento Cientifico)CAPES (Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior)Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES)Financiadora de Estudos e Projetos (FINEP)FINEP (Financiadora de Estudos e Projetos)FAPEPI (Fundacao de Amparo a Pesquisa do Estado do Piaui)FAPEPI (Fundacao de Amparo a Pesquisa do Estado do Piaui)UFPI (Universidade Federal do Piaui), from BrazilUFPI (Universidade Federal do Piaui), from Brazi

Antimony glasses with large nonlinear refractive indices, small two-photon absorption coefficients and ultrafast response at telecom wavelengths

Nonlinear (NL) optical properties of antimony oxide based glasses (AG) were characterized for excitation wavelengths from 800 to 1600 m. The NL refractive indices, n2, and the two-photon absorption (TPA) coefficient, β, have been evaluated using the Z-scan technique. Values of n2≈ 10-15 - 10-14 cm2/W of electronic origin were measured and negligible TPA coefficients (β < 0.003 cm/GW) were determined. The response time of the nonlinearity is faster than 100 fs as determined using the Kerr shutter technique. The figure-of-merit usually considered for all-optical switching, T = 2βλ/n2 , indicates that AG are very good materials for ultrafast switches at telecom wavelengths. © 2007 IEEE