26 research outputs found
Die EG-Umwelt-Audit-Verordnung - Anreiz zu Innovationen oder zu potemkinschen Dialogen?
Since 13 July 1993 the EC eco-audit regulation has regulated voluntary participation of enterprises in eco-auditing. As. yet it is a vague plan for environmental management systems and eco-auditing of enterprises, which in practice, when it comes to implementing it, may be interpreted in many different ways. The European Council's aim of promoting a steady improvement of environmental standards in enterprises with the help of this regulation can only be achieved in part. It is to be feared that instead of the desired problem-oriented analysis of weaknesses, an objective-oriented approach to secure a document certifying participation will prevail on the part of the enterprises. The inadequate description of the nature of the auditing may result in a watering down of the requirements. Such a development in terms of the implementation could tarnish the public image of this tool designed for environmental protection and lead people to consider it a swiz. To prevent this from happening the further elaboration of the regulation should continue to be a dynamic Iearning process, taking into account future practical experience. Moreover, eco-audits must not be regarded as substitutes for necessary tools of a market economy in the sphere of environmental policy
Die EG-Umwelt-Audit-Verordnung - Anreiz zu Innovationen oder zu potemkinschen Dialogen?
Since 13 July 1993 the EC eco-audit regulation has regulated voluntary participation of enterprises in eco-auditing. As. yet it is a vague plan for environmental management systems and eco-auditing of enterprises, which in practice, when it comes to implementing it, may be interpreted in many different ways. The European Council's aim of promoting a steady improvement of environmental standards in enterprises with the help of this regulation can only be achieved in part. It is to be feared that instead of the desired problem-oriented analysis of weaknesses, an objective-oriented approach to secure a document certifying participation will prevail on the part of the enterprises. The inadequate description of the nature of the auditing may result in a watering down of the requirements. Such a development in terms of the implementation could tarnish the public image of this tool designed for environmental protection and lead people to consider it a swiz. To prevent this from happening the further elaboration of the regulation should continue to be a dynamic Iearning process, taking into account future practical experience. Moreover, eco-audits must not be regarded as substitutes for necessary tools of a market economy in the sphere of environmental policy. --
Micro- and nanostructures reflect the degree of diagenetic alteration in modern and fossil brachiopod shell calcite: A multi-analytical screening approach (CL, FE-SEM, AFM, EBSD)
Fossil carbonate skeletons of marine organisms are archives for understanding the development and evolution of
palaeo-environments. However, the correct assessment of past environment dynamics is only possible when
pristine skeletons and their biogenic characteristics are unequivocally distinguishable from diagenetically-alteredskeletal elements and non-biogenic features.
In this study, we extend our work on diagenesis of biogenic aragonite (Casella et al. 2017) to the investigation of biogenic low-Mg calcite using brachiopod shells. We examined and compared microstructural characteristics inducedby laboratory-based alteration to structural features derived from diagenetic alteration in natural environments. We used four screening methods: cathodoluminescence (CL), cryogenic and conventional field emission-scanning electronmicroscopy (FE-SEM), atomic force microscopy (AFM) and electron backscatter diffraction (EBSD).We base our assessments of diagenetic alteration and overprint on measurements of, a) images of optical overprint signals, b) changes in calcite crystal orientation patterns, and c) crystal co-orientation statistics.
According to the screening process, altered and overprinted samples define two groups. In Group 1 the entire
shell is diagenetically overprinted, whereas in Group 2 the shell contains pristine as well as overprinted parts. In the case of Group 2 shells, alteration occurred either along the periphery of the shell including the primary layer or at the interior-facing surface of the fibrous/columnar layer. In addition, we observed an important mode of the overprinting process, namely the migration of diagenetic fluids through the endopunctae corroborated by mineral formation and overprinting in their immediate vicinity, while leaving shell parts between endopunctae in pristine condition.
Luminescence (CL) and microstructural imaging (FE-SEM) screening give first-order observations of the degree
of overprint as they cover macro-to micron scale alteration features. For a comprehensive assessment of
diagenetic overprint these screening methods should be complemented by screening techniques such as EBSD
and AFM. They visualise diagenetic changes at submicron and nanoscale levels depicting the replacement of
pristine nanocomposite mesocrystal biocarbonate (NMB) by inorganic rhombohedral calcite (IRC). The integration
of screening methods allows for the unequivocal identification of highly-detailed alteration features as
well as an assessment of the degree of diagenetic alteration