32 research outputs found
Original Monte Carlo Method for Analysis of Oxygen Mobility in Complex Oxides by Simulation of Oxygen Isotope Exchange Data
internationa
Influence of the mobility of oxygen on the reactivity of La1-x Sr (x) MnO3 perovskites in methane oxidation
Radically different dependences of the activity of La1 - x Sr (x) MnO3 (x = 0-0.5) perovskites in methane oxidation on the degree of substitution of strontium for lanthanum are observed for low and high temperatures. Unsubstituted LaMnO3 exhibits the highest activity in the temperature range from 300 to 500A degrees C, while the sample with the maximum degree of substitution (La0.5Sr0.5MnO3) shows the highest activity at higher temperatures of 700-900A degrees C. In the low temperature region, the activity of La1t - x Sr (x) MnO3 is determined by the amount of weakly bound (overstoichiometric) oxygen, which is formed in cation-deficient lattices and is characterized by a thermal desorption peak with T (max) = 705A degrees C. At higher temperatures (800-900A degrees C), the strongly bound oxygen of the catalyst lattice is involved in the formation of the reaction products under both unsteady- and steady-state conditions. As a consequence, the catalytic activity in methane oxidation correlates with the apparent rate constant of oxygen diffusion in the oxide bulk
On the role of oxygen in the reaction of selective NO reduction with methane over Co/ZSM-5 catalyst
Mechanism and kinetics of the selective NO reduction over Co-ZSM-5 studied by the SSITKA technique
Mechanistic Study on the Selective Oxidation of Acrolein to Acrylic Acid concerning the Role of Water
Investigation of unsteady-state redox mechanisms over ceria based catalysts for partial oxidation of methane and water gas shift
internationalInternational audienc