Polimerización del acrilato de butilo en solución y la caracterización de sus propiedades fisicoquímicas

Se propuso una metodología y formulación para la síntesis del acrilato de butilo vía polimerización en solución a temperaturas menores a 100°C, así como la evaluación de sus propiedades fisicoquímicas resultantes, tales como un buen control de la masa molecular y la predicción de la temperatura de transición vítrea (Tg). Las muestras polimerizadas se caracterizaron por diferentes técnicas como FTIR, cromatografía por exclusión de tamaños (CET) y calorimetría diferencia de barrido (DSC). Se propuso el uso del AIBN y el peróxido de benzoílo como iniciadores, se hizo uso del n-dodecanotiol como agente de transferencia para controlar su masa molecular. Con los resultados obtenidos se hace factible escalar el proceso para aplicaciones en la industria del petróleo o de los adhesivos.A methodology and formulation was proposed for the synthesis of the n-butyl acrylate via solution polymerization at temperatures below 100°C, as well as the evaluation of its resulting physicochemical properties, such as well control of molecular weight and the prediction of glass transition temperature (Tg). The polymerized samples were characterized by different techniques such as FTIR, size exclusion chromatography (CET) and differential scanning calorimetry (DSC). The use of AIBN and benzoyl peroxide as initiators was proposed, using n-dodecanethiol as a transfer agent in order to control their molecular weight. With the results obtained it becomes feasible to scale the process for applications in the petroleum industry or adhesives

Distributed architecture supporting intelligent optical measurement aggregation and streaming event telemetry

A distributed telemetry system integrating optical measurement and event data collection is demonstrated. Measurements of optical spectra from Nokia Bell Labs, of optical transponders from ADVA and SDN controller events from CTTC will be showcased.The research leading to these results has received funding from the H2020 B5G-OPEN (G.A. 101016663) and the MICINN IBON (PID2020-114135RB-I00) projects and from the ICREA Institution.Peer ReviewedPostprint (author's final draft

Demonstration of latency-aware 5G network slicing on optical metro networks

The H2020 METRO-HAUL European project has architected a latency-aware, cost-effective, agile, and programmable optical metro network. This includes the design of semi-disaggregated metro nodes with compute and storage capabilities, which interface effectively with both 5G access and multi-Tbit/s elastic optical networks in the core. In this paper, we report the automated deployment of 5G services, in particular, a public safety video surveillance use case employing low-latency object detection and tracking using on-camera and on-the-edge analytics. The demonstration features flexible deployment of network slice instances, implemented in terms of ETSI NFV Network Services. We summarize the key findings in a detailed analysis of end-to-end quality of service, service setup time, and soft-failure detection time. The results show that the round-trip-time over an 80 km link is under 800 µs and the service deployment time under 180 seconds.Horizon 2020 Framework Programme (761727); Bundesministerium für Bildung und Forschung (16KIS0979K).Peer ReviewedArticle signat per 25 autors/es: B. Shariati, Fraunhofer HHI, Berlin, Germany / L. Velasco, Universitat Politècnica de Catalunya, Barcelona, Spain / J.-J. Pedreno-Manresa, ADVA, Munich, Germany / A. Dochhan, ADVA, Munich, Germany / R. Casellas, Centre Tecnològic Telecomunicacions Catalunya, Castelldefels, Spain / A. Muqaddas, University of Bristol, Bristol, UK / O. Gonzalez de Dios, Telefónica, Madrid, Spain / L. Luque Canto, Telefónica, Madrid, Spain / B. Lent, Qognify GmbH, Bruchsal, Germany / J. E. Lopez de Vergara, Naudit HPCN, Madrid, Spain / S. Lopez-Buedo, Naudit HPCN, Madrid, Spain / F. Moreno, Universidad Politécnica de Cartagena, Cartagena, Spain / P. Pavon, Universidad Politécnica de Cartagena, Cartagena, Spain / M. Ruiz, Universitat Politècnica de Catalunya, Barcelona, Spain / S. K. Patri, ADVA, Munich, Germany / A. Giorgetti, CNIT, Pisa, Italy / F. Cugini, CNIT, Pisa, Italy / A. Sgambelluri, CNIT, Pisa, Italy / R. Nejabati, University of Bristol, Bristol, UK / D. Simeonidou, University of Bristol, Bristol, UK / R.-P. Braun, Deutsche Telekom, Germany / A. Autenrieth, ADVA, Munich, Germany / J.-P. Elbers, ADVA, Munich, Germany / J. K. Fischer, Fraunhofer HHI, Berlin, Germany / R. Freund, Fraunhofer HHI, Berlin, GermanyPostprint (author's final draft

Facile integration of ordered nanowires in functional devices

The integration of one-dimensional (1D) nanostructures of non-industry-standard semiconductors infunctional devices following bottom-up approaches is still an open challenge that hampers the exploita-tion of all their potential. Here, we present a simple approach to integrate metal oxide nanowires inelectronic devices based on controlled dielectrophoretic positioning together with proof of conceptdevices that corroborate their functionality. The method is flexible enough to manipulate nanowiresof different sizes and compositions exclusively using macroscopic solution-based techniques in conven-tional electrode designs. Our results show that fully functional devices, which display all the advantagesof single-nanowire gas sensors, photodetectors, and even field-effect transistors, are thus obtained rightafter a direct assembly step without subsequent metallization processing. This paves the way to lowcost, high throughput manufacturing of general-purpose electronic devices based on non-conventionaland high quality 1D nanostructures driving up many options for high performance and new low energyconsumption devices

NH3 sensing with self-assembled ZnO-nanowire μHP sensors in isothermal and temperature-pulsed mode

Dielectrophoretic alignment is found to be a simple and efficient method to deposit the solution prepared ZnO nanowires onto micro hot plate substrates. Due to the strong surface effects, positive temperature coefficient for resistance was encountered with ZnO nanowires in the high temperature range (>250 degrees C). The response to ammonia (NH3) was evaluated in isothermal and temperature-pulsed operation mode; the relative higher response observed in the latter case demonstrates that the use of this methodology is a good strategy to improve the performance of metal oxide sensors based on nanomaterials. Here, we evaluate the response to NH3 and qualitatively describe the sensing mechanism in temperature-pulsed mode, highlighting the main differences compared to the standard isothermal methodology

Metabolic syndrome, adiposity, diet, and emotional eating are associated with oxidative stress in adolescents

Background: Metabolic syndrome (MS), a condition related to adiposity and oxidative stress, can develop in adolescence, a critical stage in life that impacts health in adulthood. However, there is scarce scientific research about the relationship between lifestyle factors, emotion management, and oxidative stress in this phase of life.Aim: To analyze whether nutritional parameters, lifestyle factors, emotion management, and MS in adolescents are associated with oxidative stress measured by the biomarker 8-isoprostane.Methods: A cross-sectional study was carried out in 132 adolescents (48.5% girls, aged 12 ± 0.48 years) and data were collected on nutritional parameters (anthropometric measurements, biochemical analyzes, and blood pressure), lifestyle factors (physical activity, sleep, and diet), and emotion management (self-esteem, emotional eating, and mood). 8-isoprostane was analyzed in spot urine samples. The study population was categorized in three groups (healthy, at-risk, and with MS) using the International Diabetes Federation definition of MS in adolescents. To capture more complex interactions, a multiple linear regression was used to analyze the association between 8-isoprostane and the aforementioned variables.Results: Urinary 8-isoprostane levels were significantly higher in the MS group compared to the healthy group (1,280 ± 543 pg./mg vs. 950 ± 416 pg./mg respectively). In addition, univariable analysis revealed positive significant associations between 8-isoprostane and body mass index, waist circumference, waist-to-height ratio, body fat percentage, blood lipid profile and glucose, emotional eating, and refined cereal intake. Conversely, a negative significant association was found between 8-isoprostane and sleep duration and fish intake. The multiple linear regression analysis revealed associations between 8-isoprostane and LDL-c (β = 0.173 value of p = 0.049), emotional eating (low β = 0.443, value of p = 0.036; high β = 0.152, value of p = 0.470), refined cereal intake (β =0.191, value of p = 0.024), and fish intake (β = -0.187, value of p = 0.050).Conclusion: The MS group, LDL-c, emotional eating, and high refined cereals and low fish intakes were associated with higher levels of oxidative stress in an adolescent population.</p

Copper (II) oxide nanowires for p-type conductometric NH3 sensing

Copper (II) oxide (CuO) is a metal oxide suitable for developing solid state gas sensors. Nevertheless, a detailed insight into the chemical-to-electrical transduction mechanisms between gas molecules and this metal oxide is still limited. Here, individual CuO nanowires were evaluated as ammonia (NH3) and hydrogen sulphide (H2S) sensors, validating the p-type character of this semiconductor. The working principle behind their performance was qualitatively modeled and it was concluded that adsorbed oxygen at the surface plays a key role necessary to explain the experimental data. Compared to their counterparts of SnO2 nanowires, an appreciable sensitivity enhancement to NH3 for concentrations below 100 ppm was demonstrated

Total urinary polyphenols and ideal cardiovascular health metrics in Spanish adolescents enrolled in the SI Program: a cross-sectional study

To study the relationship between urinary total polyphenol excretion (TPE) in adolescents and ideal cardiovascular (CVH) metrics. 1151 adolescents aged 12.04 (0.46) years participating in the SI! Program for Secondary Schools were selected based on the availability of urine samples and information required to assess CVH metrics. Data on health behaviours (smoking status, body mass index, physical activity, and healthy diet) and health factors (blood pressure, total cholesterol, and blood glucose) were used to calculate the CVH metrics. TPE in urine was analysed by a Folin-Ciocalteu method after solid-phase extraction. Associations between TPE (categorized into tertiles) and CVH metrics (total and separate scores) were assessed using multilevel mixed-effect regression models. Higher TPE levels were associated with higher (healthier) CVH scores and ideal smoking status (OR 1.54, 95% CI 1.10; 1.87, p value = 0.007), physical activity (OR 1.12, 95% CI 1.02; 1.23, p value = 0.022) and total cholesterol (OR 1.78, 95% CI 1.16; 2.73, p value = 0.009) after multivariate adjustment. An association between TPE and total CVH scores was observed only in boys. Girls with higher TPE had higher rates of ideal total cholesterol and blood pressure. According to our findings, higher urinary TPE is related to better CVH scores, with relevant differences in this association by gender

Polyphenols in Urine and Cardiovascular Risk Factors: A Cross-Sectional Analysis Reveals Gender Differences in Spanish Adolescents from the SI! Program

Abstract: (1) Background: Epidemiological studies have shown an inverse association between polyphenol intake and cardiovascular risk factors (CVRFs) in adults, but few have provided information about adolescents. The aim of this study was to evaluate the relationship between urinary total polyphenol excretion (TPE) and CVRFs in adolescents. (2) Methods: A cross-sectional study was performed in 1194 Spanish adolescents from the SI! (Salud Integral) program. TPE in urine samples was determined by the Folin-Ciocalteu method, after solid-phase extraction, and categorized into quartiles. The association between TPE and CVRFs was estimated using mixed-effect linear regression and a structural equation model (SEM). (3) Results: Linear regression showed negative associations among the highest quartile of TPE and body fat percentage (B = −1.75, p-value = <0.001), triglycerides (TG) (B = −17.68, p-value = <0.001), total cholesterol (TC) (B = −8.66, p-value = 0.002), and low-density lipoprotein (LDL)-cholesterol (LDL-C) (B = −4.09, p-value = 0.008) in boys, after adjusting for all confounder variables. Negative associations between TPE quartiles and systolic blood pressure (SBP), diastolic blood pressure (DBP), and TC were also found in girls. Moreover, a structural equation model revealed that TPE was directly associated with body composition and blood glucose and indirectly associated with blood pressure, TG, LDL-C, and high-density lipoprotein-cholesterol (HDL-C) in boys. Conclusions: Higher concentrations of TPE were associated with a better profile of cardiovascular health, especially in boys, while in girls, the association was not as strong. Keywords: antioxidants; pediatric; body composition; cardiovascular; lipid profile; Folin-Ciocalte