Rotational Heisenberg Inequalities

Since their discovery in 1927, the Heisenberg Inequalities have become an icon of quantum mechanics. Often inappropriately referred to as the Uncertainty Principle, these inequalities relating the standard deviations of the position and momentum observables to Planck's constant are one of the cornerstones of the quantum formalism even if the physical interpretation of quantum mechanics remains still open to controversy nowadays. The Heisenberg Inequalities governing translational motion are well understood. However, the corresponding inequalities pertaining to rotational motion have not been established so far. To fill this gap, we present here the Rotational Heisenberg Inequalities relating the standard deviations of the orientation axis and orbital angular momentum observables of an isolated molecule. The reason for choosing this system is that a molecule separated from its environment corresponds to a bound system preserving the orbital angular momentum.Comment: 6 pages, 2 figures. arXiv admin note: substantial text overlap with arXiv:1412.211

Quantum description of a rotating and vibrating molecule

A rigorous quantum description of molecular dynamics with a particular emphasis on internal observables is developed accounting explicitly for kinetic couplings between nuclei and electrons. Rotational modes are treated in a genuinely quantum framework by defining a molecular orientation operator. Canonical rotational commutation relations are established explicitly. Moreover, physical constraints are imposed on the observables in order to define the state of a molecular system located in the neighborhood of the ground state defined by the equilibrium condition.Comment: 28 page