463 research outputs found
Influence of local fullerene orientation on the electronic properties of A3C60 compounds
We have investigated sodium containing fullerene superconductors Na2AC60, A =
Cs, Rb, and K, by Na-23 nuclear magnetic resonance (NMR) spectroscopy at 7.5 T
in the temperature range of 10 to 400 K. Despite the structural differences
from the Rb3C60 class of fullerene superconductors, in these compounds the NMR
line of the tetrahedrally coordinated alkali nuclei also splits into two lines
(T and T') at low temperature. In Na2CsC60 the splitting occurs at 170 K; in
the quenched cubic phase of Na2RbC60 and Na2KC60 we observe split lines at 80
K. Detailed investigations of the spectrum, spin-spin and spin-lattice
relaxation as well as spin-echo double resonance (SEDOR) in Na2CsC60 we show
that these two different tetrahedral sites are mixed on a microscopic scale.
The T and T' sites differ in the orientation of first-neighbor C60 molecules.
We present evidence that the orientations of neighboring molecules are
uncorrelated. Thermally activated molecular reorientations cause an exchange
between the T and T' sites and motional narrowing at high temperature. We infer
the same activation energy, 3300 K, in the temperature range 125 to 300 K. The
spin lattice relaxation rate is the same for T and T' down to 125 K but
different below. Both the spin-lattice relaxation rate and Knight shift are
strongly temperature dependent in the whole range investigated. We interpret
this temperature variation by the effect of phonon excitations involving the
rigid librational motion of the C60 molecules. By extending the understanding
of the structure and molecular dynamics of C60 superconductors, these results
may help in clarifying the effects of the structure on the superconducting
properties.Comment: 13 pages, 10 figures, submitted to PR
Long-lived memory for mesoscopic quantum bits
We describe a technique to create long-lived quantum memory for quantum bits
in mesoscopic systems. Specifically we show that electronic spin coherence can
be reversibly mapped onto the collective state of the surrounding nuclei. The
coherent transfer can be efficient and fast and it can be used, when combined
with standard resonance techniques, to reversibly store coherent superpositions
on the time scale of seconds. This method can also allow for ``engineering''
entangled states of nuclear ensembles and efficiently manipulating the stored
states. We investigate the feasibility of this method through a detailed
analysis of the coherence properties of the system.Comment: 4 pages, 2 figure
Entanglement in a Solid State Spin Ensemble
Entanglement is the quintessential quantum phenomenon and a necessary
ingredient in most emerging quantum technologies, including quantum repeaters,
quantum information processing (QIP) and the strongest forms of quantum
cryptography. Spin ensembles, such as those in liquid state nuclear magnetic
resonance, have been powerful in the development of quantum control methods,
however, these demonstrations contained no entanglement and ultimately
constitute classical simulations of quantum algorithms. Here we report the
on-demand generation of entanglement between an ensemble of electron and
nuclear spins in isotopically engineered phosphorus-doped silicon. We combined
high field/low temperature electron spin resonance (3.4 T, 2.9 K) with
hyperpolarisation of the 31P nuclear spin to obtain an initial state of
sufficient purity to create a non-classical, inseparable state. The state was
verified using density matrix tomography based on geometric phase gates, and
had a fidelity of 98% compared with the ideal state at this field and
temperature. The entanglement operation was performed simultaneously, with high
fidelity, to 10^10 spin pairs, and represents an essential requirement of a
silicon-based quantum information processor.Comment: 4 pages, 3 figures plus supporting information of 4 pages, 1 figure
v2: Updated reference
Charge Order Driven spin-Peierls Transition in NaV2O5
We conclude from 23Na and 51V NMR measurements in NaxV2O5(x=0.996) a charge
ordering transition starting at T=37 K and preceding the lattice distortion and
the formation of a spin gap Delta=106 K at Tc=34.7 K. Above Tc, only a single
Na site is observed in agreement with the Pmmn space group of this first
1/4-filled ladder system. Below Tc=34.7 K, this line evolves into eight
distinct 23Na quadrupolar split lines, which evidences a lattice distortion
with, at least, a doubling of the unit cell in the (a,b) plane. A model for
this unique transition implying both charge density wave and spin-Peierls order
is discussed.Comment: 4 pages, 3 figures, submitted to Phys. Rev. Let
An all silicon quantum computer
A solid-state implementation of a quantum computer composed entirely of
silicon is proposed. Qubits are Si-29 nuclear spins arranged as chains in a
Si-28 (spin-0) matrix with Larmor frequencies separated by a large magnetic
field gradient. No impurity dopants or electrical contacts are needed.
Initialization is accomplished by optical pumping, algorithmic cooling, and
pseudo-pure state techniques. Magnetic resonance force microscopy is used for
readout. This proposal takes advantage of many of the successful aspects of
solution NMR quantum computation, including ensemble measurement, RF control,
and long decoherence times, but it allows for more qubits and improved
initialization.Comment: ReVTeX 4, 5 pages, 2 figure
Vortex State of TlBaCuO via Tl NMR at 2 Tesla
We report a Tl NMR study of vortex state for an aligned
polycrystalline sample of an overdoped high- superconductor
TlBaCuO (85 K) with magnetic field 2 T along
the c axis. We observed an imperfect vortex lattice, so-called Bragg glass at
=5 K, coexistence of vortex solid with liquid between 10 and 60 K, and
vortex melting between 65 and 85 K. No evidence for local antiferromagnetic
ordering at vortex cores was found for our sample.Comment: 4 pages with 5 figure
Gaps and excitations in fullerides with partially filled bands : NMR study of Na2C60 and K4C60
We present an NMR study of Na2C60 and K4C60, two compounds that are related
by electron-hole symmetry in the C60 triply degenerate conduction band. In both
systems, it is known that NMR spin-lattice relaxation rate (1/T1) measurements
detect a gap in the electronic structure, most likely related to
singlet-triplet excitations of the Jahn-Teller distorted (JTD) C60^{2-} or
C60^{4-}. However, the extended temperature range of the measurements presented
here (10 K to 700 K) allows to reveal deviations with respect to this general
trend, both at high and low temperatures. Above room temperature, 1/T1 deviates
from the activated law that one would expect from the presence of the gap and
saturates. In the same temperature range, a lowering of symmetry is detected in
Na2C60 by the appearance of quadrupole effects on the 23Na spectra. In K4C60,
modifications of the 13C spectra lineshapes also indicate a structural
modification. We discuss this high temperature deviation in terms of a coupling
between JTD and local symmetry. At low temperatures, 1/TT tends to a
constant value for Na2C60, both for 13C and 23Na NMR. This indicates a residual
metallic character, which emphasizes the proximity of metallic and insulting
behaviors in alkali fullerides.Comment: 12 pages, 13 figure
Bang-bang control of fullerene qubits using ultra-fast phase gates
Quantum mechanics permits an entity, such as an atom, to exist in a
superposition of multiple states simultaneously. Quantum information processing
(QIP) harnesses this profound phenomenon to manipulate information in radically
new ways. A fundamental challenge in all QIP technologies is the corruption of
superposition in a quantum bit (qubit) through interaction with its
environment. Quantum bang-bang control provides a solution by repeatedly
applying `kicks' to a qubit, thus disrupting an environmental interaction.
However, the speed and precision required for the kick operations has presented
an obstacle to experimental realization. Here we demonstrate a phase gate of
unprecedented speed on a nuclear spin qubit in a fullerene molecule (N@C60),
and use it to bang-bang decouple the qubit from a strong environmental
interaction. We can thus trap the qubit in closed cycles on the Bloch sphere,
or lock it in a given state for an arbitrary period. Our procedure uses
operations on a second qubit, an electron spin, in order to generate an
arbitrary phase on the nuclear qubit. We anticipate the approach will be vital
for QIP technologies, especially at the molecular scale where other strategies,
such as electrode switching, are unfeasible
Reply to "Localized Behavior near the Zn Impurity in YBa2Cu4O8 as Measured By Nuclear Quadrupole Resonance"
Julien et al. have commented on two of our publications claiming that we have
made erroneous interpretations of the nuclear magnetic resonance (NMR) and
nuclear quadrupole resonance (NQR) data. Specifically, they believe that their
model of an extended staggered moment about a Zn impurity is the only
interpretation of the data [Julien et al., Phys. Rev Lett. 84, 3422 (2000)].
Not only does their claim ignore models presented by other authors, we show
that the model of Julien et al. [Phys. Rev Lett. 84, 3422 (2000)] does not
consistently reproduce all of the NMR data.Comment: 16 pages in PDF forma
Spin coherence lifetime extension in Tm:YAG through dynamical decoupling
We report on spin coherence lifetime extension on Tm:YAG obtained
through dynamically decoupling the thulium spins from their magnetic
environment. The coherence lifetime reached with a Carr-Purcell-Meiboom-Gill
sequence revealed a 450-fold extension [ ms] with respect
to previously measured values. Comparison to a simple theoretical model allowed
us to estimate the correlation time of the fluctuations of the ground level
transition frequency to s at 1.7 K. For attaining efficient
decoupling sequences, we developed a strategy inspired by the
\emph{zero-first-order Zeeman} effect to minimize the large inhomogeneous
broadening of the ground level spin transition.Comment: 10 pages, 7 figure
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