1,590 research outputs found
Pressure-induced Jahn-Teller switch in the homoleptic hybrid perovskite [(CH3)(2)NH2]Cu(HCOO)(3): orbital reordering by unconventional degrees of freedom
Through in situ, high-pressure X-ray diffraction experiments we have shown that the homoleptic perovskite-like coordination polymer [(CH3)2NH2]Cu(HCOO)3 undergoes a pressure-induced orbital reordering phase transition above 5.20 GPa. This transition is distinct from previously reported Jahn–Teller switching in coordination polymers, which required at least two different ligands that crystallize in a reverse spectrochemical series. We show that the orbital reordering phase transition in [(CH3)2NH2]Cu(HCOO)3 is instead primarily driven by unconventional octahedral tilts and shifts in the framework, and/or a reconfiguration of A-site cation ordering. These structural instabilities are unique to the coordination polymer perovskites, and may form the basis for undiscovered orbital reorientation phenomena in this broad family of materials
Time to be responsive in the process industry: a literature-based analysis of trends of change, solutions and challenges
The current uncertain and volatile business context is challenging firms worldwide, leading to the need to be responsive at a competitive cost. This trend is so substantial that it even affects industries traditionally competing in rather stable contexts, such as the process industry. Although the process industry includes multiple sectors with different technologies and processes, these share several aspects that make the industry as a whole distinctive to the discrete manufacturing industry. Based on a literature review, this study identifies and describes trends leading the process industry to the need for responsiveness, corresponding solutions to accommodate the need, and related challenges hindering the industrialization and diffusion of solutions in this industry. This study shows that trends, such as the uncertainty and volatility of market requirements, are challenging the process industry to develop reconfigurability solutions across multiple production levels. The development of reconfigurability solutions is hindered by modularity, integrability, co-ordination and collaboration challenges
Surface Oscillations in Overdense Plasmas Irradiated by Ultrashort Laser Pulses
The generation of electron surface oscillations in overdense plasmas
irradiated at normal incidence by an intense laser pulse is investigated.
Two-dimensional (2D) particle-in-cell simulations show a transition from a
planar, electrostatic oscillation at , with the laser
frequency, to a 2D electromagnetic oscillation at frequency and
wavevector . A new electron parametric instability, involving the
decay of a 1D electrostatic oscillation into two surface waves, is introduced
to explain the basic features of the 2D oscillations. This effect leads to the
rippling of the plasma surface within a few laser cycles, and is likely to have
a strong impact on laser interaction with solid targets.Comment: 9 pages (LaTeX, Revtex4), 4 GIF color figures, accepted for
publication in Phys. Rev. Let
The design of CO2-based working fluids for high-temperature heat source power cycles
The application of CO2power cycles is advantageous to exploit high-temperature sources (500-800°C) in the case of available low-temperature heat sinks (15-25°C). However, their efficiency is strongly reduced for higher heat sink temperatures. At these temperatures, due to the low-critical temperature of CO2(about 31°C), CO2is in fact compressed in the supercritical vapor phase rather than in the liquid phase, thus increasing energetic demand for compression. One of the solutions envisaged to overcome this problem is the addition of one or more chemicals that allow having a mixture with a higher critical temperature than the one of pure CO2. This preserve the working fluid compression in its liquid phase, even in the case of heat sinks with temperatures greater than 25°C. This research shows that the addition to CO2of a properly selected chemical component enables to increase the critical temperature up to 45°C with relevant improvements of cycle efficiency with respect to pure-CO2power cycles. In particular, it summarizes the most relevant criteria to be accounted for when selecting CO2-additives. Moreover, the paper warns of the thermodynamic effects deriving from adding to CO2a second characterized by a much more high critical temperature, such as the occurrence of infinite-pressure critical points and multiple-phase liquid-liquid and vapor-liquid critical points. Finally, the paper analyses the thermodynamic properties of a high-critical temperature CO2-based mixture, suitable for these applications, that presents multiple phase critical points. In this regard, it is specified that the paper also aims at filling a knowledge gap in the study of thermodynamic properties of mixtures presenting how do enthalpy and specific volume change in response to pressure variations in the event of liquid-liquid and vapour-liquid critical points. Finally, we present the comparison between performances of power cycles which use, as working fluid, either pure CO2or the novel designed higher temperature CO2-based mixture
Spectral shapes of solid neon
We present a Path Integral Monte Carlo calculation of the first three moments
of the displacement-displacement correlation functions of solid neon at
different temperatures for longitudinal and transverse phonon modes. The
Lennard-Jones potential is considered. The relevance of the quantum effects on
the frequency position of the peak and principally on the line-width of the
spectral shape is clearly pointed out. The spectrum is reconstructed via a
continued fraction expansion; the approximations introduced using the effective
potential quantum molecular dynamics are discussed.Comment: 3 pages, 2 figures, 3 table
Relationship between physical activity and cardiovascular disease: selected historical highlights
Dynamics of charge-displacement channeling in intense laser-plasma interactions
The dynamics of transient electric fields generated by the interaction of
high intensity laser pulses with underdense plasmas has been studied
experimentally with the proton projection imaging technique. The formation of a
charged channel, the propagation of its front edge and the late electric field
evolution have been characterised with high temporal and spatial resolution.
Particle-in-cell simulations and an electrostatic, ponderomotive model
reproduce the experimental features and trace them back to the ponderomotive
expulsion of electrons and the subsequent ion acceleration.Comment: 5 figures, accepted for publication in New Journal of Physic
Hallux valgus and fusion of the middle phalange of V ray
Hallux valgus (HV) is a foot deformity commonly seen in medical practice, often accompanied by significant functional disability and foot pain. Its prevalence in the adult population is in 23% in adults (18-65 years) and 35.7% in elderly people (over 65 years) and is higher in females (30% compared to males 13%). The anatomical variation of the lateral rays has been ascribed to the process of involution of the feet and of its functions and actions. The intermediate phalanges of the V ray can be fused or also reduced in volume. The aim of the study was to evaluate a possible association between HV and anatomical variation of V ray. The standard radiographs of 100 patients (M 21, F 79, mean age 53y) with clinical diagnosis of HV were analysed. The HV angle was 29.84 (range 16.9 - 62,5), the 1-2 intermetatarsal angle was 10.92 (range 6.93-16.63) and the hallux interphalangeal angle was 10.55 (range 1,8 – 35.3). In 98% of cases there was the presence of fusion of the phalanges. A series of 100 consecutive patients (M 25, F 75, mean age 48y) were also analysed and basing on the review of the standard radiographs the fusion of the middle phalange was found in 42% of cases. There are conflicting notions about aetiology of HV as well. Occupation, shoe wear, genetic predisposition, and pes planus have been implicated. Our study show a strong association between the HV and fusion of the middle phalange. The presence of an anatomical variation of the V ray could modify the biodynamic of the walk and consequently influence the development and progression of the HV
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