Electronic structure and effects of dynamical electron correlation in ferromagnetic bcc-Fe, fcc-Ni and antiferromagnetic NiO

LDA+DMFT method in the framework of the iterative perturbation theory (IPT) with full LDA Hamiltonian without mapping onto the effective Wannier orbitals. We then apply this LDA+DMFT method to ferromagnetic bcc-Fe and fcc-Ni as a test of transition metal, and to antiferromagnetic NiO as an example of transition metal oxide. In Fe and Ni, the width of occupied 3d bands is narrower than those in LDA and Ni 6eV satellite appears. In NiO, the resultant electronic structure is of charge-transfer insulator type and the band gap is 4.3eV. These results are in good agreement with the experimental XPS. The configuration mixing and dynamical correlation effects play a crucial role in these results

Prostate-specific antigen, Gleason sum and clinical T stage for predicting the need for radionuclide bone scan for prostate cancer patients in Japan

The definitive version is available at www.blackwell-synergy.com.ArticleINTERNATIONAL JOURNAL OF UROLOGY. 12(8): 728-732 (2005)journal articl

Effects of goshajinkigan (Niu-Che-Sen-Qi-Wan) for resiniferatoxin-sensitive afferents on detrusor overactivity induced by acetic acid in conscious rats

Electronic version of an article published as [AMERICAN JOURNAL OF CHINESE MEDICINE, 34, 2, 2006, 285-293] [doi:10.1142/S0192415X06003837] © [copyright World Scientific Publishing Company] [http://www.worldscinet.com/ajcm/ajcm.shtml]ArticleAmerican Journal of Chinese Medicine. 34(2): 285-293 (2006)journal articl

Variable coordination of amine functionalised N-heterocyclic carbene ligands to Ru, Rh and Rr: C-H and N-H activation and catalytic transfer hydrogenation

Chelating amine and amido complexes of late transition metals are highly valuable bifunctional catalysts in organic synthesis, but complexes of bidentate amine–NHC and amido–NHC ligands are scarce. Hence, we report the reactions of a secondary-amine functionalised imidazolium salt 2a and a primary-amine functionalised imidazolium salt 2b with [( p -cymene)RuCl 2 ] 2 and [Cp*MCl 2 ] 2 (M = Rh, Ir). Treating 2a with [Cp*MCl 2 ] 2 and NaOAc gave the cyclometallated compounds Cp*M(C,C)I (M = Rh, 3 ;M = Ir, 4 ), resulting from aromatic C–H activation. In contrast, treating 2b with [( p -cymene)RuCl 2 ] 2 ,Ag 2 O and KI gave the amine–NHC complex [( p -cymene)Ru(C,NH 2 )I]I ( 5 ). The reaction of 2b with [Cp*MCl 2 ] 2 (M = Rh, Ir), NaO t Bu and KI gave the amine–NHC complex [Cp*Rh(NH 2 )I]I ( 6 ) or the amido–NHC complex Cp*Ir(C,NH)I ( 7 ); both protonation states of the Ir complex could be accessed: treating 7 with trifluoroacetic acid gave the amine–NHC complex [Cp*Ir(C,NH 2 )I][CF 3 CO 2 ]( 8 ). These are the first primary amine– or amido–NHC complexes of Rh and Ir. Solid-state structures of the complexes 3–8 have been determined by single crystal X-ray diffraction. Complexes 5 , 6 and 7 are pre-catalysts for the catalytic transfer hydrogenation of acetophenone to 1-phenylethanol, with ruthenium complex 5 demonstrating especially high reactivity

Extracellular matrix signatures of human primary metastatic colon cancers and their metastases to liver

Background: Colorectal cancer is the third most frequently diagnosed cancer and the third cause of cancer deaths in the United States. Despite the fact that tumor cell-intrinsic mechanisms controlling colorectal carcinogenesis have been identified, novel prognostic and diagnostic tools as well as novel therapeutic strategies are still needed to monitor and target colon cancer progression. We and others have previously shown, using mouse models, that the extracellular matrix (ECM), a major component of the tumor microenvironment, is an important contributor to tumor progression. In order to identify candidate biomarkers, we sought to define ECM signatures of metastatic colorectal cancers and their metastases to the liver. Methods: We have used enrichment of extracellular matrix (ECM) from human patient samples and proteomics to define the ECM composition of primary colon carcinomas and their metastases to liver in comparison with normal colon and liver samples. Results: We show that robust signatures of ECM proteins characteristic of each tissue, normal and malignant, can be defined using relatively small samples from small numbers of patients. Comparisons with gene expression data from larger cohorts of patients confirm the association of subsets of the proteins identified by proteomic analysis with tumor progression and metastasis. Conclusions: The ECM protein signatures of metastatic primary colon carcinomas and metastases to liver defined in this study, offer promise for development of diagnostic and prognostic signatures of metastatic potential of colon tumors. The ECM proteins defined here represent candidate serological or tissue biomarkers and potential targets for imaging of occult metastases and residual or recurrent tumors and conceivably for therapies. Furthermore, the methods described here can be applied to other tumor types and can be used to investigate other questions such as the role of ECM in resistance to therapy

Thermal Bogoliubov transformation in nuclear structure theory

Thermal Bogoliubov transformation is an essential ingredient of the thermo field dynamics -- the real time formalism in quantum field and many-body theories at finite temperatures developed by H. Umezawa and coworkers. The approach to study properties of hot nuclei which is based on the extension of the well-known Quasiparticle-Phonon Model to finite temperatures employing the TFD formalism is presented. A distinctive feature of the QPM-TFD combination is a possibility to go beyond the standard approximations like the thermal Hartree-Fock or the thermal RPA ones.Comment: 8 pages, Proceedings of the International Bogolyubov Conference "Problems of Theoretical and Mathematical Physics", August 23 -- 27, 2009, Dubna, Russi

Stripe order, depinning, and fluctuations in La1.875_{1.875}Ba0.125_{0.125}CuO4_{4} and La1.875_{1.875}Ba0.075_{0.075}Sr0.050_{0.050}CuO4_{4}

We present a neutron scattering study of stripe correlations measured on a single crystal of La$_{1.875}$Ba$_{0.125}$CuO$_{4}$. Within the low-temperature-tetragonal (LTT) phase, superlattice peaks indicative of spin and charge stripe order are observed below 50 K. For excitation energies $\hbar\omega\le12$ meV, we have characterized the magnetic excitations that emerge from the incommensurate magnetic superlattice peaks. In the ordered state, these excitations are similar to spin waves. Following these excitations as a function of temperature, we find that there is relatively little change in the {\bf Q}-integrated dynamical spin susceptibility for $\hbar\omega\sim10$ meV as stripe order disappears and then as the structure transforms from LTT to the low-temperature-orthorhombic (LTO) phase. The {\bf Q}-integrated signal at lower energies changes more dramatically through these transitions, as it must in a transformation from an ordered to a disordered state. We argue that the continuous evolution through the transitions provides direct evidence that the incommensurate spin excitations in the disordered state are an indicator of dynamical charge stripes. An interesting feature of the thermal evolution is a variation in the incommensurability of the magnetic scattering. Similar behavior is observed in measurements on a single crystal of La$_{1.875}$Ba$_{0.075}$Sr$_{0.050}$CuO$_{4}$; maps of the scattered intensity in a region centered on the antiferromagnetic wave vector and measured at $\hbar\omega=4$ meV are well reproduced by a model of disordered stripes with a temperature-dependent mixture of stripe spacings. We discuss the relevance of our results to understanding the magnetic excitations in cuprate superconductors.Comment: 12 pages, 11 figures, 1 tabl

New insight on pseudospin doublets in nuclei

The relevance of the pseudospin symmetry in nuclei is considered. New insight is obtained from looking at the continuous transition from a model satisfying the spin symmetry to another one satisfying the pseudospin symmetry. This study suggests that there are models allowing no missing single-particle states in this transition, contrary to what is usually advocated. It rather points out to an association of pseudospin partners different from the one usually assumed, together with a strong violation of the corresponding symmetry. A comparison with results obtained from some relativistic approaches is made.Comment: 27 pages, 18 figure

Influence of random point defects introduced by proton irradiation on critical current density and vortex dynamics of Ba(Fe0.925Co0.075)2As2 single crystals

In this work we analyze the influence of random point defects introduced by 3 MeV proton irradiation on the critical current density (Jc) and vortex dynamics of a Ba(Fe0.925Co0.075)2As2 single crystal. The results show that at low temperatures (T) the irradiation produces an enhancement of Jc of up to 2.6 times. However the Jc (T) retention at different magnetic fields (H) in the elastic regime, estimated by the n exponent in Jc vs (1-(T/Tc)2)n, is poorer after the irradiations, due to the thermal softening of the pinning by the random point defects. We found that the elastic to plastic crossover and melting lines are only affected by the reduction of the superconducting critical temperature (Tc); they are exactly the same after rescaling the phase diagram by T/Tc. The pinning mechanisms in the single crystals can be associated with a mixed pinning landscape that produces a modulation in S(H,T) as a consequence of a fishtail or second peak in the magnetization.Fil: Haberkorn, Nestor Fabian. Los Alamos National Laboratory; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Maiorov, B.. Los Alamos National Laboratory; Estados UnidosFil: Usov, I. O.. Los Alamos National Laboratory; Estados UnidosFil: Weigand, M.. Los Alamos National Laboratory; Estados UnidosFil: Hirata, W.. Osaka University; JapónFil: Miyasaka, S.. Osaka University; JapónFil: Tajima, S.. Osaka University; JapónFil: Chikumoto, N.. International Superconductivity Technology Center. Superconductivity Research Laboratory; JapónFil: Tanabe, K.. International Superconductivity Technology Center. Superconductivity Research Laboratory; JapónFil: Civale, Leonardo. Los Alamos National Laboratory; Estados Unido

On the extraction of electromagnetic properties of the Delta(1232) excitation from pion photoproduction

Several methods for the treatment of pion photoproduction in the region of the Delta(1232) resonance are discussed, in particular the effective Lagrangian approach and the speed plot analysis are compared to a dynamical treatment. As a main topic, we discuss the extraction of the genuine resonance parts of the magnetic dipole and electric quadrupole multipoles of the electromagnetic excitation of the resonance. To this end, we try to relate the various values for the ratio R_{EM} of the E2 to M1 multipole excitation strengths for the Delta(1232) resonance as extracted by the different methods to corresponding ratios of a dynamical model. Moreover, it is confirmed that all methods for extracting resonance properties suffer from an unitary ambiguity which is due to some phenomenological contributions entering the models.Comment: 22 pages revtex including 7 postscript figure