14 research outputs found
Second Harmonic Generation for a Dilute Suspension of Coated Particles
We derive an expression for the effective second-harmonic coefficient of a
dilute suspension of coated spherical particles. It is assumed that the coating
material, but not the core or the host, has a nonlinear susceptibility for
second-harmonic generation (SHG). The resulting compact expression shows the
various factors affecting the effective SHG coefficient. The effective SHG per
unit volume of nonlinear coating material is found to be greatly enhanced at
certain frequencies, corresponding to the surface plasmon resonance of the
coated particles. Similar expression is also derived for a dilute suspension of
coated discs. For coating materials with third-harmonic (THG) coefficient,
results for the effective THG coefficients are given for the cases of coated
particles and coated discs.Comment: 11 pages, 3 figures; accepted for publication in Phys. Rev.
Effective nonlinear optical properties of composite media of graded spherical particles
We have developed a nonlinear differential effective dipole approximation
(NDEDA), in an attempt to investigate the effective linear and third-order
nonlinear susceptibility of composite media in which graded spherical
inclusions with weak nonlinearity are randomly embedded in a linear host
medium. Alternatively, based on a first-principles approach, we derived exactly
the linear local field inside the graded particles having power-law dielectric
gradation profiles. As a result, we obtain also the effective linear dielectric
constant and third-order nonlinear susceptibility. Excellent agreement between
the two methods is numerically demonstrated. As an application, we apply the
NDEDA to investigate the surface plasma resonant effect on the optical
absorption, optical nonlinearity enhancement, and figure of merit of
metal-dielectric composites. It is found that the presence of gradation in
metal particles yields a broad resonant band in the optical region, and further
enhances the figure of merit.Comment: 20 pages, 5 figure
Dimensional Crossover in the Effective Second Harmonic Generation of Films of Random Dielectrics
The effective nonlinear response of films of random composites consisting of
a binary composite with nonlinear particles randomly embedded in a linear host
is theoretically and numerically studied. A theoretical expression for the
effective second harmonic generation susceptibility, incorporating the
thickness of the film, is obtained by combining a modified effective-medium
approximation with the general expression for the effective second harmonic
generation susceptibility in a composite. The validity of the thoretical
results is tested against results obtained by numerical simulations on random
resistor networks. Numerical results are found to be well described by our
theory. The result implies that the effective-medium approximation provides a
convenient way for the estimation of the nonlinear response in films of random
dielectrics.Comment: 9 pages, 2 figures; accepted for publication in Phys. Rev.
Optical Properties of Materials for Optical Amplifiers at 1.3 µm
We describe the preparation and near Infra-Red fluorescence characteristics of a series of transition metal (V2+, Ni2+, Cr4+) doped crystalline inorganic materials. Within isostructural series, the effect of changes in the host lattice on the transition metal fluorescence has been investigated. This allows selection and fluorescence tuning of transition metal ion/crystalline host combinations of possible use for optical amplification in the 1.31 µm telecommunication window.