161 research outputs found

    Preparation and characteristics of the sulfonated chitosan derivatives electrodeposited onto 316l stainless steel surface

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    In order to ameliorate the properties of corrosion resistance and achieve applications in anti-biofouling of 316L stainless steel (SS), a sulfated derivative of chitosan was deposited onto stainless steel surface by an electrochemical method. In detail, chitosan-catechol (CS-CT) was synthesised in the hydrochloric acid solution by the Mannich reaction and then electrodeposited on the surface of the polished 316L stainless steel. The chitosan-catechol deposited SS sample was further modified with maleic anhydride and sulfite. The grafting progress was monitored by FTIR, UV spectrophotometer and X-ray photoelectron spectroscopy. Hydrophilicity and corrosion resistance of modified SS were characterized by water contact angle measurements, Tafel curves and electrochemical impedance spectroscopy. The morphology of the SS surface before and after the modification was investigated by atomic force microscopy and scanning electron microscope. Further, the anti-biofouling performance in terms of the anti-adsorption protein and anti-bacteria effects of all modified SS samples were estimated, and the modified 316L exhibits the capability of lower protein adsorption and improved antibacterial effect.info:eu-repo/semantics/publishedVersio

    Police killings of Black people and rates of sexually transmitted infections: A cross-sectional analysis of 75 large US metropolitan areas, 2016

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    Objectives Emerging literature shows that racialised police brutality, a form of structural racism, significantly affects health and well-being of racial/ethnic minorities in the USA. While public health research suggests that structural racism is a distal determinant of sexually transmitted infections (STIs) among Black people, no studies have empirically linked police violence to STIs. To address this gap, our study measures associations between police killings and rates of STIs among Black residents of US metropolitan statistical areas (MSAs). Methods This cross-sectional ecological analysis assessed associations between the number of Black people killed by police in 2015 and rates of primary and secondary syphilis, gonorrhoea and chlamydia per 100 000 Black residents of all ages in 2016 in 75 large MSAs. Multivariable models controlled for MSA-level demographic and socioeconomic characteristics, police expenditures, violent crime, arrest and incarceration rates, insurance rates and healthcare funding. Results In 2015, the median number of Black people killed by police per MSA was 1.0. In multivariable models, police killings were positively and significantly associated with syphilis and gonorrhoea rates among Black residents. Each additional police killing in 2015 was associated with syphilis rates that were 7.5% higher and gonorrhoea rates that were 4.0% higher in 2016. Conclusions Police killings of Black people may increase MSA-level risk of STI infections among Black residents. If future longitudinal analyses support these findings, efforts to reduce STIs among Black people should include reducing police brutality and addressing mechanisms linking this violence to STIs

    Evidence for HIV transmission across key populations: a longitudinal analysis of HIV and AIDS rates among Black people who inject drugs and Black heterosexuals in 84 large U.S. metropolitan areas, 2008–2016

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    Purpose: To assess cross-population linkages in HIV/AIDS epidemics, we tested the hypothesis that the number of newly diagnosed AIDS cases among Black people who inject drugs (PWID) was positively related to the natural log of the rate of newly diagnosed HIV infections among Black non-PWID heterosexuals in 84 large U.S. metropolitan statistical areas (MSAs) in 2008–2016. Methods: We estimated a multilevel model centering the time-varying continuous exposures at baseline between the independent (Black PWID AIDS rates) and dependent (HIV diagnoses rate among Black heterosexuals) variables. Results: At MSA level, baseline (standardized ÎČ = 0.12) Black PWID AIDS rates and change in these rates over time (standardized ÎČ = 0.11) were positively associated with the log of new HIV diagnoses rates among Black heterosexuals. Thus, MSAs with Black PWID AIDS rates that were 1 standard deviation= higher at baseline also had rates of newly diagnosed HIV infections among Black non-PWID heterosexuals that were 10.3% higher. A 1 standard deviation increase in independent variable over time corresponded to a 7.8% increase in dependent variable. Conclusions: Black PWID AIDS rates may predict HIV rates among non-PWID Black heterosexuals. Effective HIV programming may be predicated, in part, on addressing intertwining of HIV epidemics across populations

    Towards Carbon Neutral CO2 Conversion to Hydrocarbons

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    With fossil fuels still predicted to contribute close to 80 % of the primary energy consumption by 2040, methods to limit further CO2 emissions in the atmosphere are urgently needed to avoid the catastrophic scenarios associated with global warming. In parallel with improvements in energy efficiency and CO2 storage, the conversion of CO2 has emerged as a complementary route with significant potential. In this work we present the direct thermo‐catalytic conversion of CO2 to hydrocarbons using a novel iron nanoparticle–carbon nanotube (Fe@CNT) catalyst. We adopted a holistic and systematic approach to CO2 conversion by integrating process optimization—identifying reaction conditions to maximize conversion and selectivity towards long chain hydrocarbons and/or short olefins—with catalyst optimization through the addition of promoters. The result is the production of valuable hydrocarbons in a manner that can approach carbon neutrality under realistic industrial process conditions

    Production of Crotonaldehyde from Acetaldol

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    Optimum operating conditions for the production of crotonaldehyde from acetaldol were investigated and the kinetics of the reaction were determined. The most important operating conditions were found to be the cracking time, the pH value of the reaction mixture, and the initial concentration of acetaldol. The order of the reaction was found to be 1.8 with respect to the acetaldol concentration. The kinetic parameters were determined to be 20.583 (m3/kmol)0.8/min for the frequency factor, and 3416.800 kJ/kmol for the activation energy. Copyright © 1994 Publisher John Wiley & Sons, Ltd

    Binary approach to the analysis of prehistoric bison distribution and paleoecology in northern Colorado and southern Wyoming, A

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    2014 Fall.Includes bibliographical references.Bison exploitation is at the heart of prehistoric hunter-gatherer subsistence on the Great Plains and can reveal robust information regarding patterns of migration, chronology, and variability in paleoclimate. However, despite association with human subsistence practices, bison population and distribution patterns across time and space are unclear. This thesis presents a study of prehistoric bison distribution and population ecology in archaeological and natural contexts in northern Colorado and southern Wyoming. Two methods are used here to reconstruct the diet and distributions of prehistoric bison populations. The first method involves identifying the known distribution of bison in archaeological and natural settings in the study area through an analysis of archival documentation. Cultural chronologies based on archaeological associations have long been valuable in regional research, but can be imprecise and of insufficient resolution for constructing detailed sequences of prehistoric events. Therefore, to expand knowledge of the regional archaeological distribution of bison, this research utilized a total of 272 archaeological sites containing faunal remains. In addition, 291 calibrated radiocarbon dates were used to compile and analyze bison presence and absence through sum probability distributions and statistical analyses. The second method explores the paleoecology of bison through the use of carbon (13C/12C) and nitrogen (15N/14N) stable isotopes analysis of bone collagen from 35 prehistoric bison specimens. Stable isotopes analysis helps to characterize bison distribution and ecology through reconstruction of bison dietary forage and is compared with paleoclimate data in order to identify trends in bison migration and population patterns. This study adds significant chronological information to the regional record of bison presence in northern Colorado and southern Wyoming and helps to correlate bison distribution patterns with the paleoclimate record
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