2,947 research outputs found
Structural Features of Layered Iron Pnictide Oxides (Fe2As2)(Sr4M2O6)
Structural features of newly found perovskite-based iron pnictide oxide
system have been systematically studied. Compared to REFePnO system,
perovskite-based system tend to have lower Pn-Fe-Pn angle and higher pnictogen
height owing to low electronegativity of alkaline earth metal and small
repulsive force between pnictogen and oxygen atoms. As-Fe-As angles of
(Fe2As2)(Sr4Cr2O6), (Fe2As2)(Sr4V2O6) and (Fe2Pn2)(Sr4MgTiO6) are close to
ideal tetrahedron and those pnictogen heights of about 1.40 A are close to
NdFeAsO with optimized carrier concentration. These structural features of this
system may leads to realization of high Tc superconductivity.Comment: 3pages, 2figures, 1table, proceedings of M2S 200
Superconductivity at 38 K in Iron-Based Compound with Platinum-Arsenide Layers Ca10(Pt4As8)(Fe2-xPtxAs2)5
We report superconductivity in novel iron-based compounds
Ca10(PtnAs8)(Fe2-xPtxAs2)5 with n = 3 and 4. Both compounds crystallize in
triclinic structures (space group P-1), in which Fe2As2 layers alternate with
PtnAs8 spacer layers. Superconductivity with a transition temperature of 38 K
is observed in the n = 4 compound with a Pt content of x ~ 0.36 in the Fe2As2
layers. The compound with n = 3 exhibits superconductivity at 13 K.Comment: OPEN SELECT article, 11 pages, 5 figures, 2 table
Pressure Dependence of Superconducting Transition Temperature on Perovskite-Type Fe-Based Superconductors and NMR Study of Sr2VFeAsO3
We report the pressure dependences of the superconducting transition
temperature (T_c) in several perovskite-type Fe-based superconductors through
the resistivity measurements up to ~4 GPa. In Ca_4(Mg,Ti)_3Fe_2As_2O_y with the
highest T_c of 47 K in the present study, the T_c keeps almost constant up to
~1 GPa, and starts to decrease above it. From the comparison among several
systems, we obtained a tendency that low T_c with the longer a-axis length at
ambient pressure increases under pressure, but high T_c with the shorter a-axis
length at ambient pressure hardly increases. We also report the ^75As-NMR
results on Sr_2VFeAsO_3. NMR spectrum suggests that the magnetic ordering
occurs at low temperatures accompanied by some inhomogeneity. In the
superconducting state, we confirmed the anomaly by the occurrence of
superconductivity in the nuclear spin lattice relaxation rate 1/T_1, but the
spin fluctuations unrelated with the superconductivity are dominant. It is
conjectured that the localized V-3d moments are magnetically ordered and their
electrons do not contribute largely to the Fermi surface and the
superconductivity in Sr_2VFeAsO_3.Comment: 7 pages, 9 figure
Effects of metallic spacer in layered superconducting Sr2(MgTi)O3FeAs
The highly two-dimensional superconducting system
Sr2(MgTi)O3FeAs, recently synthesized in the range of 0.2 < y <
0.5, shows an Mg concentration-dependent . Reducing the Mg concentration
from y=0.5 leads to a sudden increase in , with a maximum ~40 K at
y=0.2. Using first principles calculations, the unsynthesized stoichiometric
y=0 and the substoichiometric y=0.5 compounds have been investigated. For the
50% Mg-doped phase (y=0.5), Sr2(MgTi)O3 layers are completely
insulating spacers between FeAs layers, leading to the fermiology such as that
found for other Fe pnictides. At y=0, representing a phase with metallic
Sr2TiO3 layers, the -centered Fe-derived Fermi surfaces (FSs)
considerably shrink or disappear. Instead, three -centered Ti FSs
appear, and in particular two of them have similar size, like in MgB2.
Interestingly, FSs have very low Fermi velocity in large fractions: the lowest
being 0.6 cm/s. Furthermore, our fixed spin moment calculations
suggest the possibility of magnetic ordering, with magnetic Ti and nearly
nonmagnetic Fe ions. These results indicate a crucial role of
Sr2(MgTi)O3 layers in this superconductivity.Comment: 7 pages; Proceedings of ICSM-201
Evolution of superconductivity by oxygen annealing in FeTe0.8S0.2
Oxygen annealing dramatically improved the superconducting properties of
solid-state-reacted FeTe0.8S0.2, which showed only a broad onset of
superconducting transition just after the synthesis. The zero resistivity
appeared and reached 8.5 K by the oxygen annealing at 200\degree C. The
superconducting volume fraction was also enhanced from 0 to almost 100%. The
lattice constants were compressed by the oxygen annealing, indicating that the
evolution of bulk superconductivity in FeTe0.8S0.2 was correlated to the
shrinkage of lattice.Comment: 13 pages, 6 figure
Microscopic analysis of the chemical reaction between Fe(Te,Se) thin films and underlying CaF
To understand the chemical reaction at the interface of materials, we
performed a transmission electron microscopy (TEM) observation in four types of
Fe(Te,Se) superconducting thin films prepared on different types of substrates:
CaF2 substrate, CaF2 substrate with a CaF2 buffer layer, CaF2 substrate with a
FeSe buffer layer, and a LaAlO3 substrate with a CaF2 buffer layer. Based on
the energy-dispersive X-ray spectrometer (EDX) analysis, we found possible
interdiffusion between fluorine and selenium that has a strong influence on the
superconductivity in Fe(Te,Se) films. The chemical interdiffusion also plays a
significant role in the variation of the lattice parameters. The lattice
parameters of the Fe(Te,Se) thin films are primarily determined by the chemical
substitution of anions, and the lattice mismatch only plays a secondary role.Comment: 30 pages, 9 figur
Evidence for Nodal superconductivity in SrScFePO
Point contact Andreev reflection spectra have been taken as a function of
temperature and magnetic field on the polycrystalline form of the newly
discovered iron-based superconductor Sr2ScFePO3. A zero bias conductance peak
which disappears at the superconducting transition temperature, dominates all
of the spectra. Data taken in high magnetic fields show that this feature
survives until 7T at 2K and a flattening of the feature is observed in some
contacts. Here we inspect whether these observations can be interpreted within
a d-wave, or nodal order parameter framework which would be consistent with the
recent theoretical model where the height of the P in the Fe-P-Fe plane is key
to the symmetry of the superconductivity. However, in polycrystalline samples
care must be taken when examining Andreev spectra to eliminate or take into
account artefacts associated with the possible effects of Josephson junctions
and random alignment of grains.Comment: Published versio
Contrasting Pressure Effects in Sr2VFeAsO3 and Sr2ScFePO3
We report the resistivity measurements under pressure of two Fe-based
superconductors with a thick perovskite oxide layer, Sr2VFeAsO3 and Sr2ScFePO3.
The superconducting transition temperature Tc of Sr2VFeAsO3 markedly increases
with increasing pressure. Its onset value, which was Tc{onset}=36.4 K at
ambient pressure, increases to Tc{onset}=46.0 K at ~4 GPa, ensuring the
potential of the "21113" system as a high-Tc material. However, the
superconductivity of Sr2ScFePO3 is strongly suppressed under pressure. The
Tc{onset} of ~16 K decreases to ~5 K at ~4 GPa, and the zero-resistance state
is almost lost. We discuss the factor that induces this contrasting pressure
effect.Comment: 5 pages, 4 figures, to be published in J. Phys. Soc. Jpn. No.12
(2009
18q loss of heterozygosity in microsatellite stable colorectal cancer is correlated with CpG island methylator phenotype-negative (CIMP-0) and inversely with CIMP-low and CIMP-high
<p>Abstract</p> <p>Background:</p> <p>The CpG island methylator phenotype (CIMP) with widespread promoter methylation is a distinct epigenetic phenotype in colorectal cancer, associated with microsatellite instability-high (MSI-high) and <it>BRAF </it>mutations. 18q loss of heterozygosity (LOH) commonly present in colorectal cancer with chromosomal instability (CIN) is associated with global hypomethylation in tumor cell. A recent study has shown an inverse correlation between CIN and CIMP (determined by MINTs, p16, p14 and <it>MLH1 </it>methylation) in colorectal cancer. However, no study has examined 18q LOH in relation to CIMP-high, CIMP-low (less extensive promoter methylation) and CIMP-0 (CIMP-negative), determined by quantitative DNA methylation analysis.</p> <p>Methods:</p> <p>Utilizing MethyLight technology (real-time PCR), we quantified DNA methylation in 8 CIMP-specific promoters {<it>CACNA1G</it>, <it>CDKN2A </it>(p16), <it>CRABP1, IGF2</it>, <it>MLH1, NEUROG1, RUNX3 </it>and <it>SOCS1</it>} in 758 non-MSI-high colorectal cancers obtained from two large prospective cohorts. Using four 18q microsatellite markers (D18S55, D18S56, D18S67 and D18S487) and stringent criteria for 18q LOH, we selected 374 tumors (236 LOH-positive tumors with ≥ 2 markers showing LOH; and 138 LOH-negative tumors with ≥ 3 informative markers and no LOH).</p> <p>Results:</p> <p>CIMP-0 (0/8 methylated promoters) was significantly more common in 18q LOH-positive tumors (59% = 139/236, p = 0.002) than 18q LOH-negative tumors (44% = 61/138), while CIMP-low/high (1/8–8/8 methylated promoters) was significantly more common (56%) in 18q LOH-negative tumors than 18q LOH-positive tumors (41%). These relations persisted after stratification by sex, location, or the status of MSI, p53 expression (by immunohistochemistry), or <it>KRAS/BRAF </it>mutation.</p> <p>Conclusion:</p> <p>18q LOH is correlated positively with CIMP-0 and inversely with CIMP-low and CIMP-high. Our findings provide supporting evidence for relationship between CIMP-0 and 18q LOH as well as a molecular difference between CIMP-0 and CIMP-low in colorectal cancer.</p
First-principles Electronic Structure of Superconductor CaAlOFeP: Comparison with LaFePO and CaAlOFeAs
We investigate the electronic structures of iron-based superconductors having
perovskite-like blocking layers, %CaAlOFe(AsP)
from first principles. CaAlOFeP and
CaAlOFeAs from first principles.
CaAlOFeP is found to have two hole-like Fermi surfaces
around , and one hole-like Fermi surface around M in the unfolded
Brillouin zone. This is in contrast with LaFePO, where no Fermi surface is
found around M. The relationship of their band structures and measured
transition temperatures of superconductivity is discussed. The number of Fermi
surfaces in CaAlOFeP is also different from that of
CaAlOFeAs, in which only one Fermi surface is formed around
. Analysis using maximally localized Wannier functions clarifies that
the differences between their band structures originate mainly from the
pnictogen height. We then analyze the alloying effect on the electronic
structure of CaAlOFeAsP. It is found that its electronic
structure is similar to that of CaAlOFeP and
CaAlOFeAs with the average crystal structure, though
CaAlOFeAsP contains the pnictogen height disorder. We calculate
the generalized susceptibility for CaAlOFe(AsP)
and clarify the factors determining its tendency.Comment: 5 figures, to be published in J. Phys. Soc. Jp
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