1,104 research outputs found
Exotics Searches at ATLAS
While the Standard Model of particle physics is a very successful theory and
has been tested to hold with great precision in numerous experiments, it still
leaves a number of open questions. Among those are the matter-antimatter
asymmetry in the universe, the hierarchy problem and dark matter. Many models
for new physics beyond the Standard Model provide solutions to one or several
of these shortcomings of the Standard Model. In this article, a selected subset
of recent ATLAS results from searches for such models is high-lighted, with a
special focus on searches for Dark Matter.Comment: 13 pages, 12 figures, to appear in the proceedings of the Interplay
between Particle and Astroparticle Physics workshop, 18 - 22 August, 2014,
held at Queen Mary University of London, UK; added references, contents
unchange
Physical properties and lattice dynamics of bixbyite-type V2O3
Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugĂ€nglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.Some time ago, we reported the synthesis of bixbyite-type V2O3, a new metastable polymorph of vanadium sesquioxide. Since, a number of investigations followed, dealing with different aspects like electronic and magnetic properties of the material, the deviation from ideal stoichiometry or the preparation of nanocrystals as oxygen storage material. However, most of the physical properties were only evaluated on a theoretical basis. Here, we report the lattice dynamics and physical properties of bixbyite-type V2O3 bulk material, which we acquired from physical property measurements and neutron diffraction experiments over a wide temperature range. Besides attributing different possible orientations of the magnetic moments for V1 and V2 to the identified antiferromagnetic (AFM) ground state with a NĂ©el temperature of 38.1(5) K, we use a first order GrĂŒneisen approximation to determine lattice-dependent parameters for the relatively stiff cubic lattice, and, amongst others identify the Debye temperature to be as low as 350 ± 65 K.DFG, 73789094, SPP 1415: Kristalline Nichtgleichgewichtsphasen - PrĂ€paration, Charakterisierung und in situ-Untersuchung der Bildungsmechanisme
Mechanochemical Synthesis of Cu2MgSn3S8 and Ag2MgSn3S8
Two new thiospinels of the type AI2BIICIV3SVI8 were successfully synthesized via a mechanochemical route using binary sulfides and sulfur. Cu2MgSn3S8 and Ag2MgSn3S8 are the first AI2BIICIV3SVI8 compounds with magnesium as divalent cation. The crystal structures of Cu2MgSn3S8 and Ag2MgSn3S8 were refined in the cubic space group Fd3m using Xâray powder diffraction. According to UV/Vis measurements, a direct optical bandgap of ca. 1.65 eV was determined for both Cu2MgSn3S8 and Ag2MgSn3S8. Temperatureâdependent magnetic susceptibility measurements of the Cu2MgSn3S8 sample indicate diamagnetism. A 119Sn Mössbauer spectrum confirms the tetravalent state of tin, underlining the electronâprecise description.TU Berlin, Open-Access-Mittel - 202
Valence modulations in CeRuSn
CeRuSn exhibits an extraordinary room temperature structure at 300~K with
coexistence of two types of Ce ions, namely trivalent Ce and
intermediate valent Ce, in a metallic environment. The ordered
arrangement of these two Ce types on specific crystallographic sites results in
a doubling of the unit cell along the -axis with respect to the basic
monoclinic CeCoAl-type structure. Below room temperature, structural modulation
transitions with very broad hysteresis have been reported from measurements of
various bulk properties. X-ray diffraction revealed that at low temperatures
the doubling of the CeCoAl type structure is replaced by a different modulated
ground state, approximating a near tripling of the basic CeCoAl cell. The
transition is accompanied by a significant contraction of the axis. We
present new x-ray absorption near-edge spectroscopy data at the Ce L
absorption edge, measured on a freshly cleaved surface of a CeRuSn single
crystal. In contrast to a previous report, the new data exhibit small but
significant variations as function of temperature that are consistent with a
transition of a fraction of Ce ions to the intermediate valence state,
analogous to the transition in elemental cerium,
when cooling through the structural transitions of CeRuSn. Such results in a
valence-modulated state
YbPtPb: Magnetic frustration in the Shastry-Sutherland lattice
We have synthesized single crystals of YbPtPb, which crystallize
in the layered UPtSn-type structure, where planes of Yb ions lie on
a triangular network. We report here the first results of magnetization,
specific heat, and electrical resistivity experiments. The lattice constants
and high temperature magnetic susceptibility indicate that the Yb ions are
trivalent, while Schottky peaks in the specific heat show that the ground state
is a well isolated doublet. Significant magnetic anisotropy is observed, with
the ratio of susceptibilities perpendicular and parallel to the magnetic planes
differing by as much as a factor of 30 at the lowest temperatures.
Antiferromagnetic order occurs at a N\'eel temperature =2.07 K, a
transition temperature which is more than an order of magnitude smaller than
the mean field interactions reflected by the in-plane Weiss temperature.
Further evidence for short ranged magnetic fluctuations is found in the
magnetic susceptibility and electrical resistivity, which have broad peaks
above , and in the slow development of the magnetic entropy at
. Our experiments indicate that YbPtPb is a quasi-two
dimensional and localized moment system, where strong magnetic frustration may
arise from the geometry of the underlying Shastry-Sutherland lattice.Comment: 8 pages, 8 figure
Mixed Valence Europium Nitridosilicate Eu2SiN3
The mixed valence europium nitridosilicate Eu2SiN3 has been synthesized at 900°C in welded tantalum ampules starting from europium and silicon diimide Si(NH)2 in a lithium flux. The structure of the black material has been determined by single-crystal X-ray diffraction analysis (Cmca (no. 64), a=542.3(11) pm, b=1061.0(2) pm, c=1162.9(2) pm, Z=8, 767 independent reflections, 37 parameters, R1=0.017, wR2=0.032). Eu2SiN3 is a chain-type silicate comprising one-dimensional infinite nonbranched zweier chains of corner-sharing SiN4 tetrahedra running parallel [100] with a maximum stretching factor fs=1.0. The compound is isostructural with Ca2PN3 and Rb2TiO3, and it represents the first example of a nonbranched chain silicate in the class of nitridosilicates. There are two crystallographically distinct europium sites (at two different Wyckoff positions 8f) being occupied with Eu2+ and Eu3+, respectively. 151Eu Mössbauer spectroscopy of Eu2SiN3 differentiates unequivocally these two europium atoms and confirms their equiatomic multiplicity, showing static mixed valence with a constant ratio of the Eu2+ and Eu3+ signals over the whole temperature range. The Eu2+ site shows magnetic hyperfine field splitting at 4.2 K. Magnetic susceptibility measurements exhibit Curie-Weiss behavior above 24 K with an effective magnetic moment of 7.5 ÎŒB/f.u. and a small contribution of Eu3+, in accordance with Eu2+ and Eu3+ in equiatomic ratio. Ferromagnetic ordering at unusually high temperature is detected at TC=24 K. DFT calculations of Eu2SiN3 reveal a band gap of âŒ0.2 eV, which is in agreement with the black color of the compound. Both DFT calculations and lattice energetic calculations (MAPLE) corroborate the assignment of two crystallographically independent Eu sites to Eu2+ and Eu3+
Magnetoresistance, specific heat and magnetocaloric effect of equiatomic rare-earth transition-metal magnesium compounds
We present a study of the magnetoresistance, the specific heat and the
magnetocaloric effect of equiatomic Mg intermetallics with , Eu, Gd, Yb and , Au and of GdAuIn. Depending on the
composition these compounds are paramagnetic (, Yb) or they
order either ferro- or antiferromagnetically with transition temperatures
ranging from about 13 to 81 K. All of them are metallic, but the resistivity
varies over 3 orders of magnitude. The magnetic order causes a strong decrease
of the resistivity and around the ordering temperature we find pronounced
magnetoresistance effects. The magnetic ordering also leads to well-defined
anomalies in the specific heat. An analysis of the entropy change leads to the
conclusions that generally the magnetic transition can be described by an
ordering of localized moments arising from the half-filled
shells of Eu or Gd. However, for GdAgMg we find clear evidence
for two phase transitions indicating that the magnetic ordering sets in
partially below about 125 K and is completed via an almost first-order
transition at 39 K. The magnetocaloric effect is weak for the antiferromagnets
and rather pronounced for the ferromagnets for low magnetic fields around the
zero-field Curie temperature.Comment: 12 pages, 7 figures include
Searching for hexagonal analogues of the half-metallic half-Heusler XYZ compounds
The XYZ half-Heusler crystal structure can conveniently be described as a
tetrahedral zinc blende YZ structure which is stuffed by a slightly ionic X
species. This description is well suited to understand the electronic structure
of semiconducting 8-electron compounds such as LiAlSi (formulated
Li[AlSi]) or semiconducting 18-electron compounds such as TiCoSb
(formulated Ti[CoSb]). The basis for this is that [AlSi]
(with the same electron count as Si) and [CoSb] (the same electron
count as GaSb), are both structurally and electronically, zinc-blende
semiconductors. The electronic structure of half-metallic ferromagnets in this
structure type can then be described as semiconductors with stuffing magnetic
ions which have a local moment: For example, 22 electron MnNiSb can be written
Mn[NiSb]. The tendency in the 18 electron compound for a
semiconducting gap -- believed to arise from strong covalency -- is carried
over in MnNiSb to a tendency for a gap in one spin direction. Here we similarly
propose the systematic examination of 18-electron hexagonal compounds for
semiconducting gaps; these would be the "stuffed wurtzite" analogues of the
"stuffed zinc blende" half-Heusler compounds. These semiconductors could then
serve as the basis for possibly new families of half-metallic compounds,
attained through appropriate replacement of non-magnetic ions by magnetic ones.
These semiconductors and semimetals with tunable charge carrier concentrations
could also be interesting in the context of magnetoresistive and thermoelectric
materials.Comment: 11 pages, 6 figures, of which 4 are colou
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