High pressure melting of eclogite and metasomatism of garnet peridotites from Monte Duria Area (Central Alps, N Italy): A proxy for melt-rock reaction during subduction

In the Monte Duria area (Adula-Cima Lunga unit, Central Alps, N Italy) garnet peridotites occur in direct contact with migmatised orthogneiss (Mt. Duria) and eclogites (Borgo). Both eclogites and ultramafic rocks share a common high pressure (HP) peak at 2.8\u202fGPa and 750\u202f\ub0C and post-peak static equilibration at 0.8\u20131.0\u202fGPa and 850\u202f\ub0C. Garnet peridotites show abundant amphibole, dolomite, phlogopite and orthopyroxene after olivine, suggesting that they experienced metasomatism by crust-derived agents enriched in SiO2, K2O, CO2 and H2O. Peridotites also display LREE fractionation (La/Nd\u202f=\u202f2.4) related to LREE-rich amphibole and clinopyroxene grown in equilibrium with garnet, indicating that metasomatism occurred at HP conditions. At Borgo, retrogressed garnet peridotites show low strain domains characterised by garnet compositional layering, cut by a subsequent low-pressure (LP) chlorite foliation, in direct contact with migmatised eclogites. Kfs\u202f+\u202fPl\u202f+\u202fQz\u202f+\u202fCpx interstitial pocket aggregates and Cpx\u202f+\u202fKfs thin films around symplectites after omphacite parallel to the Zo\u202f+\u202fOmp\u202f+\u202fGrt foliation in the eclogites suggest that they underwent partial melting at HP. The contact between garnet peridotites and eclogites is marked by a tremolitite layer. The same rock also occurs as layers within the peridotite lens, showing a boudinage parallel to the garnet layering of peridotites, flowing in the boudin necks. This clearly indicates that the tremolitite boudins formed when peridotites were in the garnet stability field. Tremolitites also show Phl\u202f+\u202fTc\u202f+\u202fChl\u202f+\u202fTr pseudomorphs after garnet, both crystallised in a static regime postdating the boudins formation, suggesting that they derive from a garnet-bearing precursor. Tremolitites have Mg#\u202f>\u202f0.90 and Al2O3\u202f=\u202f2.75\u202fwt% pointing to ultramafic compositions but also show enrichments in SiO2, CaO, and LREE suggesting that they formed after the reaction between the eclogite-derived melt and the garnet peridotite at HP. To test this hypothesis, we performed a thermodynamic modelling at fixed P\u202f=\u202f3\u202fGPa and T\u202f=\u202f750\u202f\ub0C to model the chemical interaction between the garnet peridotite and the eclogite-derived melt. Our results show that this interaction produces an Opx\u202f+\u202fCpx\u202f+\u202fGrt assemblage plus Amp\u202f+\u202fPhl, depending on the water activity in the melt, suggesting that tremolitites likely derive from a previous garnet websterite with amphibole and phlogopite. Both peridotites and tremolitites also show a selective enrichment in LILE recorded by amphiboles in the spinel stability field, indicating that a fluid-assisted metasomatic event occurred at LP conditions, leading to the formation of a chlorite foliation post-dating the garnet layering in peridotites, and the retrogression of Grt-websterites in tremolitites. The Monte Duria area is a unique terrane where we can observe syn-deformation eclogite-derived melt interacting with garnet peridotite at HP, proxy of subduction environments

PLEISTOCENE PALAEOCLIMATIC EVOLUTION FROM AGIOS GEORGIOS CAVE SPELEOTHEM (KILKIS, N. GREECE)

Palaeoclimatic reconstruction in N. Greece has been investigated in this study, using stable isotope analyses and U/Th dating of a speleothem (stalactite) from the cave of Agios Georgios (Kilkis). Sampling sequence was followed in detail in order to obtain high resolution analysis of the proxy. Speleothem δ18O entirely depends on two factors: changes in the δ18O of the percolation waters (a proxy for local rainfall δ18O) and the temperature of water-calcite fractionation inside the cave (a proxy for outside air temperatures). During periods of relatively stable temperatures, δ13C shifts are caused principally by variations in soil CO2 input and physico-chemical processes inside the cave. More important processes affect the δ13C signal of speleothem inside the cave are length of flow path and rates of CO2 degassing.The lower δ13C calcite values indicate greater respiratory activity of soils under wetter conditions. The stalagmite layers were dated through U/Th geochronological method, which places the carbonate precipitation in Middle Pleistocene (630-300ka BP). The isotopic composition of the layers was used in combination with the dating results to reconstruct the evolution of the area of Kilkis. Correlation with global climatic records shows that major climatic transitions that influenced northern hemisphere seem to have also affected the region of N. Greece

PLEISTOCENE PALAEOCLIMATIC EVOLUTION FROM AGIOS GEORGIOS CAVE SPELEOTHEM (KILKIS, N. GREECE)

Palaeoclimatic reconstruction in N. Greece has been investigated in this study, using stable isotope analyses and U/Th dating of a speleothem (stalactite) from the cave of Agios Georgios (Kilkis). Sampling sequence was followed in detail in order to obtain high resolution analysis of the proxy. Speleothem δ18O entirely depends on two factors: changes in the δ18O of the percolation waters (a proxy for local rainfall δ18O) and the temperature of water-calcite fractionation inside the cave (a proxy for outside air temperatures). During periods of relatively stable temperatures, δ13C shifts are caused principally by variations in soil CO2 input and physico-chemical processes inside the cave. More important processes affect the δ13C signal of speleothem inside the cave are length of flow path and rates of CO2 degassing.The lower δ13C calcite values indicate greater respiratory activity of soils under wetter conditions. The stalagmite layers were dated through U/Th geochronological method, which places the carbonate precipitation in Middle Pleistocene (630-300ka BP). The isotopic composition of the layers was used in combination with the dating results to reconstruct the evolution of the area of Kilkis. Correlation with global climatic records shows that major climatic transitions that influenced northern hemisphere seem to have also affected the region of N. Greece

The 4.2 ka event in the central Mediterranean: new data from a Corchia speleothem (Apuan Alps, central Italy)

Abstract. We present new data on the 4.2 ka event in the central Mediterranean from Corchia Cave (Tuscany, central Italy) stalagmite CC27. The stalagmite was analyzed for stable isotopes (δ13C and δ18O) and trace elements (Mg, U, P, Y), with all proxies showing a coherent phase of reduced cave recharge between ca. 4.5 and 4.1 ka BP. Based on the current climatological data on cyclogenesis, the reduction in cave recharge is considered to be associated with the weakening of the cyclone center located in the Gulf of Genoa in response to reduced advection of air masses from the Atlantic during winter. These conditions, which closely resemble a positive North Atlantic Oscillation (NAO) type of configuration, are associated with cooler and wetter summers with reduced sea warming, which reduced the western Mediterranean evaporation during autumn–early winter, further reducing precipitation

Late Quaternary palaeoenvironmental reconstruction from Lakes Ohrid and Prespa (Macedonia/Albania border) using stable isotopes

Here we present stable isotope data from three sediment records from lakes that lie along the Macedonian-Albanian border (Lake Prespa: 1 core, and Lake Ohrid: 2 cores). The records only overlap for the last 40 kyr, although the longest record contains the MIS 5/6 transition (Lake Ohrid). The sedimentary characteristics of both lakes differ significantly between the glacial and interglacial phases. At the end of MIS 6 Lake Ohrid's water level was low (high δ18Ocalcite) and, although productivity was increasing (high calcite content), the carbon supply was mainly from inorganic catchment rock sources (high δ13Ccarb). During the last interglacial, calcite and TOC production and preservation increased, progressively lower δ18Ocalcite suggest increase in humidity and lake levels till around 115 ka. During ca. 80 ka to 11 ka the lake records suggest cold conditions as indicated by negligible calcite precipitation and low organic matter content. In Lake Ohrid δ13Corg are complacent, in contrast Lake Prespa shows consistently higher δ13Corg suggesting a low oxidation of 13C-depleted organic matter in agreement with a general deterioration of climate conditions during the glacial. From 15 ka to the onset of the Holocene, calcite and TOC begin to increase, suggesting lake levels were probably low (high δ18Ocalcite). In the Holocene (11 ka to present) enhanced productivity is manifested by high calcite and organic matter content. All three cores show an early Holocene characterised by low δ18Ocalcite, apart from the very early Holocene phase in Prespa where the lowest δ18Ocalcite occurs at ca. 7.5 ka, suggesting a phase of higher lake level only in (the more sensitive) Lake Prespa. From 6 ka δ18Ocalcite suggest progressive aridification, in agreement with many other records in the Mediterranean, although the uppermost sediments in one core records low δ18Ocalcite which we interpret as a result of human activity. Overall, the isotope data present here confirm that these two big lakes have captured the large scale, low frequency palaeoclimate variation that is seen in Mediterranean lakes, although in detail there is much palaeoclimate information that could be gained, especially small scale, high frequency differences between this region and the Mediterranean

Dengue fever complicated by liver dysfunction due to possible co-infection with hepatitis E in a returning traveller from Cuba

Dengue fever is a mosquito-borne infection that co-circulates with Chikungunya and Zika virus infection in many parts of the world. Dengue virus (DENV) is occasionally responsible for acute hepatitis and a few cases of acute hepatitis due to co-infection with DENV and hepatitis E virus have been described in India. A 37-year-old Cuban woman living in Italy was admitted to our hospital with a presumed arboviral infection upon her return to Italy short after a 15-day trip to her home-country to visit relatives. An acute infection due to DENV serotype 1 was initially diagnosed, following a clinical course characterized by signs of liver dysfunction that were possibly due to co-infection with hepatitis E virus

Corrigendum to “Pollen-based paleoenvironmental and paleoclimatic change at Lake Ohrid (south-eastern Europe) during the past 500 ka” published in Biogeosciences, 13, 1423–1437, 2016

In this corrigendum we report an updated pollen record from the Lake Ohrid DEEP site spanning the past 500 ka whereby we have reprocessed and re-analyzed 104 samples affected by chemical procedure problems that occurred in one palynological laboratory. Firstly, these samples were affected by the use of wrong containers, causing in- adequate settling of particles at the set centrifuging speed. Secondly, HCl and HF treatments were combined without the prescribed intermediate centrifuging and decanting steps. The inaccuracy in the protocol resulted in the loss of smaller pollen grains and in the overrepresentation of bisaccate ones in most of the re-analyzed samples. We therefore provide an updated set of figures with the new data and have revised the description of the results, discussion and conclusions re- ported in Sadori et al. (2016) where necessary. We stress that the majority of the original results and conclusions remain valid, while the records’ reliability and resolution have improved as 12 samples that had been omitted in the original study because of low count sums are now included in the revised dataset (Sadori et al., 2018)

Imported dengue fever: a 16-years retrospective analysis in Milan (Italy) and a brief review of the European literature

Dengue Fever (DF), transmitted by Aedes mosquitoes, is the most common arthropod-borne infection, it is almost ubiquitous in tropical and subtropical areas with an estimate of 360 million infections per year. A competent vector (A. albopictus) is present in most of Southern Europe and is endemic in Italy. We conducted a 16-year retrospective study of probable/confirmed dengue fever observed at the Department of Infectious Diseases of Luigi Sacco Hospital in Milan, Italy. Overall 122 patients were included in the study, 106 with probable and 16 with proven diagnosis of dengue fever. Most patients (91%) were Italian, with a median age of 35 years (IQR 29-46 years) and similar gender distribution, travelling for tourism (80%). Asia (mainly South East Asia and Indian Subcontinent) was the most frequent travel destination (55%), followed by Central America and the Caribbeans (22%). August-September was the peak season of presentation (42.6%). The majority of our diagnoses were based on serology alone. The most common signs and symptoms were fever (99,2%), maculopapular rash (50,8%), headache (50,8%), arthralgias (50,8%) and myalgias (46,7%). Leukopenia (77%), thrombocytopenia (81%) and altered LDH, AST and ALT (respectively 60,6%, 54,1% and 45,9%) were the most common laboratory test's abnormalities. No cases of severe DF were recorded. Our epidemiological and clinical findings are largely in accordance with most recent studies about imported DF in Europe. Although very similar in presentation to other arthropod-borne illnesses, some clinical features may help in differentiating DF from other causes of fever in the returning traveler

Central Mediterranean tephrochronology between 313 and 366 ka. New insights from the Fucino paleolake sediment succession

Thirty-two tephra layers were identified in the time-interval 313–366 ka (Marine Isotope Stages 9–10) of the Quaternary lacustrine succession of the Fucino Basin, central Italy. Twenty-seven of these tephra layers yielded suitable geochemical material to explore their volcanic origins. Investigations also included the acquisition of geochemical data of some relevant, chronologically compatible proximal units from Italian volcanoes. The record contains tephra from some well known eruptions and eruptive sequences of Roman and Roccamonfina volcanoes, such as the Magliano Romano Plinian Fall, the Orvieto–Bagnoregio Ignimbrite, the Lower White Trachytic Tuff and the Brown Leucitic Tuff. In addition, the record documents eruptions currently undescribed in proximal (i.e. near-vent) sections, suggesting a more complex history of the major eruptions of the Colli Albani, Sabatini, Vulsini and Roccamonfinavolcanoes between 313 and 366 ka. Six of the investigated tephra layers were directly dated by single-crystal-fusion 40Ar/39Ar dating, providing the basis for a Bayesian age–depth model and a reassessment of the chronologies for both already known and dated eruptive units and for so far undated eruptions. The results provide a significant contribution for improving knowledge on the peri-Tyrrhenian explosive activity as well as for extending the Mediterranean tephrostratigraphical framework, which was previously based on limited proximal and distal archives for that time interval

Aligning MIS5 proxy records from Lake Ohrid (FYROM) with independently dated Mediterranean archives: implications for core chronology

The DEEP site sediment sequence obtained during the ICDP SCOPSCO project at Lake Ohrid was dated using tephrostratigraphic information, cyclostratigraphy, and orbital tuning through marine isotope record. Although this approach is suitable for the generation of a general chronological framework of the long succession, it is insufficient to resolve more detailed paleoclimatological questions, such as leads and lags of climate events between marine and terrestrial records or between different regions. In this paper, we demonstrate how the use of different tie points can affect cyclostratigraphy and orbital tuning for the period between ca. 140 and 70 ka and how the results can be correlated with directly/indirectly radiometrically-dated Mediterranean marine and continental proxy records. The alternative age model obtained shows consistent differences with that proposed by Francke et al. (2015) for the same interval, in particular at the level of the MIS6-5e transition. According to this age model, different proxies from the DEEP site sediment record support an increase of temperatures between glacial to interglacial conditions, which is almost synchronous with a rapid increase in sea surface temperature observed in the western Mediterranean. The results show how important a detailed study of independent chronological tie points is for synchronizing different records and to highlight asynchronisms of climate events